Problem 5.1E: 5.1. Can a battery that has a voltage be considered a system at equilibrium? How about a dead... Problem 5.2E: 5.2. What is the difference between a static equilibrium and a dynamic equilibrium? Give examples... Problem 5.3E: Which system in each pair best represents equilibrium species under standard conditions of... Problem 5.4E:
5.4. Supersaturated solutions can be made in which more solute is dissolved in solution than would... Problem 5.5E:
5.5. Following is a chemical reaction between zinc metal and hydrochloric acid in a closed... Problem 5.6E: 5.6. The following is a reaction with its initial conditions (amounts of each... Problem 5.7E: The following is a reaction with initial amounts indicated. 2Al+3Cl22AlCl35.0mol9.5mol1.0mol... Problem 5.8E: 5.8. The hemoglobin in blood establishes an equilibrium with oxygen gas very quickly. The... Problem 5.9E Problem 5.10E: 5.10. If and gases were contained in a system such that the total pressure were , then the terms... Problem 5.11E: 5.11. Determine the numerical value of Q for the reaction conditions indicated.
Problem 5.12E: 5.12. True or false: If all the partial pressures of reactants and products drop by half, the value... Problem 5.13E: For the reaction 2SO3(g)2SO2(g)+O2(g) when 2mol of SO3 is added to a flask at 10L and 350.K at fixed... Problem 5.14E: 5.14. Determine and for the following reaction at , using data in Appendix 2. The partial pressures... Problem 5.15E: 5.15. Consider the reaction
If the partial pressures are such that at , what is if ?
Problem 5.16E:
5.16. In atmospheric chemistry, the following chemical reaction converts , the predominant oxide of... Problem 5.17E Problem 5.18E: 5.18. Hydrogen cyanide can isomerize to hydrogen isocyanide:
(a) Calculate the equilibrium constant... Problem 5.19E: 5.19. Assume that a reaction exists such that equilibrium occurs when the partial pressures of the... Problem 5.20E Problem 5.21E: 5.21. Show that if the coefficients of a balanced chemical reaction are all divided by two. Give an... Problem 5.22E: 5.22. True or false: If for a gas-phase reaction, then all equilibrium partial pressures of... Problem 5.23E: 5.23. The balanced chemical reaction for the formation of ammonia from its elements is
(a) What is... Problem 5.24E: The answers in exercise 5.23 should show that changing the partial pressure changes the... Problem 5.25E: At a high enough temperature, the equilibrium constant is 4.00 for the gas-phase isotope exchange... Problem 5.26E Problem 5.27E: 5.27. Nitrogen dioxide,, dimerizes easily to form dinitrogen tetroxide,:
(a) Using data in Appendix... Problem 5.28E: 5.28. Another nitrogen-oxygen reaction of some importance is
which is thought to be the primary... Problem 5.29E Problem 5.30E Problem 5.31E Problem 5.32E: 5.32. For the reaction
. (a) Using in Appendix ,determine . (b) If ,what is?
Problem 5.33E: 5.33. Use the data in Appendix to calculate for
Problem 5.34E: 5.34. The of diamond, a crystalline form of elemental carbon, is at . Give the equilibrium constant... Problem 5.35E: 5.35. The densities of graphite and diamond are and , respectively. Using the expression
and... Problem 5.36E: Buckminsterfullerene, C60, is a spherical molecule composed of hexagons and pentagons of carbon... Problem 5.37E Problem 5.38E: At what pressure does H2O have an activity of 2.00? Assume a temperature of 25.0C and a molar volume... Problem 5.39E: The bisulfate or hydrogen sulfate anion, HSO4, is a weak acid. The equilibrium constant for the... Problem 5.40E Problem 5.41E: Write the equilibrium constant expression for each reaction in terms of activities, simplifying... Problem 5.42E Problem 5.43E: For the given chemical equilibrium, these data are determined experimentally: T K 350K 3.76102 450K... Problem 5.44E: Biological standard states include specifying a reference temperature of 37.0C rather than the... Problem 5.45E: a At 25.0C, Kw for the autoionization of water is 1.011014, while at 100.0C it is 5.601013. What is... Problem 5.46E: 5.46. For a reaction whose standard enthalpy change is , what temperature is needed to double the... Problem 5.47E: 5.47. For the reaction
and . Estimate for this reaction.
Problem 5.48E: 5.48. The isotope exchange reaction
has an equilibrium constant of at . Estimate the... Problem 5.49E: 5.49. Consider the following equilibrium:
What is the effect on the equilibrium of each of the... Problem 5.50E: 5.50. For the equilibrium
Equilibrium partial pressures at are and . If the volume of the system... Problem 5.51E: The decomposition of NaHCO3, used in kitchens to extinguish fires, is... Problem 5.52E: 5.52. For the equilibrium
at,. In a flask, of is introduced. (a) Calculate the equilibrium... Problem 5.53E Problem 5.54E: 5.54. For the reaction
The equilibrium constant at is . (a) If initially, of were introduced... Problem 5.55E Problem 5.56E: 5.56. Of the amino acids listed in Table , which one should have an isoelectric point closest to ,... Problem 5.57E: 5.57. Determine the concentration of the three ionic forms of glycine present if of glycine is used... Problem 5.58E: 5.58. The formation of zwitterionic glycine, , from its fully acid form and its fully basic form... Problem 5.59E: 5.59. Monosodium glutamate, or MSG, is the sodium salt of the amino acid glutamic acid. Its formula... Problem 5.60E Problem 5.61E: Consider the balanced chemical reaction CH4(g)+2Br2(g)CH2Br2(g)+2HBr(g) A system starts with... Problem 5.62E: For the gas-phase reaction 2H2+O22H2O rxnG is 457.18kJ. What does a graph of G versus lnQ lnQ... Problem 5.63E Problem 5.64E format_list_bulleted