Chemistry (Instructor's)
Chemistry (Instructor's)
10th Edition
ISBN: 9781305957787
Author: ZUMDAHL
Publisher: CENGAGE L
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Chapter 6, Problem 1RQ

Define the following terms: potential energy, kinetic energy, path-dependent function, state function, system, surroundings.

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Interpretation Introduction

Interpretation:  To understand the concepts of potential energy, kinetic energy , path-dependent function, system, state functions and surrounding.

Answer to Problem 1RQ

Answer

  • Potential energy (U): Potential energy is an energy that are stored in an object not in motion and ability of becoming active.
  • Kinetic energy (KE): The energy possessed by an object due to its motion. Kinetic energy depending upon the mass (m) and velocity (v) of an object.

                                       KE= 12mv2

  • Path-dependent function: The function which depends on the path from two value

    called path dependent functions. There are two common path dependent functions, heat and work.

  • State function: The state function or state property of a system assign the properties of a systems depends upon only its present state not past or future state.
  • System: In thermodynamics the system is defined as quantity of matter or region in the universe.
  • Surrounding: Surrounding is include everything else around the system in the universe.

Explanation of Solution

Explanation

  • Potential energy (U): Potential energy is an energy that are stored in an object not in motion and ability of becoming active.

    Chemistry (Instructor's), Chapter 6, Problem 1RQ , additional homework tip  1

    Figure 1

    Example: A ball on the table (having a mass is a potential energy)-see in Figure.1

  • Kinetic energy (KE): The energy possessed by an object due to its motion. Kinetic energy depending upon the mass (m) and velocity (v) of an object.

                                       KE= 12mv2

    Example: The ball fall down from the table. See in fig.1

  • Path-dependent function: The function which depends on the path from two value

    called path dependent functions. There are two common path dependent functions, heat and work.

    Example: Ice melting.

    Explanation: In the process of ice melting, the path functions are heat and work.

    These heat and work can explain how way the ice melting (absorb heat energy to get melt).

  • State function: The state function or state property of a system assign the properties of a systems depends upon only its present state not past or future state.

    Example: Internal energy of a ball.

    Explanation: (see in Figure.1) The internal energy of a ball is consider the initial and final of the process (fall down).

  • System: In thermodynamics the system is defined as quantity of matter or region in the universe.

    Chemistry (Instructor's), Chapter 6, Problem 1RQ , additional homework tip  2

    Figure 2

  • Surrounding: Surrounding is include everything else around the system in the universe.

    Example: A conical flask containing a solution.

    Explanation: ( See in the fig.2) In this case we consider the conical flask containing solution in which the solution is the system and other than the solution is surrounding.

Conclusion

Conclusion

The given terms were defined.

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Chapter 6 Solutions

Chemistry (Instructor's)

Ch. 6 - What is meant by the term lower in energy? Which...Ch. 6 - A fire is started in a fireplace by striking a...Ch. 6 - Liquid water turns to ice. Is this process...Ch. 6 - Consider the following statements: ''Heat is a...Ch. 6 - Consider 5.5 L of a gas at a pressure of 3.0 atm...Ch. 6 - Consider 5.5 L of a gas at a pressure of 3.0 atm...Ch. 6 - What if energy was not conserved? How would this...Ch. 6 - Hesss law is really just another statement of the...Ch. 6 - In the equation w = P V, why is there a negative...Ch. 6 - Consider an airplane trip from Chicago, Illinois,...Ch. 6 - How is average bond strength related to relative...Ch. 6 - Assuming gasoline is pure C8H18(l), predict the...Ch. 6 - What is the difference between H and E?Ch. 6 - The enthalpy change for the reaction...Ch. 6 - Explain why oceanfront areas generally have...Ch. 6 - The equation for the fermentation of glucose to...Ch. 6 - Explain why H is obtained directly from coffee-cup...Ch. 6 - The enthalpy of combustion of CH4(g) when H2O (1)...Ch. 6 - The enthalpy change for a reaction is a state...Ch. 6 - Standard enthalpies of formation are relative...Ch. 6 - The combustion of methane can be represented as...Ch. 6 - Why is it a good idea to rinse your thermos bottle...Ch. 6 - Prob. 26QCh. 6 - What is incomplete combustion of fossil fuels? Why...Ch. 6 - Explain the advantages and disadvantages of...Ch. 6 - Prob. 29ECh. 6 - Which has the greater kinetic energy, an object...Ch. 6 - Consider the following diagram when answering the...Ch. 6 - A gas absorbs 45 kJ of heat and does 29 kJ of...Ch. 6 - Calculate E for each of the following. a. q = 47...Ch. 6 - A system undergoes a process consisting of the...Ch. 6 - If the internal energy of a thermodynamic system...Ch. 6 - Calculate the internal energy change for each of...Ch. 6 - A sample of an ideal gas at 15.0 atm and 10.0 L is...Ch. 6 - A piston performs work of 210. L atm on the...Ch. 6 - Consider a mixture of air and gasoline vapor in a...Ch. 6 - As a system increases in volume, it absorbs 52.5 J...Ch. 6 - A balloon filled with 39.1 moles of helium has a...Ch. 6 - One mole of H2O(g) at 1.00 atm and 100.C occupies...Ch. 6 - One of the components of polluted air is NO. It is...Ch. 6 - The reaction SO3(g)+H2O(l)H2SO4(aq) is the last...Ch. 6 - Are the following processes exothermic or...Ch. 6 - Are the following processes exothermic or...Ch. 6 - The overall reaction in a commercial heat pack can...Ch. 6 - Consider the following reaction:...Ch. 6 - Consider the combustion of propane:...Ch. 6 - Consider the following reaction:...Ch. 6 - For the process H2O(l) H2O(g) at 298 K and 1.0...Ch. 6 - For the following reactions at constant pressure,...Ch. 6 - Consider the substances in Table 7-1. Which...Ch. 6 - The specific heat capacity of silver is 0.24 J/Cg....Ch. 6 - A 500-g sample of one of the substances listed in...Ch. 6 - It takes 585 J of energy to raise the temperature...Ch. 6 - A 30.0-g sample of water at 280. K is mixed with...Ch. 6 - A biology experiment requires the preparation of a...Ch. 6 - A 5.00-g sample of aluminum pellets (specific heat...Ch. 6 - Hydrogen gives off 120. J/g of energy when burned...Ch. 6 - A 150.0-g sample of a metal at75.0C is added to...Ch. 6 - A 110.-g sample of copper (specific heat capacity...Ch. 6 - In a coffee-cup calorimeter, 50.0 mL of 0.100 M...Ch. 6 - In a coffee-cup calorimeter, 100.0 mL of 1.0 M...Ch. 6 - A coffee-cup calorimeter initially contains 125 g...Ch. 6 - In a coffee-cup calorimeter, 1.60 g NH4NO3 is...Ch. 6 - Consider the dissolution of CaCl2:...Ch. 6 - Consider the reaction...Ch. 6 - Quinone is an important type of molecule that is...Ch. 6 - The energy content of food is typically determined...Ch. 6 - The heat capacity of a bomb calorimeter was...Ch. 6 - The combustion of 0.1584 g benzoic acid increases...Ch. 6 - The enthalpy of combustion of solid carbon to form...Ch. 6 - Combustion reactions involve reacting a substance...Ch. 6 - Given the following data calculate H for the...Ch. 6 - Prob. 78ECh. 6 - The bombardier beetle uses an explosive discharge...Ch. 6 - Calculate H for the reaction...Ch. 6 - Given the following data...Ch. 6 - Given the following data...Ch. 6 - Give the definition of the standard enthalpy of...Ch. 6 - Write reactions for which the enthalpy change will...Ch. 6 - Use the values ofHf in Appendix 4 to calculate H...Ch. 6 - Use the values of Hf in Appendix 4 to calculate H...Ch. 6 - The Ostwald process for the commercial production...Ch. 6 - Calculate H for each of the following reactions...Ch. 6 - The reusable booster rockets of the space shuttle...Ch. 6 - The space shuttle Orbiter utilizes the oxidation...Ch. 6 - Consider the reaction...Ch. 6 - The standard enthalpy of combustion of ethene gas,...Ch. 6 - Water gas is produced from the reaction of steam...Ch. 6 - Syngas can be burned directly or converted to...Ch. 6 - Ethanol (C2H5OH) has been proposed as an...Ch. 6 - Methanol (CH3OH) has also been proposed as an...Ch. 6 - Some automobiles and buses have been equipped to...Ch. 6 - Acetylene (C2H2) and butane (C4H10) are gaseous...Ch. 6 - Prob. 99ECh. 6 - The complete combustion of acetylene, C2H2(g),...Ch. 6 - It has been determined that the body can generate...Ch. 6 - One way to lose weight is to exercise! Walking...Ch. 6 - Three gas-phase reactions were run in a...Ch. 6 - Nitrogen gas reacts with hydrogen gas to form...Ch. 6 - Combustion of table sugar produces CO2(g) and H2O(...Ch. 6 - Prob. 106AECh. 6 - A serving size of six cookies contains 4 g of fat,...Ch. 6 - Calculate H for the reaction...Ch. 6 - The enthalpy of neutralization for the reaction of...Ch. 6 - Given the following data: NO2(g) NO(g) + O(g)H =...Ch. 6 - If a student performs an endothermic reaction in a...Ch. 6 - In a bomb calorimeter, the reaction vessel is...Ch. 6 - The bomb calorimeter in Exercise 102 is filled...Ch. 6 - Consider the two space shuttle fuel reactions in...Ch. 6 - Consider the following equations:...Ch. 6 - Given the following data...Ch. 6 - At 298 K, the standard enthalpies of formation for...Ch. 6 - Using the following data, calculate the standard...Ch. 6 - A sample of nickel is heated to 99.8C and placed...Ch. 6 - Given: 2Cu2O(s) + O2(g) 4CuO(s)H = 288 kJ Cu2O(s)...Ch. 6 - Calculate H for each of the following reactions,...Ch. 6 - Consider a balloon filled with helium at the...Ch. 6 - In which of the following systems is(are) work...Ch. 6 - Which of the following processes are exothermic?...Ch. 6 - Consider the reaction...Ch. 6 - A swimming pool, 10.0 m by 4.0 m, is filled with...Ch. 6 - In a coffee-cup calorimeter, 150.0 mL of 0.50 M...Ch. 6 - Calculate H for the reaction...Ch. 6 - Which of the following substances have an enthalpy...Ch. 6 - Consider 2.00 moles of an ideal gas that are taken...Ch. 6 - For the process H2O(l)H2O(g) at 298 K and 1.0 atm,...Ch. 6 - The sun supplies energy at a rate of about 1.0...Ch. 6 - The best solar panels currently available are...Ch. 6 - On Easter Sunday, April 3, 1983, nitric acid...Ch. 6 - A piece of chocolate cake contains about 400...Ch. 6 - The standard enthalpies of formation for S(g),...Ch. 6 - You have a l.00-mole sample of water at 30.C and...Ch. 6 - A 500.0-g sample of an element at 195C is dropped...Ch. 6 - When 1.00 L of 2.00 M Na2SO4 solution at 30.0c is...Ch. 6 - The preparation of NO2(g) from N2(g) and O2(g) is...Ch. 6 - Nitromethane, CH3NO2, can be used as a fuel. When...Ch. 6 - A cubic piece of uranium metal (specific heat...Ch. 6 - A gaseous hydrocarbon reacts completely with...
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