The more stable carbocation in the given pair is to be identified. Concept introduction: The carbocation becomes stable when atoms or groups attached to it stabilize the positive charge on it. The induced polarization of sigma bond is called inductive effect. The electron donating atom or group has a positive inductive effect that stabilizes the positive charge on carbon. The electron withdrawing atom or group has negative inductive effect that destabilizes the positive charge on carbon. The alkyl groups have electron donating inductive effect and stabilize carbocation (carbon with positive charge). The alkyl groups also show delocalization of electrons in sigma bonds through hyperconjugation and stabilized carbocation. Hyperconjugation is the delocalization of electrons in C-H sigma bond of methyl/alkyl group.

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Answer 1

Question

Chapter 5.9, Problem 13P

Interpretation Introduction

Interpretation:

The more stable carbocation in the given pair is to be identified.

Concept introduction:

The carbocation becomes stable when atoms or groups attached to it stabilize the positive charge on it.

The induced polarization of sigma bond is called inductive effect.

The electron donating atom or group has a positive inductive effect that stabilizes the positive charge on carbon.

The electron withdrawing atom or group has negative inductive effect that destabilizes the positive charge on carbon.

The alkyl groups have electron donating inductive effect and stabilize carbocation (carbon with positive charge).

The alkyl groups also show delocalization of electrons in sigma bonds through hyperconjugation and stabilized carbocation.

Hyperconjugation is the delocalization of electrons in C-H sigma bond of methyl/alkyl group.

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Answer 2

Question

Chapter 5.9, Problem 13P

Interpretation Introduction

Interpretation:

The more stable carbocation in the given pair is to be identified.

Concept introduction:

The carbocation becomes stable when atoms or groups attached to it stabilize the positive charge on it.

The induced polarization of sigma bond is called inductive effect.

The electron donating atom or group has a positive inductive effect that stabilizes the positive charge on carbon.

The electron withdrawing atom or group has negative inductive effect that destabilizes the positive charge on carbon.

The alkyl groups have electron donating inductive effect and stabilize carbocation (carbon with positive charge).

The alkyl groups also show delocalization of electrons in sigma bonds through hyperconjugation and stabilized carbocation.

Hyperconjugation is the delocalization of electrons in C-H sigma bond of methyl/alkyl group.

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Answer 3

Question

Chapter 5.9, Problem 13P

Interpretation Introduction

Interpretation:

The more stable carbocation in the given pair is to be identified.

Concept introduction:

The carbocation becomes stable when atoms or groups attached to it stabilize the positive charge on it.

The induced polarization of sigma bond is called inductive effect.

The electron donating atom or group has a positive inductive effect that stabilizes the positive charge on carbon.

The electron withdrawing atom or group has negative inductive effect that destabilizes the positive charge on carbon.

The alkyl groups have electron donating inductive effect and stabilize carbocation (carbon with positive charge).

The alkyl groups also show delocalization of electrons in sigma bonds through hyperconjugation and stabilized carbocation.

Hyperconjugation is the delocalization of electrons in C-H sigma bond of methyl/alkyl group.

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Answer 4

Question

Chapter 5.9, Problem 13P

Interpretation Introduction

Interpretation:

The more stable carbocation in the given pair is to be identified.

Concept introduction:

The carbocation becomes stable when atoms or groups attached to it stabilize the positive charge on it.

The induced polarization of sigma bond is called inductive effect.

The electron donating atom or group has a positive inductive effect that stabilizes the positive charge on carbon.

The electron withdrawing atom or group has negative inductive effect that destabilizes the positive charge on carbon.

The alkyl groups have electron donating inductive effect and stabilize carbocation (carbon with positive charge).

The alkyl groups also show delocalization of electrons in sigma bonds through hyperconjugation and stabilized carbocation.

Hyperconjugation is the delocalization of electrons in C-H sigma bond of methyl/alkyl group.

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Answer 5

Chapter 5.9, Problem 13P

Interpretation Introduction

Interpretation:

The more stable carbocation in the given pair is to be identified.

Concept introduction:

The carbocation becomes stable when atoms or groups attached to it stabilize the positive charge on it.

The induced polarization of sigma bond is called inductive effect.

The electron donating atom or group has a positive inductive effect that stabilizes the positive charge on carbon.

The electron withdrawing atom or group has negative inductive effect that destabilizes the positive charge on carbon.

The alkyl groups have electron donating inductive effect and stabilize carbocation (carbon with positive charge).

The alkyl groups also show delocalization of electrons in sigma bonds through hyperconjugation and stabilized carbocation.

Hyperconjugation is the delocalization of electrons in C-H sigma bond of methyl/alkyl group.

Answer 6

Chapter 5.9, Problem 13P

Interpretation Introduction

Interpretation:

The more stable carbocation in the given pair is to be identified.

Concept introduction:

The carbocation becomes stable when atoms or groups attached to it stabilize the positive charge on it.

The induced polarization of sigma bond is called inductive effect.

The electron donating atom or group has a positive inductive effect that stabilizes the positive charge on carbon.

The electron withdrawing atom or group has negative inductive effect that destabilizes the positive charge on carbon.

The alkyl groups have electron donating inductive effect and stabilize carbocation (carbon with positive charge).

The alkyl groups also show delocalization of electrons in sigma bonds through hyperconjugation and stabilized carbocation.

Hyperconjugation is the delocalization of electrons in C-H sigma bond of methyl/alkyl group.

Answer 7

Chapter 5.9, Problem 13P

Interpretation Introduction

Interpretation:

The more stable carbocation in the given pair is to be identified.

Concept introduction:

The carbocation becomes stable when atoms or groups attached to it stabilize the positive charge on it.

The induced polarization of sigma bond is called inductive effect.

The electron donating atom or group has a positive inductive effect that stabilizes the positive charge on carbon.

The electron withdrawing atom or group has negative inductive effect that destabilizes the positive charge on carbon.

The alkyl groups have electron donating inductive effect and stabilize carbocation (carbon with positive charge).

The alkyl groups also show delocalization of electrons in sigma bonds through hyperconjugation and stabilized carbocation.

Hyperconjugation is the delocalization of electrons in C-H sigma bond of methyl/alkyl group.

Answer 8

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Answer 9

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Answer 10

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Answer 11

Ch. 5.1 - Prob. 1P Ch. 5.1 - Prob. 2P Ch. 5.1 - Many compounds contain more than one functional...Ch. 5.2 - Prob. 4P Ch. 5.3 - Prob. 5P Ch. 5.4 - Classify the isomeric C4H10O alcohols as being...Ch. 5.5 - Bromine is less electronegative than chlorine, yet...Ch. 5.6 - Prob. 8P Ch. 5.7 - Prob. 9P Ch. 5.8 - Prob. 10P

Solution Summary: The author explains that the more stable carbocation in the given pair is to be identified.

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