Organic Chemistry
Organic Chemistry
2nd Edition
ISBN: 9781118452288
Author: David R. Klein
Publisher: WILEY
Question
Book Icon
Chapter 3.3, Problem 4PTS

a)

Interpretation Introduction

Interpretation: More acidic compound to be identified in the following.

Concept Introduction

PKa Value: The pKa value computes the acidity of an acid. This value depends upon the chemical property and identity of the compound.

pKa = - log Ka

Where,

Ka is the measure of strength of an acid. If the acid is strong means Ka on the order of 1010 and weak means Ka on the order of 1050. Strong acid means pKa value is low value and Weak acid means pKa value is high.

If we know which proton is the more acidic and which proton is the less acidic we can make the determination regarding basicity.

The pKa values for some compounds and their conjugate base

Organic Chemistry, Chapter 3.3, Problem 4PTS , additional homework tip  1

Organic Chemistry, Chapter 3.3, Problem 4PTS , additional homework tip  2

Organic Chemistry, Chapter 3.3, Problem 4PTS , additional homework tip  3

Organic Chemistry, Chapter 3.3, Problem 4PTS , additional homework tip  4

Organic Chemistry, Chapter 3.3, Problem 4PTS , additional homework tip  5

Organic Chemistry, Chapter 3.3, Problem 4PTS , additional homework tip  6

Organic Chemistry, Chapter 3.3, Problem 4PTS , additional homework tip  7

Organic Chemistry, Chapter 3.3, Problem 4PTS , additional homework tip  8

b)

Interpretation Introduction

Interpretation: More acidic compound to be identified in the following.

Concept Introduction

PKa Value: The pKa value computes the acidity of an acid. This value depends upon the chemical property and identity of the compound.

pKa = - log Ka

Where,

Ka is the measure of strength of an acid. If the acid is strong means Ka on the order of 1010 and weak means Ka on the order of 1050. Strong acid means pKa value is low value and Weak acid means pKa value is high.

If we know which proton is the more acidic and which proton is the less acidic we can make the determination regarding basicity.

The pKa values for some compounds and their conjugate base

Organic Chemistry, Chapter 3.3, Problem 4PTS , additional homework tip  9

Organic Chemistry, Chapter 3.3, Problem 4PTS , additional homework tip  10

Organic Chemistry, Chapter 3.3, Problem 4PTS , additional homework tip  11

Organic Chemistry, Chapter 3.3, Problem 4PTS , additional homework tip  12

Organic Chemistry, Chapter 3.3, Problem 4PTS , additional homework tip  13

Organic Chemistry, Chapter 3.3, Problem 4PTS , additional homework tip  14

Organic Chemistry, Chapter 3.3, Problem 4PTS , additional homework tip  15

Organic Chemistry, Chapter 3.3, Problem 4PTS , additional homework tip  16

c)

Interpretation Introduction

Interpretation: More acidic compound to be identified in the following.

Concept Introduction

PKa Value: The pKa value computes the acidity of an acid. This value depends upon the chemical property and identity of the compound.

pKa = - log Ka

Where,

Ka is the measure of strength of an acid. If the acid is strong means Ka on the order of 1010 and weak means Ka on the order of 1050. Strong acid means pKa value is low value and Weak acid means pKa value is high.

If we know which proton is the more acidic and which proton is the less acidic we can make the determination regarding basicity.

The pKa values for some compounds and their conjugate base

Organic Chemistry, Chapter 3.3, Problem 4PTS , additional homework tip  17

Organic Chemistry, Chapter 3.3, Problem 4PTS , additional homework tip  18

Organic Chemistry, Chapter 3.3, Problem 4PTS , additional homework tip  19

Organic Chemistry, Chapter 3.3, Problem 4PTS , additional homework tip  20

Organic Chemistry, Chapter 3.3, Problem 4PTS , additional homework tip  21

Organic Chemistry, Chapter 3.3, Problem 4PTS , additional homework tip  22

Organic Chemistry, Chapter 3.3, Problem 4PTS , additional homework tip  23

Organic Chemistry, Chapter 3.3, Problem 4PTS , additional homework tip  24

d)

Interpretation Introduction

Interpretation: More acidic compound to be identified in the following.

Concept Introduction

PKa Value: The pKa value computes the acidity of an acid. This value depends upon the chemical property and identity of the compound.

pKa = - log Ka

Where,

Ka is the measure of strength of an acid. If the acid is strong means Ka on the order of 1010 and weak means Ka on the order of 1050. Strong acid means pKa value is low value and Weak acid means pKa value is high.

If we know which proton is the more acidic and which proton is the less acidic we can make the determination regarding basicity.

The pKa values for some compounds and their conjugate base

Organic Chemistry, Chapter 3.3, Problem 4PTS , additional homework tip  25

Organic Chemistry, Chapter 3.3, Problem 4PTS , additional homework tip  26

Organic Chemistry, Chapter 3.3, Problem 4PTS , additional homework tip  27

Organic Chemistry, Chapter 3.3, Problem 4PTS , additional homework tip  28

Organic Chemistry, Chapter 3.3, Problem 4PTS , additional homework tip  29

Organic Chemistry, Chapter 3.3, Problem 4PTS , additional homework tip  30

Organic Chemistry, Chapter 3.3, Problem 4PTS , additional homework tip  31

Organic Chemistry, Chapter 3.3, Problem 4PTS , additional homework tip  32

e)

Interpretation Introduction

Interpretation: More acidic compound to be identified in the following.

Concept Introduction

PKa Value: The pKa value computes the acidity of an acid. This value depends upon the chemical property and identity of the compound.

pKa = - log Ka

Where,

Ka is the measure of strength of an acid. If the acid is strong means Ka on the order of 1010 and weak means Ka on the order of 1050. Strong acid means pKa value is low value and Weak acid means pKa value is high.

If we know which proton is the more acidic and which proton is the less acidic we can make the determination regarding basicity.

The pKa values for some compounds and their conjugate base

Organic Chemistry, Chapter 3.3, Problem 4PTS , additional homework tip  33

Organic Chemistry, Chapter 3.3, Problem 4PTS , additional homework tip  34

Organic Chemistry, Chapter 3.3, Problem 4PTS , additional homework tip  35

Organic Chemistry, Chapter 3.3, Problem 4PTS , additional homework tip  36

Organic Chemistry, Chapter 3.3, Problem 4PTS , additional homework tip  37

Organic Chemistry, Chapter 3.3, Problem 4PTS , additional homework tip  38

Organic Chemistry, Chapter 3.3, Problem 4PTS , additional homework tip  39

Organic Chemistry, Chapter 3.3, Problem 4PTS , additional homework tip  40

f)

Interpretation Introduction

Interpretation: More acidic compound to be identified in the following.

Concept Introduction

PKa Value: The pKa value computes the acidity of an acid. This value depends upon the chemical property and identity of the compound.

pKa = - log Ka

Where,

Ka is the measure of strength of an acid. If the acid is strong means Ka on the order of 1010 and weak means Ka on the order of 1050. Strong acid means pKa value is low value and Weak acid means pKa value is high.

If we know which proton is the more acidic and which proton is the less acidic we can make the determination regarding basicity.

The pKa values for some compounds and their conjugate base

Organic Chemistry, Chapter 3.3, Problem 4PTS , additional homework tip  41

Organic Chemistry, Chapter 3.3, Problem 4PTS , additional homework tip  42

Organic Chemistry, Chapter 3.3, Problem 4PTS , additional homework tip  43

Organic Chemistry, Chapter 3.3, Problem 4PTS , additional homework tip  44

Organic Chemistry, Chapter 3.3, Problem 4PTS , additional homework tip  45

Organic Chemistry, Chapter 3.3, Problem 4PTS , additional homework tip  46

Organic Chemistry, Chapter 3.3, Problem 4PTS , additional homework tip  47

Organic Chemistry, Chapter 3.3, Problem 4PTS , additional homework tip  48

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