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Science Chemistry Organic Chemistry: Principles And Mechanisms

The orbital interaction that would be necessary to generate each sp hybrid orbital from pure AOs is to be drawn by considering the given pair of sp hybrid orbitals. Concept introduction: Any sp-hybridized atom has two sp hybrid orbitals and two unhybridized p orbitals. The two sp hybrid orbitals are aligned along the same axis and point in opposite directions. Mixing of the lobe with the same phase leads to constructive interference, thus increasing the size of the lobe. The other lobe of p orbital having an opposite phase as s orbital leads to destructive interference on that side. The size of the lobe on this side is smaller than the other lobe. The larger lobe shows the overlapping of s and p orbitals with the same phase. The smaller lobe is often omitted entirely for simplicity.

The orbital interaction that would be necessary to generate each sp hybrid orbital from pure AOs is to be drawn by considering the given pair of sp hybrid orbitals. Concept introduction: Any sp-hybridized atom has two sp hybrid orbitals and two unhybridized p orbitals. The two sp hybrid orbitals are aligned along the same axis and point in opposite directions. Mixing of the lobe with the same phase leads to constructive interference, thus increasing the size of the lobe. The other lobe of p orbital having an opposite phase as s orbital leads to destructive interference on that side. The size of the lobe on this side is smaller than the other lobe. The larger lobe shows the overlapping of s and p orbitals with the same phase. The smaller lobe is often omitted entirely for simplicity.

Solution Summary: The author explains the orbital interactions that would be necessary to generate each sp-hybridized atom from pure AOs.

Organic Chemistry: Principles And Mechanisms

Organic Chemistry: Principles And Mechanisms

2nd Edition

ISBN: 9780393630756

Author: KARTY, Joel

Publisher: W.w. Norton & Company,

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Question

Chapter 3, Problem 3.7P

Interpretation Introduction

Interpretation:

The orbital interaction that would be necessary to generate each sp hybrid orbital from pure AOs is to be drawn by considering the given pair of sp hybrid orbitals.

Concept introduction:

Any sp-hybridized atom has two sp hybrid orbitals and two unhybridized p orbitals. The two sp hybrid orbitals are aligned along the same axis and point in opposite directions. Mixing of the lobe with the same phase leads to constructive interference, thus increasing the size of the lobe. The other lobe of p orbital having an opposite phase as s orbital leads to destructive interference on that side. The size of the lobe on this side is smaller than the other lobe. The larger lobe shows the overlapping of s and p orbitals with the same phase. The smaller lobe is often omitted entirely for simplicity.

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Chapter 3, Problem 3.6P

Chapter 3, Problem 3.8P

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Chapter 3 Solutions

Organic Chemistry: Principles And Mechanisms

Ch. 3 - Prob. 3.1P Ch. 3 - Prob. 3.2P Ch. 3 - Prob. 3.3P Ch. 3 - Prob. 3.4P Ch. 3 - Prob. 3.5P Ch. 3 - Prob. 3.6P Ch. 3 - Prob. 3.7P Ch. 3 - Prob. 3.8P Ch. 3 - Prob. 3.9P Ch. 3 - Prob. 3.10P

Ch. 3 - Prob. 3.11P Ch. 3 - Prob. 3.12P Ch. 3 - Prob. 3.13P Ch. 3 - Prob. 3.14P Ch. 3 - Prob. 3.15P Ch. 3 - Prob. 3.16P Ch. 3 - Prob. 3.17P Ch. 3 - Prob. 3.18P Ch. 3 - Prob. 3.19P Ch. 3 - Prob. 3.20P Ch. 3 - Prob. 3.21P Ch. 3 - Prob. 3.22P Ch. 3 - Prob. 3.23P Ch. 3 - Prob. 3.24P Ch. 3 - Prob. 3.25P Ch. 3 - Prob. 3.26P Ch. 3 - Prob. 3.27P Ch. 3 - Prob. 3.28P Ch. 3 - Prob. 3.29P Ch. 3 - Prob. 3.30P Ch. 3 - Prob. 3.31P Ch. 3 - Prob. 3.32P Ch. 3 - Prob. 3.33P Ch. 3 - Prob. 3.34P Ch. 3 - Prob. 3.35P Ch. 3 - Prob. 3.36P Ch. 3 - Prob. 3.37P Ch. 3 - Prob. 3.38P Ch. 3 - Prob. 3.39P Ch. 3 - Prob. 3.40P Ch. 3 - Prob. 3.41P Ch. 3 - Prob. 3.42P Ch. 3 - Prob. 3.43P Ch. 3 - Prob. 3.44P Ch. 3 - Prob. 3.45P Ch. 3 - Prob. 3.46P Ch. 3 - Prob. 3.47P Ch. 3 - Prob. 3.48P Ch. 3 - Prob. 3.49P Ch. 3 - Prob. 3.50P Ch. 3 - Prob. 3.51P Ch. 3 - Prob. 3.52P Ch. 3 - Prob. 3.53P Ch. 3 - Prob. 3.54P Ch. 3 - Prob. 3.55P Ch. 3 - Prob. 3.56P Ch. 3 - Prob. 3.1YT Ch. 3 - Prob. 3.2YT Ch. 3 - Prob. 3.3YT Ch. 3 - Prob. 3.4YT Ch. 3 - Prob. 3.5YT Ch. 3 - Prob. 3.6YT Ch. 3 - Prob. 3.7YT Ch. 3 - Prob. 3.8YT Ch. 3 - Prob. 3.9YT Ch. 3 - Prob. 3.10YT Ch. 3 - Prob. 3.11YT Ch. 3 - Prob. 3.12YT Ch. 3 - Prob. 3.13YT

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