Whether the given statement is true or false has to be checked and also explanation has to be given. Concept Introduction: Chiral center: A tetrahedral atom that is bonded to four different groups is called as chiral center. The most commonly known tetrahedral atom is carbon.

Question

4. (a) Draw all possible isomers of C4H3CI2. (b) Indicate which pairs of compounds are enantiomers of one another. (c) Indicate which pairs of compounds are diastereomers of one another. (d) Indicate which compounds would have optical rotations of 0°. (e) Assign R and S configurations to all chirality centers of the compounds in part (a).

Answer 1

Question

Chapter 3, Problem 3.37P

(a)

Interpretation Introduction

Interpretation:

Whether the given statement is true or false has to be checked and also explanation has to be given.

Concept Introduction:

Chiral center:

A tetrahedral atom that is bonded to four different groups is called as chiral center. The most commonly known tetrahedral atom is carbon.

(b)

Interpretation Introduction

Interpretation:

Whether the given statement is true or false has to be checked and also explanation has to be given.

Concept Introduction:

Chiral center:

A tetrahedral atom that is bonded to four different groups is called as chiral center. The most commonly known tetrahedral atom is carbon.

(c)

Interpretation Introduction

Interpretation:

Whether the given statement is true or false has to be checked and also explanation has to be given.

Concept Introduction:

Chiral center:

A tetrahedral atom that is bonded to four different groups is called as chiral center. The most commonly known tetrahedral atom is carbon.

(d)

Interpretation Introduction

Interpretation:

Whether the given statement is true or false has to be checked and also explanation has to be given.

Concept Introduction:

Chiral center:

A tetrahedral atom that is bonded to four different groups is called as chiral center. The most commonly known tetrahedral atom is carbon.

(e)

Interpretation Introduction

Interpretation:

Whether the given statement is true or false has to be checked and also explanation has to be given.

Concept Introduction:

Chiral center:

A tetrahedral atom that is bonded to four different groups is called as chiral center. The most commonly known tetrahedral atom is carbon.

(f)

Interpretation Introduction

Interpretation:

Whether the given statement is true or false has to be checked and also explanation has to be given.

Concept Introduction:

Chiral center:

A tetrahedral atom that is bonded to four different groups is called as chiral center. The most commonly known tetrahedral atom is carbon.

Meso compound:

It is an achiral compound having two or more chiral centers that also has chiral isomers.

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4. (a) Draw all possible isomers of C4H3CI2. (b) Indicate which pairs of compounds are enantiomers of one another. (c) Indicate which pairs of compounds are diastereomers of one another. (d) Indicate which compounds would have optical rotations of 0°. (e) Assign R and S configurations to all chirality centers of the compounds in part (a).

(a) Identify type of molecules either chiral, achiral, or meso for each compound shown below and (b) Indicate the number of chiral centers in each molecule.

The amino acid threonine has two chiral centers. The stereoisomer found in proteins has the configuration 2S,3R about the two chiral centers. Draw (a) a Fischer projection of this stereoisomer and (b) a three-dimensional representation

Answer 2

Question

Chapter 3, Problem 3.37P

(a)

Interpretation Introduction

Interpretation:

Whether the given statement is true or false has to be checked and also explanation has to be given.

Concept Introduction:

Chiral center:

A tetrahedral atom that is bonded to four different groups is called as chiral center. The most commonly known tetrahedral atom is carbon.

(b)

Interpretation Introduction

Interpretation:

Whether the given statement is true or false has to be checked and also explanation has to be given.

Concept Introduction:

Chiral center:

A tetrahedral atom that is bonded to four different groups is called as chiral center. The most commonly known tetrahedral atom is carbon.

(c)

Interpretation Introduction

Interpretation:

Whether the given statement is true or false has to be checked and also explanation has to be given.

Concept Introduction:

Chiral center:

A tetrahedral atom that is bonded to four different groups is called as chiral center. The most commonly known tetrahedral atom is carbon.

(d)

Interpretation Introduction

Interpretation:

Whether the given statement is true or false has to be checked and also explanation has to be given.

Concept Introduction:

Chiral center:

A tetrahedral atom that is bonded to four different groups is called as chiral center. The most commonly known tetrahedral atom is carbon.

(e)

Interpretation Introduction

Interpretation:

Whether the given statement is true or false has to be checked and also explanation has to be given.

Concept Introduction:

Chiral center:

A tetrahedral atom that is bonded to four different groups is called as chiral center. The most commonly known tetrahedral atom is carbon.

(f)

Interpretation Introduction

Interpretation:

Whether the given statement is true or false has to be checked and also explanation has to be given.

Concept Introduction:

Chiral center:

A tetrahedral atom that is bonded to four different groups is called as chiral center. The most commonly known tetrahedral atom is carbon.

Meso compound:

It is an achiral compound having two or more chiral centers that also has chiral isomers.

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Answer 3

Question

Chapter 3, Problem 3.37P

(a)

Interpretation Introduction

Interpretation:

Whether the given statement is true or false has to be checked and also explanation has to be given.

Concept Introduction:

Chiral center:

A tetrahedral atom that is bonded to four different groups is called as chiral center. The most commonly known tetrahedral atom is carbon.

(b)

Interpretation Introduction

Interpretation:

Whether the given statement is true or false has to be checked and also explanation has to be given.

Concept Introduction:

Chiral center:

A tetrahedral atom that is bonded to four different groups is called as chiral center. The most commonly known tetrahedral atom is carbon.

(c)

Interpretation Introduction

Interpretation:

Whether the given statement is true or false has to be checked and also explanation has to be given.

Concept Introduction:

Chiral center:

A tetrahedral atom that is bonded to four different groups is called as chiral center. The most commonly known tetrahedral atom is carbon.

(d)

Interpretation Introduction

Interpretation:

Whether the given statement is true or false has to be checked and also explanation has to be given.

Concept Introduction:

Chiral center:

A tetrahedral atom that is bonded to four different groups is called as chiral center. The most commonly known tetrahedral atom is carbon.

(e)

Interpretation Introduction

Interpretation:

Whether the given statement is true or false has to be checked and also explanation has to be given.

Concept Introduction:

Chiral center:

A tetrahedral atom that is bonded to four different groups is called as chiral center. The most commonly known tetrahedral atom is carbon.

(f)

Interpretation Introduction

Interpretation:

Whether the given statement is true or false has to be checked and also explanation has to be given.

Concept Introduction:

Chiral center:

A tetrahedral atom that is bonded to four different groups is called as chiral center. The most commonly known tetrahedral atom is carbon.

Meso compound:

It is an achiral compound having two or more chiral centers that also has chiral isomers.

Expert Solution & Answer

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Answer 4

Question

Chapter 3, Problem 3.37P

(a)

Interpretation Introduction

Interpretation:

Whether the given statement is true or false has to be checked and also explanation has to be given.

Concept Introduction:

Chiral center:

A tetrahedral atom that is bonded to four different groups is called as chiral center. The most commonly known tetrahedral atom is carbon.

(b)

Interpretation Introduction

Interpretation:

Whether the given statement is true or false has to be checked and also explanation has to be given.

Concept Introduction:

Chiral center:

A tetrahedral atom that is bonded to four different groups is called as chiral center. The most commonly known tetrahedral atom is carbon.

(c)

Interpretation Introduction

Interpretation:

Whether the given statement is true or false has to be checked and also explanation has to be given.

Concept Introduction:

Chiral center:

A tetrahedral atom that is bonded to four different groups is called as chiral center. The most commonly known tetrahedral atom is carbon.

(d)

Interpretation Introduction

Interpretation:

Whether the given statement is true or false has to be checked and also explanation has to be given.

Concept Introduction:

Chiral center:

A tetrahedral atom that is bonded to four different groups is called as chiral center. The most commonly known tetrahedral atom is carbon.

(e)

Interpretation Introduction

Interpretation:

Whether the given statement is true or false has to be checked and also explanation has to be given.

Concept Introduction:

Chiral center:

A tetrahedral atom that is bonded to four different groups is called as chiral center. The most commonly known tetrahedral atom is carbon.

(f)

Interpretation Introduction

Interpretation:

Whether the given statement is true or false has to be checked and also explanation has to be given.

Concept Introduction:

Chiral center:

A tetrahedral atom that is bonded to four different groups is called as chiral center. The most commonly known tetrahedral atom is carbon.

Meso compound:

It is an achiral compound having two or more chiral centers that also has chiral isomers.

Expert Solution & Answer

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Answer 5

Chapter 3, Problem 3.37P

(a)

Interpretation Introduction

Interpretation:

Whether the given statement is true or false has to be checked and also explanation has to be given.

Concept Introduction:

Chiral center:

A tetrahedral atom that is bonded to four different groups is called as chiral center. The most commonly known tetrahedral atom is carbon.

(b)

Interpretation Introduction

Interpretation:

Whether the given statement is true or false has to be checked and also explanation has to be given.

Concept Introduction:

Chiral center:

A tetrahedral atom that is bonded to four different groups is called as chiral center. The most commonly known tetrahedral atom is carbon.

(c)

Interpretation Introduction

Interpretation:

Whether the given statement is true or false has to be checked and also explanation has to be given.

Concept Introduction:

Chiral center:

A tetrahedral atom that is bonded to four different groups is called as chiral center. The most commonly known tetrahedral atom is carbon.

(d)

Interpretation Introduction

Interpretation:

Whether the given statement is true or false has to be checked and also explanation has to be given.

Concept Introduction:

Chiral center:

A tetrahedral atom that is bonded to four different groups is called as chiral center. The most commonly known tetrahedral atom is carbon.

(e)

Interpretation Introduction

Interpretation:

Whether the given statement is true or false has to be checked and also explanation has to be given.

Concept Introduction:

Chiral center:

A tetrahedral atom that is bonded to four different groups is called as chiral center. The most commonly known tetrahedral atom is carbon.

(f)

Interpretation Introduction

Interpretation:

Whether the given statement is true or false has to be checked and also explanation has to be given.

Concept Introduction:

Chiral center:

A tetrahedral atom that is bonded to four different groups is called as chiral center. The most commonly known tetrahedral atom is carbon.

Meso compound:

It is an achiral compound having two or more chiral centers that also has chiral isomers.

Answer 6

Chapter 3, Problem 3.37P

(a)

Interpretation Introduction

Interpretation:

Whether the given statement is true or false has to be checked and also explanation has to be given.

Concept Introduction:

Chiral center:

A tetrahedral atom that is bonded to four different groups is called as chiral center. The most commonly known tetrahedral atom is carbon.

Answer 7

Chapter 3, Problem 3.37P

(a)

Interpretation Introduction

Interpretation:

Whether the given statement is true or false has to be checked and also explanation has to be given.

Concept Introduction:

Chiral center:

A tetrahedral atom that is bonded to four different groups is called as chiral center. The most commonly known tetrahedral atom is carbon.

Answer 8

(b)

Interpretation Introduction

Interpretation:

Whether the given statement is true or false has to be checked and also explanation has to be given.

Concept Introduction:

Chiral center:

A tetrahedral atom that is bonded to four different groups is called as chiral center. The most commonly known tetrahedral atom is carbon.

Answer 9

(b)

Interpretation Introduction

Interpretation:

Whether the given statement is true or false has to be checked and also explanation has to be given.

Concept Introduction:

Chiral center:

A tetrahedral atom that is bonded to four different groups is called as chiral center. The most commonly known tetrahedral atom is carbon.

Answer 10

(c)

Interpretation Introduction

Interpretation:

Whether the given statement is true or false has to be checked and also explanation has to be given.

Concept Introduction:

Chiral center:

A tetrahedral atom that is bonded to four different groups is called as chiral center. The most commonly known tetrahedral atom is carbon.

Answer 11

(c)

Interpretation Introduction

Interpretation:

Whether the given statement is true or false has to be checked and also explanation has to be given.

Concept Introduction:

Chiral center:

A tetrahedral atom that is bonded to four different groups is called as chiral center. The most commonly known tetrahedral atom is carbon.

Answer 12

(d)

Interpretation Introduction

Interpretation:

Whether the given statement is true or false has to be checked and also explanation has to be given.

Concept Introduction:

Chiral center:

A tetrahedral atom that is bonded to four different groups is called as chiral center. The most commonly known tetrahedral atom is carbon.

Answer 13

(d)

Interpretation Introduction

Interpretation:

Whether the given statement is true or false has to be checked and also explanation has to be given.

Concept Introduction:

Chiral center:

A tetrahedral atom that is bonded to four different groups is called as chiral center. The most commonly known tetrahedral atom is carbon.

Answer 14

(e)

Interpretation Introduction

Interpretation:

Whether the given statement is true or false has to be checked and also explanation has to be given.

Concept Introduction:

Chiral center:

A tetrahedral atom that is bonded to four different groups is called as chiral center. The most commonly known tetrahedral atom is carbon.

Answer 15

(e)

Interpretation Introduction

Interpretation:

Whether the given statement is true or false has to be checked and also explanation has to be given.

Concept Introduction:

Chiral center:

A tetrahedral atom that is bonded to four different groups is called as chiral center. The most commonly known tetrahedral atom is carbon.

Answer 16

(f)

Interpretation Introduction

Interpretation:

Whether the given statement is true or false has to be checked and also explanation has to be given.

Concept Introduction:

Chiral center:

A tetrahedral atom that is bonded to four different groups is called as chiral center. The most commonly known tetrahedral atom is carbon.

Meso compound:

It is an achiral compound having two or more chiral centers that also has chiral isomers.

Answer 17

(f)

Interpretation Introduction

Interpretation:

Whether the given statement is true or false has to be checked and also explanation has to be given.

Concept Introduction:

Chiral center:

A tetrahedral atom that is bonded to four different groups is called as chiral center. The most commonly known tetrahedral atom is carbon.

Meso compound:

It is an achiral compound having two or more chiral centers that also has chiral isomers.

Answer 18

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Answer 29

Ch. 3.2 - Prob. 3.1P Ch. 3.3 - Assign priorities to the groups in each set. (a)...Ch. 3.3 - Prob. 3.3P Ch. 3.4 - Following are stereorepresentations for the four...Ch. 3.4 - Prob. 3.5P Ch. 3.4 - Prob. 3.6P Ch. 3.5 - How many stereoisomers exist for...Ch. 3.5 - How many stereoisomers exist for...Ch. 3.7 - Prob. 3.9P Ch. 3.7 - Prob. 3.10P

Whether the given statement is true or false has to be checked and also explanation has to be given. Concept Introduction: Chiral center: A tetrahedral atom that is bonded to four different groups is called as chiral center. The most commonly known tetrahedral atom is carbon.

Solution Summary: The author explains that a tetrahedral atom that is bonded to four different groups is called as chiral center.

Interpretation:

Whether the given statement is true or false has to be checked and also explanation has to be given.

Concept Introduction:

Chiral center:

A tetrahedral atom that is bonded to four different groups is called as chiral center. The most commonly known tetrahedral atom is carbon.

Interpretation:

Whether the given statement is true or false has to be checked and also explanation has to be given.

Concept Introduction:

Chiral center:

A tetrahedral atom that is bonded to four different groups is called as chiral center. The most commonly known tetrahedral atom is carbon.

Interpretation:

Whether the given statement is true or false has to be checked and also explanation has to be given.

Concept Introduction:

Chiral center:

A tetrahedral atom that is bonded to four different groups is called as chiral center. The most commonly known tetrahedral atom is carbon.

Interpretation:

Whether the given statement is true or false has to be checked and also explanation has to be given.

Concept Introduction:

Chiral center:

A tetrahedral atom that is bonded to four different groups is called as chiral center. The most commonly known tetrahedral atom is carbon.

Interpretation:

Whether the given statement is true or false has to be checked and also explanation has to be given.

Concept Introduction:

Chiral center:

A tetrahedral atom that is bonded to four different groups is called as chiral center. The most commonly known tetrahedral atom is carbon.

Chapter 3 Solutions

Whether the given statement is true or false has to be checked and also explanation has to be given. Concept Introduction: Chiral center: A tetrahedral atom that is bonded to four different groups is called as chiral center. The most commonly known tetrahedral atom is carbon.

Solution Summary: The author explains that a tetrahedral atom that is bonded to four different groups is called as chiral center.

Interpretation: Whether the given statement is true or false has to be checked and also explanation has to be given. Concept Introduction: Chiral center: A tetrahedral atom that is bonded to four different groups is called as chiral center. The most commonly known tetrahedral atom is carbon.

Interpretation: Whether the given statement is true or false has to be checked and also explanation has to be given. Concept Introduction: Chiral center: A tetrahedral atom that is bonded to four different groups is called as chiral center. The most commonly known tetrahedral atom is carbon.

Interpretation: Whether the given statement is true or false has to be checked and also explanation has to be given. Concept Introduction: Chiral center: A tetrahedral atom that is bonded to four different groups is called as chiral center. The most commonly known tetrahedral atom is carbon.

Interpretation: Whether the given statement is true or false has to be checked and also explanation has to be given. Concept Introduction: Chiral center: A tetrahedral atom that is bonded to four different groups is called as chiral center. The most commonly known tetrahedral atom is carbon.

Interpretation: Whether the given statement is true or false has to be checked and also explanation has to be given. Concept Introduction: Chiral center: A tetrahedral atom that is bonded to four different groups is called as chiral center. The most commonly known tetrahedral atom is carbon.

Chapter 3 Solutions

Interpretation:

Whether the given statement is true or false has to be checked and also explanation has to be given.

Concept Introduction:

Chiral center:

A tetrahedral atom that is bonded to four different groups is called as chiral center. The most commonly known tetrahedral atom is carbon.

Interpretation:

Whether the given statement is true or false has to be checked and also explanation has to be given.

Concept Introduction:

Chiral center:

A tetrahedral atom that is bonded to four different groups is called as chiral center. The most commonly known tetrahedral atom is carbon.

Interpretation:

Whether the given statement is true or false has to be checked and also explanation has to be given.

Concept Introduction:

Chiral center:

A tetrahedral atom that is bonded to four different groups is called as chiral center. The most commonly known tetrahedral atom is carbon.

Interpretation:

Whether the given statement is true or false has to be checked and also explanation has to be given.

Concept Introduction:

Chiral center:

A tetrahedral atom that is bonded to four different groups is called as chiral center. The most commonly known tetrahedral atom is carbon.

Interpretation:

Whether the given statement is true or false has to be checked and also explanation has to be given.

Concept Introduction:

Chiral center:

A tetrahedral atom that is bonded to four different groups is called as chiral center. The most commonly known tetrahedral atom is carbon.