Concept explainers
(a)
Interpretation:
The ratio of electrostatic energy between the given charges and the ratio of distance in the given statements should be calculated by using the concept of electrostatic energy.
Concept Introduction:
Energy is the capacity to do work or transfer heat where work is the movement of a body using some force. The SI unit of energy is joule (
Electrostatic energy is the potential energy which results from the interaction of charged particles. Oppositely charged particles attract each other and like particles charges repel each other. The magnitude of the resulting electrostatic potential energy is directly proportional to the product of the two charges (
If the charges
(b)
Interpretation:
The ratio of electrostatic energy between the given charges and the ratio of distance in the given statements should be calculated by using the concept of electrostatic energy.
Concept Introduction:
Energy is the capacity to do work or transfer heat where work is the movement of a body using some force. The SI unit of energy is joule (
Electrostatic energy is the potential energy which results from the interaction of charged particles. Oppositely charged particles attract each other and like particles charges repel each other. The magnitude of the resulting electrostatic potential energy is directly proportional to the product of the two charges (
If the charges
Want to see the full answer?
Check out a sample textbook solutionChapter 3 Solutions
Chemistry: Atoms First
- Consider an electron in the N shell. (a) What is the smallest orbital angular momentum it could have? (b) What is the largest orbital angular momentum it could have? Express your answers in terms of h and in SI units. (c) What is the largest orbital angular momentum this electron could have in any chosen direction? Express your answers in terms of h and in SI units. (d) What is the largest spin angular momentum this electron could have in any chosen direction? Express your answers in terms of h and in SI units. (e) For the electron in part (c), what is the ratio of its spin angular momentum in the z-direction to its orbital angular momentum in the z-direction?arrow_forwardThe first ionization energy for rubidium is +403.0 kJ mol¯¹. How much energy (as kJ) would be required to convert 19.10 g of gaseous rubidium to its gaseous +1 monatomic ion at constant temperature?arrow_forwardThe ionization energy of lithium is 520.2 kJ/mole, and the electron affinity of hydrogen is 72.8 kJ/mole.(a) Find the separation distance in LiH at which the Coulomb potential energy equals the energy cost of removing an electron from Li and adding it to H.(b) The measured electric dipole moment of the molecule LiH is 2.00 × 10^−29 C · m. What is the fractional ionic character of LiH?(c) Instead of removing an electron from Li and attaching it to H, we could regard the formation of LiH as occurring by removing an electron from H and attaching it to Li (electron affinity = 59.6 kJ/mole). Why don’t we consider this as the formation process?arrow_forward
- 1. a) Calculate the numerical values of the energies of the first four energy levels in hydrogen in units of both joules (J) and in electron-volts (eV). The first four energy levels are found substituting n = 1, 2, 3, 4 into the equation you found in section (f) above. Show all work. b) Use r = n²ħ²/(e²km) to calculate numerical values for the radii of the first four allowed electron 'orbits' in hydrogen, in units of m. The radius of the 'orbit' closest to the nucleus is called the Bohr radius and is given the symbol ao. (You should notice that each radius is a multiple of the Bohr radius, ie. when n = 1 then r = ao, if n = 2 then r = 2² ao, at n = 3 then r = 9 ao, etc.) 1 2 3 4 c) Summarize your numerical results in the following table; Quantum number n Radius of electron's 'orbit' (m) Electron Energy (J) Electron Energy (eV)arrow_forwardAt large interatomic separations, an alkali halide moleculeMX has a lower energy as two neutral atoms, M + X; atshort separations, the ionic form (M+)(X-) has a lowerenergy. At a certain distance, Rc, the energies of the twoforms become equal, and it is near this distance that theelectron will jump from the metal to the halogen atom during a collision. Because the forces between neutral atomsare weak at large distances, a reasonably good approximation can be made by ignoring any variation in potentialV(R) for the neutral atoms between Rc and R - `. For theions in this distance range, V(R) is dominated by theirCoulomb attraction.(a) Express Rc for the first ionization energy of the metalM and the electron affinity of the halogen X.(b) Calculate Rc for LiF, KBr, and NaCl using data fromAppendix F.arrow_forward2) The ionization energy of potassium is 4.34 eV; the electron affinity of iodine is 3.06 eV. At what separation distance will the KI molecule gain enough Coulomb energy to overcome the energy needed to form the K+ and I ions?arrow_forward
- (a) Calculate the energy in joules of a 3.23 g object moving at a speed of 713 m/s.Ek = J(b) Determine how much greater the electrostatic energy is between charges of +2 and −2 than it is between charges of +1 and −1 (assume that the distance between the charges is the same in each case).1.5 times2.0 times2.5 times3.0 times3.5 times4.0 times4.5 times5.0 timesarrow_forward5. (a) Use the hydrogen-like model z2 (in eV) En --13.6 to calculate the total energy of the three electrons of lithium (Li), which has the electron configuration: 1s? 2s'. The three ionization energies for Li(g) are: IE, = 5.392 ev; IE2 = 75.64 eV; IE = 122.5 ev. With the help of Koopman's theorem, what is the total energy of ropulsion between lithium's three electrons (in kJ mol')?arrow_forward10. Consider two hydrogen atoms. The electron in the first one is in n=1 state, whereas in the second the electron is in the n=3 state. (a) which atom is in the ground state configuration? Why? (b) Which orbital has a larger radius? (c) Which electron is moving faster and why? (d) Which electron has a lower potential energy? (e) Which atom has higher ionization energy? Hint: assume that the radius of the n=3 orbital is =5 rBarrow_forward
- A fundamental relationship of electrostatics states that the en-ergy required to separate opposite charges of magnitudes Q1and Q2 that are the distance dapart is proportional to Q1XQ2/d .Use this relationship and any other factors to explain the fol-lowing observations: (a) the IE₂ of He (Z=2) is morethantwice the IE₁ of H (Z=1); (b) the IE₁ of He is less than twice the IE₁ of H.arrow_forwardThe sum of IE1through IE₄ for Group 4A(14) elements shows a decrease from C to Si, a slight increase from Si to Ge, adecrease from Ge to Sn, and an increase from Sn to Pb. (a) What is the expected trend for IEs down a group? (b) Suggest a reason for the deviations in Group 4A(14).(c) Which group might show even greater deviations?arrow_forwardV7.arrow_forward
- Chemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage LearningChemistry: Principles and PracticeChemistryISBN:9780534420123Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward MercerPublisher:Cengage Learning