Organic Chemistry
Organic Chemistry
12th Edition
ISBN: 9781118875766
Author: T. W. Graham Solomons, Craig B. Fryhle, Scott A. Snyder
Publisher: WILEY
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Chapter 3, Problem 3LGP
Interpretation Introduction

Interpretation:

The chemical reactions when the given species encounter the aqueous sodium bicarbonate solution are to be written.

Concept introduction:

Acid–base reactions are the reactions in which the acid reacts with the base and tend to neutralize the effect of each other by producing a salt. In the esterification of 3-methylbutyl ethanoate from acetic acid and 3-methyl-1-butanol in the presence of a sulfuric acid catalyst, the ester portion remains in the organic layer on top, whereas water and alcohol constitute the aqueous inorganic layer below, because ester is less denser than water. The impurities, ethanoic acid, and sulfuric acid are removed by treating it with sodium bicarbonate whereas, alcohol is taken up by water.

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What is the relationship between the value of pKa and the strength of a weak acid?
Formic acid dissociates reversibly according to the following equation. HCOOH(aq) ⇌ HCOO-(aq) + H+(aq) Write the law of mass action for this equilibrium.K = Is the equilibrium constant in (a) a Ka? Briefly explain. If a solution is initially 0.20 mol/L HCOOH and the equilibrium constant in (a) is 1.8 × 10-4, what is the concentration of hydrogen ions at equilibrium? Show your work.           sub parts to be solved Use the value obtained in (c) to find the solution’s pH and pOH at 25 °C. If you were unable to complete (c), you may assume a 0.0030 mol/L concentration of hydrogen ions. Would the addition of sodium formate (NaHCOO) to this solution increase pH? Explain.
Formic acid dissociates reversibly according to the following equation. HCOOH(aq) ⇌ HCOO-(aq) + H+(aq) Write the law of mass action for this equilibrium.K = Is the equilibrium constant in (a) a Ka? Briefly explain. If a solution is initially 0.20 mol/L HCOOH and the equilibrium constant in (a) is 1.8 × 10-4, what is the concentration of hydrogen ions at equilibrium? Show your work.         question 4, 5 need to be solved   4.Use the value obtained in (c) to find the solution’s pH and pOH at 25 °C. If you were unable to complete (c), you may assume a 0.0030 mol/L concentration of hydrogen ions. 5.Would the addition of sodium formate (NaHCOO) to this solution increase pH? Explain.

Chapter 3 Solutions

Organic Chemistry

Ch. 3 - Prob. 11PPCh. 3 - Prob. 12PPCh. 3 - Prob. 13PPCh. 3 - Prob. 14PPCh. 3 - PRACTICE PROBLEM 3.15 Nitro groups have a large...Ch. 3 - PRACTICE PROBLEM 3.16 Your laboratory instructor...Ch. 3 - Prob. 17PPCh. 3 - Prob. 18PPCh. 3 - Prob. 19PPCh. 3 - What is the conjugate base of each of the...Ch. 3 - List the bases you gave as answers to Problem 3.20...Ch. 3 - 3.22 What is the conjugate acid of each of the...Ch. 3 - List the acids you gave as answers to Problem 3.22...Ch. 3 - Rank the following in order of increasing acidity.Ch. 3 - Without consulting tables, select the stronger...Ch. 3 - Designate the Lewis acid and Lewis base in each of...Ch. 3 - Prob. 27PCh. 3 - Prob. 28PCh. 3 - Write an equation, using the curved-arrow...Ch. 3 - 3.30 What reaction will take place if ethyl...Ch. 3 - 3.31 (a) The of formic acid. What is the? (b)...Ch. 3 - Acid HA has pKa=20; acid HB has pKa=10. (a) Which...Ch. 3 - Prob. 33PCh. 3 - 3.34 (a) Arrange the following compounds in order...Ch. 3 - 3.35 Arrange the following compounds in order of...Ch. 3 - 3.36 Arrange the following in order of increasing...Ch. 3 - Prob. 37PCh. 3 - 3.38 Supply the curved arrows necessary for the...Ch. 3 - Glycine is an amino acid that can be obtained from...Ch. 3 - 3.40 Malonic acid, , is a diprotic acid. The for...Ch. 3 - 3.41 The free-energy change, , for the ionization...Ch. 3 - 3.42 At the enthalpy change, , for the ionization...Ch. 3 - The compound at right has (for obvious reasons)...Ch. 3 - 3.44. (a) Given the above sequence of...Ch. 3 - Prob. 45PCh. 3 - Prob. 46PCh. 3 - 3.47 As noted in Table 3.1, the of acetone, , is...Ch. 3 - Formamide (HCONH2) has a pKa of approximately 25....Ch. 3 - List all the chemical species likely to be present...Ch. 3 - Prob. 2LGPCh. 3 - Prob. 3LGPCh. 3 - Prob. 4LGP
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