Chapter 25, Problem 25.62P

Interpretation Introduction

(a)

Interpretation: The products formed by the reaction of given compound with excess ${\text{CH}}_{\text{3}}\text{I}$ followed by ${\text{Ag}}_2\text{O}$ and heat are to be drawn.

Concept introduction: Amines on reaction with excess ${\text{CH}}_{\text{3}}\text{I}$ followed by ${\text{Ag}}_{\text{2}}\text{O}$ undergo Hofmann elimination. The major product formed by the Hofmann elimination of amines is alkene. The removal of proton from $\text{β}$ carbon atom of ammonium salt leads to the formation of $\text{π}$ bond of the alkene. The mechanism followed in the Hofmann elimination is $\text{E2}$.

Answer to Problem 25.62P

The products formed by the reaction of given compound with excess ${\text{CH}}_{\text{3}}\text{I}$ followed by ${\text{Ag}}_2\text{O}$ are shown below:

Explanation of Solution

Amines on reaction with excess ${\text{CH}}_{\text{3}}\text{I}$ followed by ${\text{Ag}}_{\text{2}}\text{O}$ undergo Hofmann elimination. The major product formed by the Hofmann elimination of amines is alkene. The removal of proton from $\text{β}$ carbon atom of ammonium salt leads to the formation of $\text{π}$ bond of the alkene. The mechanism followed in the Hofmann elimination is $\text{E2}$.

The products formed by the reaction of given compound with excess ${\text{CH}}_{\text{3}}\text{I}$ followed by ${\text{Ag}}_2\text{O}$ are shown below.

Figure 1

Conclusion

The products formed by the reaction of given compound with excess ${\text{CH}}_{\text{3}}\text{I}$ followed by ${\text{Ag}}_2\text{O}$ are shown in Figure 1.

Interpretation Introduction

(b)

Interpretation: The products formed by the reaction of given compound with excess ${\text{CH}}_{\text{3}}\text{I}$ followed by ${\text{Ag}}_2\text{O}$ and heat are to be drawn.

Concept introduction: Amines on reaction with excess ${\text{CH}}_{\text{3}}\text{I}$ followed by ${\text{Ag}}_{\text{2}}\text{O}$ undergo Hofmann elimination. The major product formed by the Hofmann elimination of amines is alkene. The removal of proton from $\text{β}$ carbon atom of ammonium salt leads to the formation of $\text{π}$ bond of the alkene. The mechanism followed in the Hofmann elimination is $\text{E2}$.

Answer to Problem 25.62P

The products formed by the reaction of given compound with excess ${\text{CH}}_{\text{3}}\text{I}$ followed by ${\text{Ag}}_2\text{O}$ are shown below:

Explanation of Solution

Amines on reaction with excess ${\text{CH}}_{\text{3}}\text{I}$ followed by ${\text{Ag}}_{\text{2}}\text{O}$ undergo Hofmann elimination. The major product formed by the Hofmann elimination of amines is alkene. The removal of proton from $\text{β}$ carbon atom of ammonium salt leads to the formation of $\text{π}$ bond of the alkene. The mechanism followed in the Hofmann elimination is $\text{E2}$.

The products formed by the reaction of given compound with excess ${\text{CH}}_{\text{3}}\text{I}$ followed by ${\text{Ag}}_2\text{O}$ are shown below.

Figure 2

Conclusion

The products formed by the reaction of given compound with excess ${\text{CH}}_{\text{3}}\text{I}$ followed by ${\text{Ag}}_2\text{O}$ are shown in Figure 2.

Interpretation Introduction

(c)

Interpretation: The products formed by the reaction of given compound with excess ${\text{CH}}_{\text{3}}\text{I}$ followed by ${\text{Ag}}_2\text{O}$ and heat are to be drawn.

Concept introduction: Amines on reaction with excess ${\text{CH}}_{\text{3}}\text{I}$ followed by ${\text{Ag}}_{\text{2}}\text{O}$ undergo Hofmann elimination. The major product formed by the Hofmann elimination of amines is alkene. The removal of proton from $\text{β}$ carbon atom of ammonium salt leads to the formation of $\text{π}$ bond of the alkene. The mechanism followed in the Hofmann elimination is $\text{E2}$.

Answer to Problem 25.62P

The products formed by the reaction of given compound with excess ${\text{CH}}_{\text{3}}\text{I}$ followed by ${\text{Ag}}_2\text{O}$ are shown below:

Explanation of Solution

Amines on reaction with excess ${\text{CH}}_{\text{3}}\text{I}$ followed by ${\text{Ag}}_{\text{2}}\text{O}$ undergo Hofmann elimination. The major product formed by the Hofmann elimination of amines is alkene. The removal of proton from $\text{β}$ carbon atom of ammonium salt leads to the formation of $\text{π}$ bond of the alkene. The mechanism followed in the Hofmann elimination is $\text{E2}$.

The products formed by the reaction of given compound with excess ${\text{CH}}_{\text{3}}\text{I}$ followed by ${\text{Ag}}_2\text{O}$ are shown below.

Figure 3

Conclusion

The products formed by the reaction of given compound with excess ${\text{CH}}_{\text{3}}\text{I}$ followed by ${\text{Ag}}_2\text{O}$ are shown in Figure 3.

Interpretation Introduction

(d)

Interpretation: The products formed by the reaction of given compound with excess ${\text{CH}}_{\text{3}}\text{I}$ followed by ${\text{Ag}}_2\text{O}$ and heat are to be drawn.

Concept introduction: Amines on reaction with excess ${\text{CH}}_{\text{3}}\text{I}$ followed by ${\text{Ag}}_{\text{2}}\text{O}$ undergo Hofmann elimination. The major product formed by the Hofmann elimination of amines is alkene. The removal of proton from $\text{β}$ carbon atom of ammonium salt leads to the formation of $\text{π}$ bond of the alkene. The mechanism followed in the Hofmann elimination is $\text{E2}$.

Answer to Problem 25.62P

The products formed by the reaction of given compound with excess ${\text{CH}}_{\text{3}}\text{I}$ followed by ${\text{Ag}}_2\text{O}$ are shown below:

Explanation of Solution

Amines on reaction with excess ${\text{CH}}_{\text{3}}\text{I}$ followed by ${\text{Ag}}_{\text{2}}\text{O}$ undergo Hofmann elimination. The major product formed by the Hofmann elimination of amines is alkene. The removal of proton from $\text{β}$ carbon atom of ammonium salt leads to the formation of $\text{π}$ bond of the alkene. The mechanism followed in the Hofmann elimination is $\text{E2}$.

The products formed by the reaction of given compound with excess ${\text{CH}}_{\text{3}}\text{I}$ followed by ${\text{Ag}}_2\text{O}$ are shown below.

Figure 4

Conclusion

The products formed by the reaction of given compound with excess ${\text{CH}}_{\text{3}}\text{I}$ followed by ${\text{Ag}}_2\text{O}$ are shown in Figure 4.

Interpretation Introduction

(e)

Interpretation: The products formed by the reaction of given compound with excess ${\text{CH}}_{\text{3}}\text{I}$ followed by ${\text{Ag}}_2\text{O}$ and heat are to be drawn.

Concept introduction: Amines on reaction with excess ${\text{CH}}_{\text{3}}\text{I}$ followed by ${\text{Ag}}_{\text{2}}\text{O}$ undergo Hofmann elimination. The major product formed by the Hofmann elimination of amines is alkene. The removal of proton from $\text{β}$ carbon atom of ammonium salt leads to the formation of $\text{π}$ bond of the alkene. The mechanism followed in the Hofmann elimination is $\text{E2}$.

Answer to Problem 25.62P

The products formed by the reaction of given compound with excess ${\text{CH}}_{\text{3}}\text{I}$ followed by ${\text{Ag}}_2\text{O}$ are shown below:

Explanation of Solution

Amines on reaction with excess ${\text{CH}}_{\text{3}}\text{I}$ followed by ${\text{Ag}}_{\text{2}}\text{O}$ undergo Hofmann elimination. The major product formed by the Hofmann elimination of amines is alkene. The removal of proton from $\text{β}$ carbon atom of ammonium salt leads to the formation of $\text{π}$ bond of the alkene. The mechanism followed in the Hofmann elimination is $\text{E2}$.

The products formed by the reaction of given compound with excess ${\text{CH}}_{\text{3}}\text{I}$ followed by ${\text{Ag}}_2\text{O}$ are shown below.

Figure 5

Conclusion

The products formed by the reaction of given compound with excess ${\text{CH}}_{\text{3}}\text{I}$ followed by ${\text{Ag}}_2\text{O}$ are shown in Figure 5.