Introduction to General, Organic and Biochemistry
11th Edition
ISBN: 9781285869759
Author: Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher: Cengage Learning
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Chapter 6, Problem 6.84P
6-84 (Chemical Connections 6D) What is the chemical formula for the main component of limestone and marble?
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3. (a) The Lattice enthalpy for the solid ionic compound AgBr is +900. kJ/mole.
Write the chemical equation that corresponds to the Lattice Enthalpy for AgBr(s) in the space above.
Then explain in your own words why this is a large positive number.
(b) The hydration enthalpy for AgBr is -821 kJ/mole.
Write the chemical equation that corresponds to the Hydration Enthalpy for AgBr(s) in the space above.
Then explain in your own words why this is a large negative number.…
3. (a) The Lattice enthalpy for the solid ionic compound AgBr is +900. kJ/mole.
Write the chemical equation that corresponds to the Lattice Enthalpy for AgBr(s) in the space above.
Then explain in your own words why this is a large positive number.
(b) The hydration enthalpy for AgBris -821 kJ/mole.
Write the chemical equation that corresponds to the Hydration Enthalpy for AgBr(s) in the space above.
Then explain in your own words why this is a large negative number.
(c) Would you expect this compound to be soluble in water? Why/Why not? Calculate anything you need in
order to figure this out, and explain your answer.
please answer all
Chapter 6 Solutions
Introduction to General, Organic and Biochemistry
Ch. 6.5 - Problem 6-1 How would we prepare 250 mL of a 4.4%...Ch. 6.5 - Prob. 6.2PCh. 6.5 - Problem 6-3 How would we prepare 2.0 L of a 1.06 M...Ch. 6.5 - Prob. 6.4PCh. 6.5 - Problem 6-5 If a 0.300 M glucose solution is...Ch. 6.5 - Problem 6-6 A certain wine contains 0.010 M NaHSO3...Ch. 6.5 - Prob. 6.7PCh. 6.5 - Problem 6-8 A concentrated solution of 15% w/v KOH...Ch. 6.5 - Problem 6-9 Sodium hydrogen sulfate, NaHSO4, which...Ch. 6.8 - Prob. 6.10P
Ch. 6.8 - Prob. 6.11PCh. 6.8 - Prob. 6.12PCh. 6.8 - Problem 6-13 What is the osmolarity of a 3.3% w/v...Ch. 6.8 - Prob. 6.14PCh. 6 - 6-15 Answer true or false. (a) A solute is the...Ch. 6 - 6-16 Answer true or false. (a) Solubility is a...Ch. 6 - 6-17 Vinegar is a homogeneous aqueous solution...Ch. 6 - 6-18 Suppose you prepare a solution by dissolving...Ch. 6 - 6-19 In each of the following, tell whether the...Ch. 6 - 6-20 Give a familiar example of solutions of each...Ch. 6 - 6-21 Are mixtures of gases true solutions or...Ch. 6 - 6-22 Answer true or false. (a) Water is a good...Ch. 6 - 6-23 We dissolved 0.32 g of aspartic acid in 115.0...Ch. 6 - Prob. 6.24PCh. 6 - 6-25 A small amount of solid is added to a...Ch. 6 - 6-26 On the basis of polarity and hydrogen...Ch. 6 - Prob. 6.27PCh. 6 - 6-28 Which pairs of liquids are likely to be...Ch. 6 - Prob. 6.29PCh. 6 - 6-30 Near a power plant, warm water is discharged...Ch. 6 - 6-31 If a bottle of beer is allowed to stand for...Ch. 6 - 6-32 Would you expect the solubility of ammonia...Ch. 6 - Prob. 6.33PCh. 6 - Prob. 6.34PCh. 6 - 6-35 Describe how we would prepare the following...Ch. 6 - Prob. 6.36PCh. 6 - 6-37 Calculate the w/v percentage of each of these...Ch. 6 - 6-38 Describe how we would prepare 250 mL of 0.10...Ch. 6 - 6-39 Assuming that the appropriate volumetric...Ch. 6 - 6-40 What is the molarity of each solution? (a) 47...Ch. 6 - 6-41 A teardrop with a volume of 0.5 mL contains...Ch. 6 - Prob. 6.42PCh. 6 - 6-43 The label on a sparkling cider says it...Ch. 6 - Prob. 6.44PCh. 6 - 6-45 The label on ajar of jam says it contains 13...Ch. 6 - 6-46 A particular toothpaste contains 0.17 g NaF...Ch. 6 - 6-47 A student has a bottle labeled 0.750% albumin...Ch. 6 - 6-48 How many grams of solute are present in each...Ch. 6 - 6-49 A student has a stock solution of 30.0% w/v...Ch. 6 - Prob. 6.50PCh. 6 - Prob. 6.51PCh. 6 - Prob. 6.52PCh. 6 - 6-53 Dioxin is considered to be poisonous in...Ch. 6 - 6-54 An industrial wastewater contains 3.60 ppb...Ch. 6 - 6-55 According to the label on a piece of cheese,...Ch. 6 - Prob. 6.56PCh. 6 - Prob. 6.57PCh. 6 - Prob. 6.58PCh. 6 - Prob. 6.59PCh. 6 - 6-60 Predict which of these covalent compounds is...Ch. 6 - Prob. 6.61PCh. 6 - Prob. 6.62PCh. 6 - Prob. 6.63PCh. 6 - Prob. 6.64PCh. 6 - Prob. 6.65PCh. 6 - 6-66 What gives nanotubes their unique optical and...Ch. 6 - 6-67 Calculate the freezing points of solutions...Ch. 6 - 6-68 If we add 175 g of ethylene glycol, C2H6O2,...Ch. 6 - Prob. 6.69PCh. 6 - 6-70 In winter, after a snowstorm, salt (NaCI) is...Ch. 6 - 6-71 A 4 M acetic acid (CH3COOH) solution lowers...Ch. 6 - Prob. 6.72PCh. 6 - 6-73 In each case, tell which side (if either)...Ch. 6 - 6-74 An osmotic semipermeable membrane that allows...Ch. 6 - 6-75 Calculate the osmolarity of each of the...Ch. 6 - Prob. 6.76PCh. 6 - Prob. 6.77PCh. 6 - 6-78 (Chemical Connections 6A) Oxides of nitrogen...Ch. 6 - Prob. 6.79PCh. 6 - Prob. 6.80PCh. 6 - Prob. 6.81PCh. 6 - 6-82 (Chemical Connections 6C) A solution contains...Ch. 6 - 6-83 (Chemical Connections 6C) The concentration...Ch. 6 - 6-84 (Chemical Connections 6D) What is the...Ch. 6 - Prob. 6.85PCh. 6 - Prob. 6.86PCh. 6 - Prob. 6.87PCh. 6 - Prob. 6.88PCh. 6 - Prob. 6.89PCh. 6 - Prob. 6.90PCh. 6 - 6-91 When a cucumber is put into a saline solution...Ch. 6 - Prob. 6.92PCh. 6 - 6-93 Two bottles of water are carbonated, with CO2...Ch. 6 - Prob. 6.94PCh. 6 - Prob. 6.95PCh. 6 - 6-96 We know that a 0.89% saline (NaCI) solution...Ch. 6 - Prob. 6.97PCh. 6 - Prob. 6.98PCh. 6 - 6-99 A concentrated nitric acid solution contains...Ch. 6 - 6-100 Which will have greater osmotic pressure?...Ch. 6 - Prob. 6.101PCh. 6 - Prob. 6.102PCh. 6 - 6-103 A swimming pool containing 20,000. L of...Ch. 6 - Prob. 6.104PCh. 6 - Prob. 6.105PCh. 6 - Prob. 6.106PCh. 6 - Prob. 6.107PCh. 6 - Prob. 6.108PCh. 6 - Prob. 6.109PCh. 6 - Prob. 6.110PCh. 6 - 6-111 As noted in Section 6-8C, the amount of...Ch. 6 - 6-112 List the following aqueous solutions in...Ch. 6 - 6-113 List the following aqueous solutions in...
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- 6-66 What gives nanotubes their unique optical and electrical properties?arrow_forwardAcetone, CH3COCH3, is a common laboratory solvent. It is usually contaminated with water, however. Why does acetone absorb water so readily? Draw molecular structures showing how water and acetone can interact. What intermolecular force(s) is(are) involved in the interaction?arrow_forwardWill red blood cells crenate, hemolyze, or remain unaffected when placed in each of the solutions in Problem 8-107?arrow_forward
- 6-53 Dioxin is considered to be poisonous in concentrations above 2 ppb. If a lake containing L has been contaminated by 0.1 g of dioxin, did the concentration reach a dangerous level?arrow_forward6-60 Predict which of these covalent compounds is soluble in water. (a) C2H6 (b) CH3OH (c) HF (d) NH3 (e) CCI4arrow_forward6-113 List the following aqueous solutions in order of decreasing freezing point: 0.040 M glycerin (C3H8O3) 0.025 M NaBr, and 0.015 M AI(NO3)3 Assume complete dissociation of any salts.arrow_forward
- 6-32 Would you expect the solubility of ammonia gas in water at 2 atm pressure to be: (a) greater than, (b) the same as, or (c) smaller than at 0.5 atm pressure?arrow_forward6-111 As noted in Section 6-8C, the amount of external pressure that must be applied to a more concentrated solution to stop the passage of solvent molecules across a semipermeable membrane is known as the osmotic pressure The osmotic pressure obeys a law similar in form to the ideal gas law (discussed in Section 5-4), where Substituting for pressure and solving for osmotic pressures gives the following equation: RT MRT, where M is the concentration or molarity of the solution. (a) Determine the osmotic pressure at 25°C of a 0.0020 M sucrose (C12H22O11) solution. (b) Seawater contains 3.4 g of salts for every liter of solution. Assuming the solute consists entirely of NaCl (and complete dissociation of the NaCI salt), calculate the osmotic pressure of seawater at 25°C. (c) The average osmotic pressure of blood is 7.7 atm at 25°C. What concentration of glucose (C6H12O6) will be isotonic with blood? (d) Lysozyme is an enzyme that breaks bacterial cell walls. A solution containing 0.150 g of this enzyme in 210. mL of solution has an osmotic pressure of 0.953 torr at 25°C. What is the molar mass of lysozyme? (e) The osmotic pressure of an aqueous solution of a certain protein was measured in order to determine the protein's molar mass. The solution contained 3.50 mg of protein dissolved in sufficient water to form 5.00 mL of solution. The osmotic pressure of the solution at 25°C was found to be 1.54 torr. Calculate the molar mass of the protein.arrow_forward6-112 List the following aqueous solutions in order of increasing boiling point: 0.060 M glucose (C6H12O6), 0.025 M LiBr, and 0.025 M Zn(NO3)2.Assume complete dissociation of any salts.arrow_forward
- 6-31 If a bottle of beer is allowed to stand for several hours after being opened, it becomes "flat" (it loses CO2). Explain.arrow_forward6-103 A swimming pool containing 20,000. L of water is chlorinated to have a final CI2 concentration of 0.00500 M. What is the CI2 concentration in ppm? How many kilograms of CI2 were added to the swimming pool to reach this concentration?arrow_forwardHeat is released when some solutions form; heat is absorbed when other solutions form. Provide a molecular explanation for the difference between these two types of spontaneous processes.arrow_forward
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