Chemistry Atoms First2e
2nd Edition
ISBN: 9781947172647
Author: OpenStax
Publisher: OpenStax College
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Textbook Question
Chapter 3, Problem 49E
Using complete subshell notation (
(a)N
(b) Si
(c) Fe
(d) Te
(e) Tb
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Boron, atomic number 5, occurs naturally as two isotopes, 10B and 11B, with natural abundances of 19.9% and 80.1%, respectively.
(a) In what ways do the two isotopes differ from each other? Does the electronic configuration of 10B differ from that of 11B?
(b) Draw the orbital diagram for an atom of 11B. Which electrons are the valence electrons?
(c) Indicate three ways in which the 1s electrons in boron differ from its 2s electrons.
(d) Elemental boron reacts with fluorine to form BF3, a gas. Write a balanced chemical equation for the reaction of solid boron with fluorine gas.
(e) ΔHf° for BF3(g) is -1135.6 kj/mol. Calculate the standard enthalpy change in the reaction of boron with fluorine.
(f) Will the mass percentage of F be the same in 10BF3 and 11BF3? If not, why is that the case?
Boron, atomic number 5, occurs naturally as two isotopes, 10B and 11B, with natural abundances of 19.9% and 80.1%, respectively.(a) In what ways do the two isotopes differ from each other? Does the electronic configuration of 10B differ from that of 11B? (b) Drawthe orbital diagram for an atom of 11B. Which electrons are the valence electrons? (c) Indicate three ways in which the 1s electrons inboron differ from its 2s electrons. (d) Elemental boron reacts with fluorine to form BF3, a gas. Write a balanced chemical equation forthe reaction of solid boron with fluorine gas. (e) ΔHf° for BF31g2 is -1135.6 kJ>mol. Calculate the standard enthalpy change in thereaction of boron with fluorine. (f) Will the mass percentage of F be the same in 10BF3 and 11BF3? If not, why is that the case?
(a) Why do successive IEs of a given element always increase? (b) When the difference between successive IEs of a given element is exceptionally large (for example, between IE1 and IE2 of K), what do we learn about its electron configuration? (c) The bars represent the relative magnitudes of the first five ionization energies of an atom: Identify the element and write its complete electron config uration, assuming it comes from (a) Period 2; (b) Period 3; (c) Period 4.
Chapter 3 Solutions
Chemistry Atoms First2e
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