Chemistry
Chemistry
9th Edition
ISBN: 9781133611097
Author: Steven S. Zumdahl
Publisher: Cengage Learning
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Chapter 5, Problem 31Q
Interpretation Introduction

Interpretation:

For the given decomposition reaction of NH3 the volume of product gases is twice the volume of NH3 at constant pressure and temperature should be explained, the increment of total pressure at constant volume and temperature after the completion reaction should be determine and explain the reason for increment and the comparison between the partial pressures of product gases and initial pressure of NH3 should be determined.

Concept introduction:

  • Balanced equation of a reaction is written according to law of conservation of mass.
  • According to Avogadro’s law of gas molecules,

    If the number of moles of gases in a container is increased then the volume will increase at constant temperature and pressure.

    Equation for Avogadro’s law is,

    Vinitialninitial=Vfinalnfinal

  • According to ideal gas law: the pressure of gas is directly proportional to the number of moles of gas at constant volume and temperature.

Pn=RTV, P and n are proportional.

Mathematically, for two gases (1 and 2) at constant V and T,

P1n1=P2n2P1P2=n1n2

  • Mole ratios between the reactant and products of a reaction are depends upon the coefficients of respective reactant in a balanced chemical equation.
  • Partial pressure of a gas in a mixture of gases is the pressure of that gas when it alone.

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A 2.00 L reaction container at 25.0 °C contains CO2 (g) and O2 (g). The total pressure of the gases in the container was 656 torr and the mole fraction of CO2 is 0.245.    A)Calculate the partial pressure of oxygen gas in the mixture. B)Calculate the mass of oxygen gas in the mixture (in g). C)Which gas will rise to the top of the container? Explain your answer.
When CO2( g) is put in a sealed container at 701 K and a pressure of 10.0 atm and is heated to 1401 K, the pressure rises to 22.5 atm. Some of the CO2 decomposes to CO and O2. Calculate the mole percent of CO2 that decomposes.
12. A sample of solid potassium chlorate was heated in a test tube and decomposed into potassium chloride and oxygen gas.  The oxygen produced was collected by displacement of water at 22ºC at a total pressure of 754 torr.  The volume of the gas collected was 0.650 L, and the vapor pressure of water at 22ºC is 21 torr. Calculate the partial pressure of O2 in the gas collected and the mass of potassium chlorate in the sample that was decomposed. (2.13 g)

Chapter 5 Solutions

Chemistry

Ch. 5 - Prob. 3ALQCh. 5 - Prob. 4ALQCh. 5 - Prob. 6ALQCh. 5 - Prob. 8ALQCh. 5 - Prob. 11ALQCh. 5 - Prob. 12ALQCh. 5 - Prob. 15ALQCh. 5 - Prob. 16ALQCh. 5 - Draw molecular-level views that show the...Ch. 5 - Prob. 20QCh. 5 - Prob. 21QCh. 5 - Prob. 22QCh. 5 - Prob. 23QCh. 5 - As weather balloons rise from the earths surface,...Ch. 5 - Prob. 25QCh. 5 - Consider two different containers, each filled...Ch. 5 - Prob. 27QCh. 5 - Prob. 28QCh. 5 - Prob. 29QCh. 5 - Prob. 30QCh. 5 - Prob. 31QCh. 5 - Prob. 32QCh. 5 - Prob. 33QCh. 5 - Without looking at a table of values, which of the...Ch. 5 - Prob. 35QCh. 5 - Prob. 36QCh. 5 - Prob. 37ECh. 5 - Prob. 38ECh. 5 - A sealed-tube manometer (as shown below) can be...Ch. 5 - Prob. 40ECh. 5 - A diagram for an open-tube manometer is shown...Ch. 5 - Prob. 42ECh. 5 - Prob. 43ECh. 5 - Prob. 44ECh. 5 - Prob. 45ECh. 5 - Prob. 46ECh. 5 - Prob. 47ECh. 5 - Prob. 48ECh. 5 - Prob. 49ECh. 5 - Prob. 50ECh. 5 - The Steel reaction vessel of a bomb calorimeter,...Ch. 5 - A 5.0-L flask contains 0.60 g O2 at a temperature...Ch. 5 - Prob. 53ECh. 5 - A person accidentally swallows a drop of liquid...Ch. 5 - A gas sample containing 1.50 moles at 25C exerts a...Ch. 5 - Prob. 56ECh. 5 - Prob. 57ECh. 5 - What will be the effect on the volume of an ideal...Ch. 5 - Prob. 59ECh. 5 - Prob. 60ECh. 5 - An ideal gas is contained in a cylinder with a...Ch. 5 - Prob. 62ECh. 5 - A sealed balloon is filled with 1.00 L helium at...Ch. 5 - Prob. 64ECh. 5 - Consider the following reaction:...Ch. 5 - A student adds 4.00 g of dry ice (solid CO2) to an...Ch. 5 - Air bags are activated when a severe impact causes...Ch. 5 - Concentrated hydrogen peroxide solutions are...Ch. 5 - In 1897 the Swedish explorer Andre tried to reach...Ch. 5 - Sulfur trioxide, SO3, is produced in enormous...Ch. 5 - A 15.0-L rigid container was charged with 0.500...Ch. 5 - An important process for the production of...Ch. 5 - Consider the reaction between 50.0 mL liquid...Ch. 5 - Urea (H2NCONH2) is used extensively as a nitrogen...Ch. 5 - Prob. 75ECh. 5 - Prob. 76ECh. 5 - Prob. 77ECh. 5 - A compound has the empirical formula CHCl. A...Ch. 5 - Prob. 79ECh. 5 - Given that a sample of air is made up of nitrogen,...Ch. 5 - Prob. 81ECh. 5 - Prob. 82ECh. 5 - A piece of solid carbon dioxide, with a mass of...Ch. 5 - Prob. 84ECh. 5 - Consider the flasks in the following diagram. What...Ch. 5 - Consider the flask apparatus in Exercise 85, which...Ch. 5 - Prob. 87ECh. 5 - At 0C a 1.0-L flask contains 5.0 102 mole of N2,...Ch. 5 - Prob. 89ECh. 5 - A tank contains a mixture of 52.5 g oxygen gas and...Ch. 5 - Prob. 91ECh. 5 - Helium is collected over water at 25C and 1.00 atm...Ch. 5 - At elevated temperatures, sodium chlorate...Ch. 5 - Xenon and fluorine will react to form binary...Ch. 5 - Methanol (CH3OH) can be produced by the following...Ch. 5 - In the Mthode Champenoise, grape juice is...Ch. 5 - Hydrogen azide, HN3, decomposes on heating by the...Ch. 5 - Prob. 98ECh. 5 - Prob. 99ECh. 5 - The oxides of Group 2A metals (symbolized by M...Ch. 5 - Prob. 101ECh. 5 - Prob. 102ECh. 5 - Prob. 103ECh. 5 - Prob. 104ECh. 5 - Prob. 105ECh. 5 - Prob. 106ECh. 5 - Prob. 107ECh. 5 - Prob. 108ECh. 5 - Prob. 109ECh. 5 - Prob. 110ECh. 5 - Prob. 111ECh. 5 - Prob. 112ECh. 5 - Prob. 113ECh. 5 - Prob. 114ECh. 5 - Prob. 115ECh. 5 - Prob. 116ECh. 5 - Use the data in Table 84 to calculate the partial...Ch. 5 - Prob. 118ECh. 5 - Prob. 119ECh. 5 - Prob. 120ECh. 5 - Prob. 121ECh. 5 - Prob. 122ECh. 5 - Prob. 123AECh. 5 - At STP, 1.0 L Br2 reacts completely with 3.0 L F2,...Ch. 5 - Prob. 125AECh. 5 - Prob. 126AECh. 5 - Prob. 127AECh. 5 - Cyclopropane, a gas that when mixed with oxygen is...Ch. 5 - The nitrogen content of organic compounds can be...Ch. 5 - Prob. 130AECh. 5 - A 15.0L tank is filled with H2 to a pressure of...Ch. 5 - A spherical glass container of unknown volume...Ch. 5 - Prob. 133AECh. 5 - A 20.0L stainless steel container at 25C was...Ch. 5 - Metallic molybdenum can be produced from the...Ch. 5 - Prob. 136AECh. 5 - Prob. 137AECh. 5 - One of the chemical controversies of the...Ch. 5 - An organic compound contains C, H, N, and O....Ch. 5 - Prob. 140AECh. 5 - Prob. 141CWPCh. 5 - Prob. 142CWPCh. 5 - A certain flexible weather balloon contains helium...Ch. 5 - A large flask with a volume of 936 mL is evacuated...Ch. 5 - A 20.0L nickel container was charged with 0.859...Ch. 5 - Consider the unbalanced chemical equation below:...Ch. 5 - Prob. 147CWPCh. 5 - Which of the following statements is(are) true? a....Ch. 5 - A chemist weighed out 5.14 g of a mixture...Ch. 5 - A mixture of chromium and zinc weighing 0.362 g...Ch. 5 - Prob. 151CPCh. 5 - You have an equimolar mixture of the gases SO2 and...Ch. 5 - Methane (CH4) gas flows into a combustion chamber...Ch. 5 - Prob. 154CPCh. 5 - Prob. 155CPCh. 5 - Prob. 156CPCh. 5 - You have a helium balloon at 1.00 atm and 25C. You...Ch. 5 - We state that the ideal gas law tends to hold best...Ch. 5 - You are given an unknown gaseous binary compound...Ch. 5 - Prob. 160CPCh. 5 - In the presence of nitric acid, UO2+ undergoes a...Ch. 5 - Silane, SiH4, is the silicon analogue of methane,...Ch. 5 - Prob. 163IPCh. 5 - Prob. 164IPCh. 5 - Prob. 165MP
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