Chemistry for Engineering Students
4th Edition
ISBN: 9781337398909
Author: Lawrence S. Brown, Tom Holme
Publisher: Cengage Learning
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Chapter 7, Problem 7.104PAE
7.104 Hydrogen azide,
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Chapter 7 Solutions
Chemistry for Engineering Students
Ch. 7 - List some factors influencing the biocompatibility...Ch. 7 - • use electron configurations to explain why...Ch. 7 - • describe die energy changes in the formation of...Ch. 7 - • define electronegativity and state how...Ch. 7 - • identify or predict polar, nonpolar, and ionic...Ch. 7 - • write Lewis electron structures for molecules or...Ch. 7 - • describe chemical bonding using a model based on...Ch. 7 - • explain how hybridization reconciles observed...Ch. 7 - • predict the geometry of a molecule from its,...Ch. 7 - • use models (real or software) to help visualize...
Ch. 7 - • explain the formation of multiple bonds in terms...Ch. 7 - • identify sigma and pi bonds in a molecule and...Ch. 7 - Define the term biocompatibility.Ch. 7 - List some properties associated with biomaterials...Ch. 7 - Prob. 7.3PAECh. 7 - Prob. 7.4PAECh. 7 - Prob. 7.5PAECh. 7 - Prob. 7.6PAECh. 7 - Why is the ion not found in nature?Ch. 7 - Why do nonmetals tend to form anions rather than...Ch. 7 - Prob. 7.9PAECh. 7 - 7.10 Arrange the members of each of the following...Ch. 7 - 7.11 Arrange the following sets of anions in order...Ch. 7 - 7.12 Which pair will form a compound with the...Ch. 7 - 7.13 Figure 7-2 depicts the interactions of an ion...Ch. 7 - 7.14 Describe the difference between a covalent...Ch. 7 - 7.15 Covalently bonded compounds tend to have much...Ch. 7 - Prob. 7.16PAECh. 7 - 7.17 Coulombic forces are often used to explain...Ch. 7 - 7.18 In terms of the strengths of the covalent...Ch. 7 - 7.19 If the formation of chemical bonds always...Ch. 7 - 7.20 Draw the Lewis dot symbol for each of the...Ch. 7 - 7.21 Theoretical models for the structure of...Ch. 7 - 7.22 Use Lewis dot symbols to explain why chlorine...Ch. 7 - 7.23 Define the term lone pair.Ch. 7 - 7.24 How many electrons are shared between two...Ch. 7 - 7.25 How does the bond energy of a double bond...Ch. 7 - 7.26 How is electronegativity defined?Ch. 7 - 7.27 Distinguish between electron affinity and...Ch. 7 - 7.28 Certain elements in the periodic table shown...Ch. 7 - 7.29 When two atoms with different...Ch. 7 - 7.30 The bond in HF is said to be polar, with the...Ch. 7 - 7.31 Why is a bond between two atoms with...Ch. 7 - Prob. 7.32PAECh. 7 - 7.33 In each group of three bonds, which bond is...Ch. 7 - Prob. 7.34PAECh. 7 - 7.35 Which one of the following contains botb...Ch. 7 - Prob. 7.36PAECh. 7 - 7.37 Draw the Lewis structure for each of the...Ch. 7 - 7.38 Draw a Lewis structure for each of the...Ch. 7 - Prob. 7.39PAECh. 7 - 7.40 Why is it impossible for hydrogen to be the...Ch. 7 - Prob. 7.41PAECh. 7 - 7.42 Draw resonance structure for (a) (b) and (c)Ch. 7 - Prob. 7.43PAECh. 7 - Prob. 7.44PAECh. 7 - Prob. 7.45PAECh. 7 - 7.46 Consider the nitrogen-oxygen bond lengths in...Ch. 7 - 7.47 Which of the species listed has a Lewis...Ch. 7 - 7.48 Identify what is incorrect in the Lewis...Ch. 7 - 7.49 Identify what is incorrect in the Lewis...Ch. 7 - 7.50 Chemical species are said to be isoelectronic...Ch. 7 - 7.51 Explain the concept of wave interference in...Ch. 7 - 7.52 How does orbital overlap explain the buildup...Ch. 7 - 7.53 How do sigma and pi bonds differ? How are...Ch. 7 - 7.54 CO , CO2 , CH3OH , and CO32 , all contain...Ch. 7 - 7.55 Draw the Lewis dot structure of the following...Ch. 7 - 7.56 Draw the Lewis dot structures of the...Ch. 7 - 7.57 What observation about molecules compels us...Ch. 7 - Prob. 7.58PAECh. 7 - 7.59 What type of hybrid orbital is generated by...Ch. 7 - 7.60 What type of hybridization would be expected...Ch. 7 - 7.61 What hybrid orbitals would be expected for...Ch. 7 - 7.62 What type of hybridization would you expect...Ch. 7 - 7.63 What physical concept forms the premise of...Ch. 7 - 7.64 Predict the geometry of the following...Ch. 7 - Prob. 7.65PAECh. 7 - Prob. 7.66PAECh. 7 - Prob. 7.67PAECh. 7 - 7.68 Give approximate values for the indicated...Ch. 7 - 7.69 Propene has the chemical formula Describe the...Ch. 7 - Prob. 7.70PAECh. 7 - Prob. 7.71PAECh. 7 - 7.72 How does an MSN differ from amorphous silica...Ch. 7 - Prob. 7.73PAECh. 7 - 7.74 In a lattice, a positive ion is often...Ch. 7 - 7.75 Use the concept of lattice energy to...Ch. 7 - Prob. 7.76PAECh. 7 - Prob. 7.77PAECh. 7 - Prob. 7.78PAECh. 7 - Prob. 7.79PAECh. 7 - Prob. 7.80PAECh. 7 - Prob. 7.81PAECh. 7 - Prob. 7.82PAECh. 7 - Prob. 7.83PAECh. 7 - 7.84 Which of the following molecules is least...Ch. 7 - 7.85 Consider the molecule whose structure is...Ch. 7 - 7.86 Nitrogen triiodide, NI3(s) , is unstable and...Ch. 7 - 7.87 Nitrogen is capable of forming single,...Ch. 7 - 7.88 The N5+ cation has been synthesized and...Ch. 7 - Prob. 7.89PAECh. 7 - Prob. 7.90PAECh. 7 - 7.91 A Lewis structure for the oxalate ion is...Ch. 7 - Prob. 7.92PAECh. 7 - 7.93 An unknown metal M forms a chloride with the...Ch. 7 - Prob. 7.94PAECh. 7 - Prob. 7.95PAECh. 7 - 7.96 Consider the hydrocarbons whose structures...Ch. 7 - 7.97 Consider the structure shown below for as...Ch. 7 - Prob. 7.98PAECh. 7 - Prob. 7.99PAECh. 7 - Prob. 7.100PAECh. 7 - 7.101 Lead selenide nanocrystals may provide a...Ch. 7 - Prob. 7.102PAECh. 7 - Prob. 7.103PAECh. 7 - 7.104 Hydrogen azide, HN3 , is a liquid that...Ch. 7 - Prob. 7.105PAECh. 7 - Prob. 7.106PAECh. 7 - 7.107 How do the Lewis symbols for C, Si, and Ge...Ch. 7 - Prob. 7.108PAECh. 7 - Prob. 7.109PAE
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- Nitrosyl azide, N4O, is a pale yellow solid first synthesized in 1993. Write the Lewis structure for nitrosyl azide.arrow_forwardIn which of the following molecules does the sulfur have an expanded octet? For those that do, write the Lewis structure. (a) SO2 (b) SF4 (c) SO2Cl2 (d) SF6arrow_forwardWrite all resonance structures of chlorobenzene, C6H5Cl, a molecule with the same cyclic structure as benzene. In all structures, keep the CCl bond as a single bond. Which resonance structures are the most important?arrow_forward
- Acetic acid has the structure CH3CO(OH), in which the OH group is bonded to a C atom. The two carbonoxygen bonds have different lengths. When an acetic acid molecule loses the H from the OH group to form the acetate ion, the two carbonoxygen bonds become equal in length. Explain.arrow_forwardUsing the standard enthalpy of formation data in Appendix G, calculate the bond energy of the carbon-sulfur double bond in CS2.arrow_forward6. Use Lewis structures to show the electron transfer that enables these ionic compounds to be formed:(a) CaO (b) NaBrarrow_forward
- Phosphorus pentachloride, a key industrial compound with annual world production of about 2 x 107 kg, is used to make other compounds. It reacts with sulfur dioxide to produce phosphorus oxychloride (POCl3) and thionyl chloride (SOCl2). Draw a Lewis structure, and name the molecular shape of each product.arrow_forwardDetermine the number of valence electrons in nitrous acid (HNO₂, sometimes written as HONO) and then draw the corresponding Lewis structure.arrow_forwardA resident expert on electronegativity comes up to visit with you. He makes two claims (seen below) about electronegativity with relation to covalent bonding. Is the expert correct or can you refute him with your knowledge of electronegativity? (a) If a diatomic molecule is made up of atoms X and Y, which have different electronegativities, the molecule must be polar. (b) The farther two atoms are apart in a bond, the larger the dipole moment will be.arrow_forward
- Nitrogen trifluoride, NF3, has been considered a potent greenhouse gasreleased in some high-tech industries, including the manufacture of LCD(Liquid Crystal Display) and solar panels.Part (i) Draw the Lewis structure of NF3.Part (ii) Define the type of chemical bond between the three fluorine atoms and thenitrogen atom.Part (iii) Describe the molecular geometry of NF3.arrow_forwardLl.59.arrow_forwardSulfur tetrafluoride reacts slowly with oxygen gas to form sulfur tetrafluoride monoxide. Write a balanced chemical equation for the reaction. In the sulfur tetrafluoride monoxide molecule the O atom and the four F atoms are bonded to a central S atom. Write a Lewis structure for this molecule in which the formal charges of all atoms is zero. Use bond energies to estimate the enthalpy of the above reaction. (S-F bond energy = 327 kJ/mole). Is it endothermic or exothermic? Determine the electron geometry of the molecule and predict two possible molecular geometries. Which of the two molecular geometries in part d is more likely to be observed? Explain.arrow_forward
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