Statistics for Engineers and Scientists
4th Edition
ISBN: 9780073401331
Author: William Navidi Prof.
Publisher: McGraw-Hill Education
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Chapter 3.3, Problem 10E
The conversion of ammonium cyanide to urea is a second-order reaction. This means that the concentration C of ammonium cyanide at time t is given by 1/C = kl + 1/C0, where C0 is the initial concentration and k is the rate constant. Assume the initial concentration is known to be 0.1 mol/L exactly. Assume that time can be measured with negligible uncertainty.
- a. After 45 minutes, the concentration of ammonium cyanide is measured to be 0.0811 ± 0.0005 mol/L. Estimate the rate constant k, and find the uncertainty in the estimate.
- b. Use the result in part (a) to estimate the time when the concentration of ammonium cyanide will be 0.0750 mol/L, and find the uncertainty in this estimate.
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Chapter 3 Solutions
Statistics for Engineers and Scientists
Ch. 3.1 - The boiling point of water is measured four times....Ch. 3.1 - Two thermometers are calibrated by measuring the...Ch. 3.1 - The weight of an object is given as 67.2 0.3 g....Ch. 3.1 - Prob. 4ECh. 3.1 - A person stands on a bathroom scale. The reading...Ch. 3.1 - A person gets on and off a bathroom scale four...Ch. 3.1 - In a hypothetical scenario, the National Institute...Ch. 3.1 - Prob. 8ECh. 3.1 - A new and unknown weight is weighed on the same...Ch. 3.1 - Prob. 10E
Ch. 3.1 - The length of a rod was measured eight times. The...Ch. 3.2 - Assume that X and Y are independent measurements...Ch. 3.2 - The length of a rod is to be measured by a process...Ch. 3.2 - The volume of a cone is given by V = r2h/3, where...Ch. 3.2 - In the article The Worlds Longest Continued Series...Ch. 3.2 - A cylindrical hole is bored through a steel block,...Ch. 3.2 - A force of F = 2.2 0.1 N is applied to a block...Ch. 3.2 - The period T of a simple pendulum is given by...Ch. 3.2 - The specific gravity of a substance is given by G...Ch. 3.2 - Prob. 10ECh. 3.2 - According to Newtons law of cooling, the...Ch. 3.2 - Prob. 12ECh. 3.2 - Nine independent measurements are made of the...Ch. 3.2 - A certain scale has an uncertainty of 3 g and a...Ch. 3.2 - The volume of a rock is measured by placing the...Ch. 3.2 - A student measures the spring constant k of a...Ch. 3.2 - A certain chemical process is run 10 times at a...Ch. 3.2 - An object is weighed four times, and the results,...Ch. 3.2 - Prob. 19ECh. 3.2 - Prob. 20ECh. 3.3 - Find the uncertainty in Y, given that X = 2.0 0.3...Ch. 3.3 - Given that X and Y are related by the given...Ch. 3.3 - The volume of a cone is given by V = r2h/3, where...Ch. 3.3 - Prob. 4ECh. 3.3 - The period T of a simple pendulum is given by...Ch. 3.3 - The change in temperature of an iron bar brought...Ch. 3.3 - The friction velocity F of water flowing through a...Ch. 3.3 - The refractive index n of a piece of glass is...Ch. 3.3 - The density of a rock will be measured by placing...Ch. 3.3 - The conversion of ammonium cyanide to urea is a...Ch. 3.3 - Prob. 11ECh. 3.3 - Prob. 12ECh. 3.3 - The acceleration g due to gravity is estimated by...Ch. 3.3 - Refer to Exercise 4. Assume that T = 298.4 0.2 K....Ch. 3.3 - Refer to Exercise 5. a. Assume g = 9.80 m/s2...Ch. 3.3 - Refer to Exercise 6. Assume that c = 448 J/kgC and...Ch. 3.3 - Prob. 17ECh. 3.3 - Refer to Exercise 8. Assume the critical angle is...Ch. 3.3 - Refer to Exercise 9. Assume that the mass of the...Ch. 3.3 - Prob. 20ECh. 3.4 - Find the uncertainty in U, assuming that X = 10.0 ...Ch. 3.4 - The volume of a cone is given by V = r2h/3, where...Ch. 3.4 - From a fixed point on the ground, the distance to...Ch. 3.4 - Refer to Exercise 10 in Section 3.2. Assume that ...Ch. 3.4 - When air enters a compressor at pressure P1 and...Ch. 3.4 - One way to measure the water content of a soil is...Ch. 3.4 - Prob. 7ECh. 3.4 - Prob. 8ECh. 3.4 - The Beer-Lambert law relates the absorbance A of a...Ch. 3.4 - In the article Temperature-Dependent Optical...Ch. 3.4 - Refer to Exercise 12 in Section 3.2. Assume that 0...Ch. 3.4 - Prob. 12ECh. 3.4 - Archaeologists studying meat storage methods...Ch. 3.4 - Prob. 14ECh. 3.4 - A cylindrical wire of radius R elongates when...Ch. 3.4 - Prob. 16ECh. 3.4 - Refer to Exercise 16. In an experiment to...Ch. 3.4 - The vertical displacement v of a cracked slurry...Ch. 3.4 - The shape of a bacterium can be approximated by a...Ch. 3.4 - Prob. 20ECh. 3.4 - Refer to Exercise 10 in Section 3.2. Assume that ...Ch. 3.4 - Refer to Exercise 5. Assume that P1 = 15.3 0.2...Ch. 3.4 - Refer to Exercise 7. Assume that p = 4.3 0.1 cm...Ch. 3.4 - Prob. 24ECh. 3.4 - Refer to Exercise 12. Estimate n, and find the...Ch. 3.4 - Refer to Exercise 14. Assume that l = 10.0 cm ...Ch. 3.4 - Prob. 27ECh. 3.4 - Refer to Exercise 16. Assume that T0 = 73.1 0.1F,...Ch. 3.4 - Prob. 29ECh. 3.4 - Prob. 30ECh. 3.4 - Prob. 31ECh. 3 - Prob. 1SECh. 3 - Prob. 2SECh. 3 - Prob. 3SECh. 3 - Prob. 4SECh. 3 - Prob. 5SECh. 3 - Let A and B represent two variants (alleles) of...Ch. 3 - The heating capacity of a calorimeter is known to...Ch. 3 - Sixteen independent measurements were made of the...Ch. 3 - If two gases have molar masses M1 and M2, Grahams...Ch. 3 - A piece of plywood is composed of five layers. The...Ch. 3 - The article Effect of Varying Solids Concentration...Ch. 3 - Prob. 13SECh. 3 - Prob. 14SECh. 3 - Prob. 15SECh. 3 - The mean yield from process A is estimated to be...Ch. 3 - The flow rate of water through a cylindrical pipe...Ch. 3 - Prob. 18SECh. 3 - The decomposition of nitrogen dioxide (NO2) into...Ch. 3 - Prob. 20SECh. 3 - A track has the shape of a square capped on two...Ch. 3 - Prob. 22SECh. 3 - Prob. 23SE
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