1 Chemistry: The Central Science 2 Atoms, Molecules, And Ions 3 Stoichiometry: Ratios Of Combination 4 Reactions In Aqueous Solutions 5 Thermochemistry 6 Quantum Theory And The Electronic Structure Of Atoms 7 Electron Configuration And The Periodic Table 8 Chemical Bonding I: Basic Concepts 9 Chemical Bonding Ii: Molecular Geometry And Bonding Theories 10 Gases 11 Intermolecular Forces And The Physical Properties Of Liquids And Solids 12 Modern Materials 13 Physical Properties Of Solutions 14 Chemical Kinetics 15 Chemical Equilibrium 16 Acids And Bases 17 Acid-base Equilibria And Solubility Equilibria 18 Entropy, Free Energy, And Equilibrium 19 Electrochemistry 20 Nuclear Chemistry 21 Environmental Chemistry 22 Coordination Chemistry 23 Metallurgy And The Chemistry Of Metals 24 Nonmetallic Elements And Their Compounds 25 Organic Chemistry expand_more
7.1 Sample Problem And Checkpoint 7.2 Sample Problem And Checkpoint 7.3 Sample Problem 7.4 Sample Problem And Checkpoint 7.5 Sample Problem And Checkpoint 7.6 Sample Problem And Checkpoint 7.7 Sample Problem 7.8 Sample Problem 7.9 Sample Problem Chapter Questions expand_more
Problem 1KSP: Often we can compare properties of two elements based solely on periodic trends. For which pair of... Problem 2KSP: 7.2
The colored spheres represent the ions Based on sue and using only a periodic table, determine... Problem 3KSP: Group 8A exhibits the highest first ionization energy. Which group do you expect to exhibit the... Problem 4KSP: Which of the following best describes why Z eff does not change significantly from top to bottom... Problem 1QP: 7.1 Briefly describe the significance of Mendeleev's periodic table.
Problem 2QP: What is Moseley's contribution to the modern periodic table? Problem 3QP: 7.3 Describe the general layout of a modern periodic table.
Problem 4QP: 7.4 What is the most important relationship among elements in the same group in the periodic... Problem 5QP Problem 6QP Problem 7QP Problem 8QP: 7.8 What is a main group element? Give names and symbols of four main group elements.
Problem 9QP: 7.9 Without referring to a periodic table, write the name and give the symbol for one element in... Problem 10QP Problem 11QP: You are given a sample of a dark, shiny solid and asked to determine whether it is the nonmetal... Problem 12QP: What are valence electrons? For main group elements, the number of valence electrons of an element... Problem 13QP: Write the outer electron configurations for the (a) alkali metals, (b) alkaline earth metals, (c)... Problem 14QP: Use the first-row transition metals ( Sc to Cu ) as an example to illustrate the characteristics of... Problem 15QP: Arsenic is not an essential element for the human body. Based on its position in the periodic table,... Problem 16QP: 7.16 In the periodic table, the element hydrogen is sometimes grouped with the alkali metals and... Problem 17QP: 7.17 A neutral atom of a certain element has 34 electrons. Consulting only the periodic table,... Problem 18QP: 7.18 Group the following electron configurations in pairs that would represent elements with similar... Problem 19QP: Group the following electron configurations in pairs that would represent elements with similar... Problem 20QP Problem 21QP: Specify the group of the periodic table in which each of the following elements is found: (a) [ Ne ]... Problem 22QP Problem 23QP: Explain why the atomic radius of Be is smaller than that of Li. Problem 24QP: The electron configuration of B is 1 S 2 2 S 2 2 P 1 . (a) If each core electron (i.e., the is... Problem 25QP: 7 25 The electron configuration of C is . (a) If each core electron (i.e., the 1s electrons) were... Problem 26QP: Define atomic radius. Does the size of an atom have a precise meaning? Explain. Problem 27QP: How does atomic radius change (a) from left to right across a period and (b) from top to bottom in a... Problem 28QP Problem 29QP: Sketch the outline of the periodic table, and show group and period trends in the first ionization... Problem 30QP Problem 31QP: Explain the trends in electron affinity from aluminum to chlorine (see Figure 7.10). Problem 32QP: A hydrogen-like ion is an ion containing only one electron. The energies of the electron in a... Problem 33QP Problem 34QP: On the basis of their positions in the periodic table, select the atom with the larger atomic radius... Problem 35QP: 7.35 Arrange the following atoms in order of increasing atomic radius:
Problem 36QP: 7.36 Which is the largest atom in the third period of the periodic table?
Problem 37QP: Which is the smallest atom in Group 7A ? Problem 38QP: Based on size, identify the spheres shown as Na, Mg. O, and S. Problem 39QP: Based on size, identify the spheres shown as K, Ca, S, and Se . Problem 40QP: Why is the radius of the lithium atom considerably larger than the radius of the hydrogen atom? Problem 41QP: Use the second period of the periodic table as an example to show that the size of atoms decreases... Problem 42QP: Arrange the following in order of increasing first ionization energy: Na, Cl, Al, S , and C s . Problem 43QP: Arrange the following in order of increasing first ionization energy: F. K, P, Ca, and Ne. Problem 44QP: 7.44 Use the third period of the periodic table as an example to illustrate the change in first... Problem 45QP: In general, the first ionization energy increases from left to right across a given period.... Problem 46QP Problem 47QP: 7.47 Two atoms have the electron configurations . The first ionization energy of one is 2080 kJ mol,... Problem 48QP Problem 49QP: Specify which of the following elements you would expect to have the greatest electron affinity. He,... Problem 50QP: Considering their electron affinities, do you think it is possible for the alkali metals to form an... Problem 51QP: Explain why alkali metals have a greater affinity for electrons than alkaline earth metals. Problem 52QP: 7.52 How does the electron configuration of ions derived from main group elements give them... Problem 53QP: 7.53 What do we mean when we say that two ions or an atom and an ion are isoelectronic?
Problem 54QP Problem 55QP: Give three examples of first-row transition metal (Se to Cu) ions that are isoelectronic with argon. Problem 56QP: A M 2+ ion derived from a metal in the first transition metal series has four electrons in the 3d... Problem 57QP: A metal ion with a net +3 charge has five electrons in the 3d subshell. Identify the metal. Problem 58QP Problem 59QP: 7.59 Group the species that are isoelectronic: .
Problem 60QP: 7.60 Write the ground-state electron configurations of the following transition metal ions:
Problem 61QP Problem 62QP: 7.62 Which of the following species are isoelectronic with each other:
Problem 63QP Problem 64QP Problem 65QP: Indicate which one of the two species in each of the following pairs is smaller: ( a ) Cl or Cl - ,... Problem 66QP Problem 67QP Problem 68QP Problem 69QP Problem 70QP Problem 71QP Problem 72QP Problem 73QP Problem 74QP Problem 75QP Problem 76QP Problem 77QP Problem 78QP Problem 79QP: 7 79 Write balanced equations for the reactions between each of the following oxides and water: .
Problem 80QP: Write formulas for and name the binary hydrogen compounds of the second-period elements (Li to F).... Problem 81QP Problem 82AP Problem 83AP Problem 84AP: Write equations representing the following processes: (a) The electron affinity of S - (b) The third... Problem 85AP Problem 86AP: Write the empirical (or molecular) formulas of compounds that the elements in the third period... Problem 87AP: 7.87 Arrange the following species in isoelectronic pairs:
Problem 88AP: In which of the following are the species written in decreasing order by size of radius: ( a ) Be,... Problem 89AP: Which of the following properties show a clear periodic variation: (a) first ionization energy, (b)... Problem 90AP Problem 91AP Problem 92AP: 7.92 For each pair of elements listed, give three properties that show their chemical similarity:... Problem 93AP: What is the most reactive element on the periodic table? Problem 94AP: Explain why the first electron affinity of sulfur is 200 kJ/mol but the second electron affinity is... Problem 95AP Problem 96AP: 7.96 Predict the products of the following oxides with water: . Write an equation for each of the... Problem 97AP: 7.97 write the formulas and names of the oxides of the second-period elements (Li to N). Identify... Problem 98AP Problem 99AP: The formula for calculating the energies of an electron in a hydrogen-like ion is given in Problem... Problem 100AP: 7.100 Why do noble gases have negative electron affinity values?
Problem 101AP: 7.101 The atomic radius of K is 227 pm and that of . Calculate the percent decrease in volume that... Problem 102AP: 7.102 The atomic radius of F is 72 pm and that of is 133 pm. Calculate the percent increase in... Problem 103AP: Match each of the elements on the right with its description on the left: (a) A dark-red liquid (b)... Problem 104AP Problem 105AP Problem 106AP Problem 107AP Problem 108AP: Explain, in terms of their electron configurations, why Fe 2+ is more easily oxidized to Fe 3+ than... Problem 109AP: 7.109 Write the formulas and names of the hydrides of the following second-period elements: Li, C,... Problem 110AP Problem 111AP Problem 112AP Problem 113AP: Most transition metal ions are colored. For example, a solution of CuSO 4 is blue. How would you... Problem 114AP Problem 115AP Problem 116AP Problem 117AP: 7.117 Although it is possible to determine the second, third, and higher ionization energies of an... Problem 118AP Problem 119AP Problem 120AP: Predict the atomic number and ground-state electron configuration of the next member of the alkali... Problem 121AP Problem 122AP: 7.122 Match each of the elements on the right with its description on the left:
(a)
A pale yellow... Problem 123AP: One way to estimate the effective charge ( Z eff ) of a many-electron atom is to use the equation I... Problem 124AP: Use your knowledge of thermochemistry to calculate the Δ H for the following processes: ( a ) Cl - (... Problem 125AP Problem 126AP: 7.126 On one graph, plot the effective nuclear charge (shown in parentheses) and atomic radius (see... Problem 127AP: 7.127 One allotropic form of an element X is a colorless crystalline solid. The reaction of X with... Problem 128AP: 7.128 Calculate the maximum wavelength of light (in nm) required to ionize a single sodium atom.
Problem 129AP Problem 130AP: Element M is a shiny and highly reactive metal ( melting point 63°C ) , and element X is a highly... Problem 131AP: Write the ground-state electron configurations of the following ions, which play important roles in... Problem 132AP: Thallium (Tl) is a neurotoxin and exists mostly in the Tl(I) oxidation state in its compounds.... Problem 133AP: Both Mg 2+ and Ca 2+ are important biological ions. One of their functions is to bind to the... Problem 134AP Problem 135AP Problem 136AP Problem 137AP Problem 138AP: 7.138 The ionization energy of a certain element is 412 kJ/mol. When the atoms of this element are... Problem 139AP: 7.139 Experimentally, the electron affinity of an element can be determined by using a laser light... Problem 1SEPP: A halogen has valence electrons in which orbitals? a) s b) s and p c) P d) s, p, and d Problem 2SEPP Problem 3SEPP Problem 4SEPP format_list_bulleted