Organic Chemistry (6th Edition)
6th Edition
ISBN: 9781260119107
Author: Janice Gorzynski Smith
Publisher: McGraw Hill Education
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Chapter 26.7, Problem 18P
Interpretation Introduction
(a)
Interpretation: The
Concept introduction: The characteristic bond of glycoside is
Interpretation Introduction
(b)
Interpretation: The aglycon and monosaccharides formed by the hydrolysis of rebaudioside A are to be predicted.
Concept introduction: The characteristic bond of glycoside is
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A triglyceride can be optically active if it contains two or more different fatty acids.(a) Draw the structure of an optically active triglyceride containing one equivalent of myristic acid and two equivalentsof oleic acid
A triglyceride can be optically active if it contains two or more different fatty acids.(a) Draw the structure of an optically active triglyceride containing one equivalent of myristic acid and two equivalentsof oleic acid.(b) Draw the structure of an optically inactive triglyceride with the same fatty acid composition.
a) Label all the O atoms that are part of a glycoside in rebaudioside A. Rebaudioside A, marketed under the trade name Truvia, is a sweet glycoside obtained from the stevia plant, which has been used for centuries in Paraguay to sweeten foods. (b) The alcohol or phenol formed from the hydrolysis of a glycoside is called an aglycon. What aglycon and monosaccharides are formed by the hydrolysis of rebaudioside A?
Chapter 26 Solutions
Organic Chemistry (6th Edition)
Ch. 26.2 - Prob. 1PCh. 26.2 - Prob. 2PCh. 26.2 - Label each stereogenic center as R or S. a. b. c....Ch. 26.2 - Convert the ball-and-stick model to a Fischer...Ch. 26.2 - Prob. 5PCh. 26.2 - Prob. 6PCh. 26.3 - Prob. 7PCh. 26.3 - Prob. 8PCh. 26.4 - Prob. 9PCh. 26.4 - Prob. 10P
Ch. 26.6 - Prob. 11PCh. 26.6 - Prob. 12PCh. 26.6 - Prob. 13PCh. 26.6 - Prob. 14PCh. 26.6 - Prob. 15PCh. 26.7 - Prob. 16PCh. 26.7 - Draw a stepwise mechanism for the following...Ch. 26.7 - Prob. 18PCh. 26.8 - Prob. 19PCh. 26.9 - Prob. 20PCh. 26.9 - Prob. 21PCh. 26.9 - Draw the products formed when D-arabinose is...Ch. 26.9 - Prob. 23PCh. 26.10 - Prob. 24PCh. 26.10 - Prob. 25PCh. 26.10 - Prob. 26PCh. 26.10 - Prob. 27PCh. 26.11 - Prob. 28PCh. 26.11 - Prob. 29PCh. 26.12 - Prob. 30PCh. 26.12 - Prob. 31PCh. 26.13 - Prob. 32PCh. 26.13 - Prob. 33PCh. 26.13 - Problem-28.35
Draw the structures of the...Ch. 26.13 - Prob. 35PCh. 26 - 28.37 Convert each ball-and-stick model to a...Ch. 26 - Prob. 37PCh. 26 - Prob. 38PCh. 26 - 28.40 Convert each compound to a Fischer...Ch. 26 - Prob. 40PCh. 26 - Prob. 41PCh. 26 - 28.43 Draw a Haworth projection for each compound...Ch. 26 - Prob. 43PCh. 26 - 28.45 Draw both pyranose anomers of each...Ch. 26 - Prob. 45PCh. 26 - 28.50 Draw the products formed when D-altrose is...Ch. 26 - 28.58 Draw a stepwise mechanism for the following...Ch. 26 - Prob. 62PCh. 26 - Prob. 63PCh. 26 - Prob. 64PCh. 26 - Prob. 65PCh. 26 - Prob. 66PCh. 26 - Prob. 67PCh. 26 - Prob. 68PCh. 26 - Prob. 69PCh. 26 - Prob. 70P
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- From Figure 18.7, arrange the following substances in order of increasing percentage of unsaturated fatty acids: chicken fat, beef fat, corn oil, butter, and sunflower oil.arrow_forwardAmygdalin is a toxic component in the pits of bitter almonds, peaches, and apricots. Q.) Name the two monosaccharide units in amygdalin and describe the glycosidic bond by which they are joined.arrow_forwardDraw the structure of: (a) a polysaccharide formed by joining D-mannose units in 1->4-ß-glycosidic linkages; (b) a polysaccharide formed by joining D-glucose units in 1->6-a-glycosidic linkages. The polysaccharide in (b) is dextran, a component of dental plaque.arrow_forward
- Crocin, which occurs naturally in crocus and gardenia flowers, is primarily responsible for the color of saffron. (a) What lipid and monosaccharides are formed by the hydrolysis of crocin? (b) Classify the lipid as a monoterpenoid, diperpenoid, etc., and locate the isoprene units.arrow_forwardCellobiose, a disaccharide obtained by the hydrolysis of cellulose, is composed of two glucose units joined together in a 1→4-β-glycoside bond. What is the structure of cellobiose?arrow_forwardDefine Glycoside Hydrolysis ?arrow_forward
- 3. A(n) is a molecule that is synthesized in one part of the body and has an effect in a different part. A) fatty acid B) enzyme C) hormone D) vitamin 4. DNA is a double-stranded nucleic acid that exists as a double helix. Which is responsible for holding the double helix of DNA together? A) Phosphodiester bonds between complementary base pairs on each strand B) B-N-glycosidic linkages between the sugar-phosphate backbone of each strand C) Disulfide bonds between the cysteine residues on each strand D) Hydrogen bonding between complementary bases on each strand 5. Which type of inhibitor is most likely to bind somewhere other than an enzyme's active site? A) competitive B) lock and key C) noncompetitive D) substrate 6. The compound shown below is best classified as what type of lipid? HO, A) Triacylglycerol B) Soap C) Fatty acid D) Waxarrow_forwardWhat is the type of glycosidic bond here?arrow_forwardMonosaccharides are cyclic hemiacetals that can react with alcohols to form acetals. The bond between the anomeric carbon atom of the monosaccharide and the oxygen atom of the -OR group is called a glycosidic bond. The name of the linkage contains the designation alpha (a) or beta (B) (from the anomeric carbon in the glycosidic bond) and the carbon numbers for the carbons from the two sugars. For this example, the linkage is an a-1,4 glycosidic bond. Н НО HO اب تاب است H OH H OH -OH Н Н OH H + OH HO a anomer CH₂OH H Н H О OH H2C OH Н H Classify the glycosidic linkage in the disaccharide. Н OH Н H OH OH OH - HO Н H HO OH OH Н CH₂OH H -OH H OH он H H -OH Н OH an a glycosidic bond Н OH + H2O о о о о В-1,6 a-1,6 a-1,1 B-1,5 I DON'T KNOW YET submitarrow_forward
- Draw the structure of: (a) a polysaccharide formed by joining D-mannose units in 1→4-β- glycosidic linkages; (b) a polysaccharide formed by joining D-glucose units in 1→6-α- glycosidic linkages. The polysaccharide in (b) is dextran, a component of dental plaque.arrow_forwardWhat glycosidic bond is present?arrow_forwardCholic acid is secreted in bile as an amide linked to the aminogroup of glycine. This cholic acid–amino acid combination acts asan emulsifying agent to disperse lipids in the intestines for easierdigestion. Draw the structure of the cholic acid–glycine combination,and explain why it is a good emulsifying agent.arrow_forward
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