Organic Chemistry - Standalone book
10th Edition
ISBN: 9780073511214
Author: Francis A Carey Dr., Robert M. Giuliano
Publisher: McGraw-Hill Education
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Question
Chapter 6, Problem 31P
Interpretation Introduction
Interpretation:
The rate of racemization of
Concept introduction:
The conversion of optically pure molecule into the mixture of enantiomers (i.e. racemic mixture) is called racemization.
The change in absolute configuration at the chirality center in the substitution reaction is called inversion of configuration.
If the absolute configuration at the chirality center remains same in the substitution reaction, it is called retention of configuration.
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Students have asked these similar questions
Compound D, shown below, reacts with
hydrogen bromide by electrophilic addition. A
mixture of two organic compounds, E and F, is
formed.
CH3
CH₂CH₂
CH3
H
compound D
HBr
Mixture of organic compounds E and F
(i) Name the the two organic compounds E and
F and show their condensed formula.
(ii) Briefly explain the mechanism of the
reaction between compound D and hydrogen
bromide to form either compound E or
compound F. (You can list/state the main
steps)
(iii) Which compound, E or F is the major
product?
(a) Under certain conditions, the reaction of 0.5 M 1-bromobutane with 1.0 M sodium methoxide forms 1-methoxybutane at arate of 0.05 mol>L per second. What would be the rate if 0.1 M 1-bromobutane and 2.0 M NaOCH3 were used?
A solution of pure (S)-2-iodobutane ([a] = +15.90°) in acetone is allowed to react with radioactive iodide, 131I -, until 1.0% of the iodobutane contains radioactive iodine. The specific rotation of this recovered iodobutane is found to be +15.58°. (a) What does this result suggest about the mechanism of the reaction of 2-iodobutane with iodide ion?
Chapter 6 Solutions
Organic Chemistry - Standalone book
Ch. 6.1 - Prob. 1PCh. 6.2 - 1-Bromo-3-chloropropane reacts with one molar...Ch. 6.3 - Prob. 3PCh. 6.3 - The Fischer projection for (+)-2-bromooctane is...Ch. 6.3 - Would you expect the 2-octanol formed by SN2...Ch. 6.3 - Prob. 6PCh. 6.4 - Prob. 7PCh. 6.4 - The first step in the synthesis of the...Ch. 6.6 - Prob. 9PCh. 6.6 - Prob. 10P
Ch. 6.7 - Prob. 11PCh. 6.8 - Prob. 12PCh. 6.9 - Diethyl ether (CH3CH2OCH2CH3) has a dielectric...Ch. 6.9 - Unlike protic solvent which solvate from complexes...Ch. 6.10 - Prob. 15PCh. 6.10 - Prob. 16PCh. 6.10 - The hydrolysis of sulfonate of 2-octanol is...Ch. 6.11 - Prob. 18PCh. 6 - Prob. 19PCh. 6 - Prob. 20PCh. 6 - Both of the following reactions involve...Ch. 6 - Prob. 22PCh. 6 - Prob. 23PCh. 6 - Sodium nitrite (NaNO2) reacted with 2-iodooctane...Ch. 6 - Prob. 25PCh. 6 - Prob. 26PCh. 6 - Prob. 27PCh. 6 - The reaction of 2,2-dimethyl-1-propanol with HBr...Ch. 6 - If the temperature is not kept below 25oC during...Ch. 6 - The reaction of cyclopentyl bromide with sodium...Ch. 6 - Prob. 31PCh. 6 - Prob. 32PCh. 6 - Write an equation, clearly showing the...Ch. 6 - Prob. 34PCh. 6 - Based on what we know about nucleophiles and...Ch. 6 - Prob. 36PCh. 6 - Prob. 37PCh. 6 - Prob. 38PCh. 6 - Prob. 39PCh. 6 - Prob. 40PCh. 6 - Prob. 41DSPCh. 6 - Prob. 42DSPCh. 6 - Prob. 43DSPCh. 6 - Prob. 44DSPCh. 6 - Prob. 45DSPCh. 6 - Prob. 46DSP
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