(a)
Interpretation: The products formed by the reaction of given compound with excess
Concept introduction:
Answer to Problem 25.62P
The products formed by the reaction of given compound with excess
Explanation of Solution
Amines on reaction with excess
The products formed by the reaction of given compound with excess
Figure 1
The products formed by the reaction of given compound with excess
(b)
Interpretation: The products formed by the reaction of given compound with excess
Concept introduction: Amines on reaction with excess
Answer to Problem 25.62P
The products formed by the reaction of given compound with excess
Explanation of Solution
Amines on reaction with excess
The products formed by the reaction of given compound with excess
Figure 2
The products formed by the reaction of given compound with excess
(c)
Interpretation: The products formed by the reaction of given compound with excess
Concept introduction: Amines on reaction with excess
Answer to Problem 25.62P
The products formed by the reaction of given compound with excess
Explanation of Solution
Amines on reaction with excess
The products formed by the reaction of given compound with excess
Figure 3
The products formed by the reaction of given compound with excess
(d)
Interpretation: The products formed by the reaction of given compound with excess
Concept introduction: Amines on reaction with excess
Answer to Problem 25.62P
The products formed by the reaction of given compound with excess
Explanation of Solution
Amines on reaction with excess
The products formed by the reaction of given compound with excess
Figure 4
The products formed by the reaction of given compound with excess
(e)
Interpretation: The products formed by the reaction of given compound with excess
Concept introduction: Amines on reaction with excess
Answer to Problem 25.62P
The products formed by the reaction of given compound with excess
Explanation of Solution
Amines on reaction with excess
The products formed by the reaction of given compound with excess
Figure 5
The products formed by the reaction of given compound with excess
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Chapter 25 Solutions
Organic Chemistry
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- Which amines cannot be prepared by a Gabriel synthesis? Explain your choices. NH2 NH2 NH2 а. b. C. d.arrow_forwardWhat products are formed when the amine below reacts with HC1? CH,CH,CH,-N- -N-CH,CH,CH-CH,CH;CH, A) CH;CH,CH, NH, + CH,CICH,CH;CH;CH;CH, B) CH,CH,CH,- CH,CH CH,CH,CH,CH, + CI C) CH,CH,CH,-N-CH,CH-CH-CH,CH,CH, H,CI D) CH,CH,CH, N-CH,CH,CH,CHCH,CH, + CI"arrow_forwardWhat carboxylic acid and amine are needed to synthesize the pain reliever phenacetin? Phenacetin was once a component of the over-the-counter pain reliever APC (aspirin, phenacetin, caffeine), but it is no longer used because of its kidney toxicity.arrow_forward
- Determine which producevthe least basic primary amine 1. NaN3 2.H2/Pd Br А. H2/Pd,C 'NO2 Br 1. NaCN/HCI 2.H2/Pd,C С. D. A and C B.arrow_forwardAssign a common name to each of the following amines. 17-16 a. CH3-CH-CH3 NH2 b. H2N-CH2-CH,-CH2-CH; c. CH3-CH2-Ņ-CH,-CH3 ČH,-CH3 d. CH3-CH2-CH2–NH-CH-CH3 ČH3arrow_forwardReactions of aldehydes and ketones with amines and amine derivatives a. Draw reaction with a primary amine forms an imine. Hydrazine and hydroxylamine can also be used; they form a hydrazone and an oxime, respectively. b. Draw reaction with a secondary amine forms an enamine.arrow_forward
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