Concept explainers
(a)
Interpretation:
The reagents that are needed to convert acetophenone
Concept introduction:
The structural representation of sugar molecule in cyclic form is known as Haworth projection. A compound in which the hydroxyl group of first and sixth carbon atom is on the same side is known as
Answer to Problem 25.63P
The reagent that is required to convert acetophenone
Explanation of Solution
The given compound is shown below.
Figure 1
Carbonyl compounds react with secondary
Figure 2
Thus, the reagent that is required to convert acetophenone
The reagent that is required to convert acetophenone
(b)
Interpretation:
The reagents that are needed to convert acetophenone
Concept introduction:
The structural representation of sugar molecule in cyclic form is known as Haworth projection. A compound in which the hydroxyl group of first and sixth carbon atom is on the same side is known as
Answer to Problem 25.63P
The reagent that is required to convert acetophenone
Explanation of Solution
The given compound is shown below.
Figure 3
Carbonyl compounds react with primary amines in the presence of mild acid to form imine. Therefore, the reaction that shows the conversion of acetophenone into the given compound is shown below.
Figure 4
Thus, the reagent that is required to convert acetophenone
The reagent that is required to convert acetophenone
(c)
Interpretation:
The reagents that are needed to convert acetophenone
Concept introduction:
The structural representation of sugar molecule in cyclic form is known as Haworth projection. A compound in which the hydroxyl group of first and sixth carbon atom is on the same side is known as
Answer to Problem 25.63P
he reagents that are required to convert acetophenone
Explanation of Solution
The given compound is shown below.
Figure 5
Carbonyl compounds react with ammonia to form imine. The conversion of imine to amines takes place by using selective reducing agent called sodium cyanoborohydride. Therefore, the reaction that shows the conversion of acetophenone into the given compound is shown below.
Figure 6
Thus, reagent that is required to convert acetophenone
The reagents that are required to convert acetophenone
(d)
Interpretation:
The reagents that are needed to convert acetophenone
Concept introduction:
The structural representation of sugar molecule in cyclic form is known as Haworth projection. A compound in which the hydroxyl group of first and sixth carbon atom is on the same side is known as
Answer to Problem 25.63P
The reagents that are required to convert acetophenone
Explanation of Solution
The given compound is shown below.
Figure 7
The reaction that shows the conversion of acetophenone into the given compound is shown below.
Figure 8
The given reaction is a two step process. The first step involves reduction of carbonyl compounds into alcohol by using sodium borohydride. This results in the formation of
Thus, the reagents that are required to convert acetophenone
The reagents that are required to convert acetophenone
(e)
Interpretation:
The reagents that are needed to convert acetophenone
Concept introduction:
The structural representation of sugar molecule in cyclic form is known as Haworth projection. A compound in which the hydroxyl group of first and sixth carbon atom is on the same side is known as
Answer to Problem 25.63P
The reagents that are required to convert acetophenone
Explanation of Solution
The given compound is shown below.
Figure 9
The reaction that shows the conversion of acetophenone into the given compound is shown below.
Figure 10
The first step involves reduction of carbonyl compounds into alcohol by using sodium borohydride. This results in the formation of
Thus, the reagents that are required to convert acetophenone
The reagents that are required to convert acetophenone
(f)
Interpretation:
The reagents that are needed to convert acetophenone
Concept introduction:
The structural representation of sugar molecule in cyclic form is known as Haworth projection. A compound in which the hydroxyl group of first and sixth carbon atom is on the same side is known as
Answer to Problem 25.63P
The reagent that is required to convert acetophenone
Explanation of Solution
The given compound is shown below.
Figure 11
The reaction that shows the conversion of acetophenone into the given compound is shown below.
Figure 12
The first step is the bromination step which results in the formation of
Thus, reagent that is required to convert acetophenone
The reagent that is required to convert acetophenone
Want to see more full solutions like this?
Chapter 25 Solutions
Organic Chemistry
- Draw the organic product(s) formed when CH3CH₂CH₂OH is treated with each reagent. a. H₂SO4 d. HBr g. TsCl, pyridine b. NaH h. [1] NaH; [2] CH₂CH₂Br e. SOCI₂, pyridine f. PBr3 c. HCI + ZnCl₂ Hint: NaH deprotonates the alcohol forming an alkoxidearrow_forwardDraw the products formed when each compound is treated with CH;CH,COCI, AICI3. CH(CH3)2 N(CH)2 Br CH3 CH(CH)2 a. b. C. d. е.arrow_forwardRank the compounds in each group in order of increasing water solubility. a. (CH3),CH, CH3OCH2CH3, CH3CH;CH,CH3, CH;CH,CH2OH b. Brarrow_forward
- Draw the product formed when pentanal (CH3 CH₂ CH₂ CH₂ CHO) is treated with each reagent. With some reagents, no reaction occurs. a. NaBH4, CH3OH b. [1] LiAiH4: [2] H₂O c. H₂, Pd-C d. PCC e. Na₂Cr₂O7, H₂SO4, H₂O f. Ag₂O, NH4OH g. [1] CH3 MgBr; [2] H₂O h. [1] C6H5 Li: [2] H₂O i. [1] (CH3)2 CuLi; [2] H₂O J. [1] HC=CNa; [2] H₂O k. [1] CH 3 C=CLI; [2] H₂O 1. The product in (a), then TBDMS-CI, imidazolearrow_forwardDraw the products formed when phenol(C6H5OH) is treated with each reagent. Give an explanation. c. CH3CH2Cl, AlCl3 l. product in (c), then KMnO4arrow_forward48. Which set of reagents would accomplish this conversion H. H. CH3OH with H* as a catalyst NaH followed by CH3OH CH3ONA followed CH3OH CH3ONA followed by CH3Br a. b. C. d.arrow_forward
- Draw the products formed when p-methylaniline (p-CH3C6H4NH2) is treated with each reagent. a. HCl b. CH3COCl c. (CH3CO)2O d. excess CH3I e. (CH3)2C = O f. CH3COCl, AlCl3 g. CH3CO2H h. NaNO2, HCl i. Part (b), then CH3COCl, AlCl j. CH3CHO, NaBH3CNarrow_forwardDraw the organic product(s) formed when CH3CH2CH2OH is treated with each reagent. a.H2SO4 b.NaH c.HCl + ZnCl2 d.HBr e.SOCl2, pyridine f.PBr3 g.TsCl, pyridine h. [1] NaH; [2] CH3CH2Br [1] i.TsCl, pyridine; [2] NaSH j.POCl3, pyridinearrow_forwardWhich product is formed by the reaction of the compound shown with NaBH4? A. B. OH OH 1. NaBH4 2. H3O+ C. D. OH OHarrow_forward
- Which molecule is hydrolyzed most slowly with aqueous NaOH? D. C. В. A.arrow_forwardSynthesize each compound from cyclohexanol using any other organic or inorganic compounds. CH,OH a. g. (Each cyclohexane ring must come from cyclohexanol.) COOH b. d. h. сно CHs (Each cyclohexane ring must come from cyclohexanol.)arrow_forwardWhat alkenes are formed when each alcohol is dehydrated with TSOH? Label the major product when a mixture results. OH Xom OH a. OH b. CH₂CH3 OH C. d. CH₂CH₂CH₂CH₂OH e.arrow_forward
- ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage LearningChemistryChemistryISBN:9781259911156Author:Raymond Chang Dr., Jason Overby ProfessorPublisher:McGraw-Hill EducationPrinciples of Instrumental AnalysisChemistryISBN:9781305577213Author:Douglas A. Skoog, F. James Holler, Stanley R. CrouchPublisher:Cengage Learning
- Organic ChemistryChemistryISBN:9780078021558Author:Janice Gorzynski Smith Dr.Publisher:McGraw-Hill EducationChemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage LearningElementary Principles of Chemical Processes, Bind...ChemistryISBN:9781118431221Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. BullardPublisher:WILEY