General, Organic, & Biological Chemistry
3rd Edition
ISBN: 9780073511245
Author: Janice Gorzynski Smith Dr.
Publisher: McGraw-Hill Education
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Chapter 24.3, Problem 24.4P
Interpretation Introduction
Interpretation:
The energy required for the phosphorylation of fructose-6-phosphate needs to be determined.
Concept introduction:
For a coupled reaction, the amount of energy involved in the reaction is sum of amount of energies involved in the reactions with the help of which the coupled reaction is obtained. When the energy is released in the reaction, the energy change is reported as negative value. When the energy is absorbed in the reaction, the energy is reported as a positive value
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Why guanosine triphosphate (GTP) is important in cellbioenergetics ?
Glycerol kinase catalyzes the phosphorylation of glycerol from ATP, yielding glycerol-3-phosphate and ADP. The standard state free energy for hydrolysis of glycerol-3-
phosphate is -9.20 kj/mol and for the hydrolysis of ATP is-30.5 kJ/mol.
Calculate the standard-state free energy change and equilibrium constant for the glycerol kinase reaction at 37 *C.
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The standard free energy change (ΔG°') for hydrolysis of fructose-l,6-bisphosphate (FBP) to fructose-6-phosphate (F-6-P) and Pi is -16.7 kJ/mol:
FBP + H2O → Fructose-6-P + Pi
The standard free energy change (ΔG°') for ATP hydrolysis is -30.5 kJ/mol:
ATP + H2O → ADP + Pi
a
What is the standard free energy change for the phosphofructokinase reaction:
ATP + Fructose-6-phosphate → ADP + FBP
ΔG°' = -13.8 kJ/mol
b
What is the equilibrium constant for this reaction at 25.0 °C?
K'eq =
Chapter 24 Solutions
General, Organic, & Biological Chemistry
Ch. 24.2 - Analyze the following reaction by considering the...Ch. 24.2 - Prob. 24.2PCh. 24.3 - Prob. 24.3PCh. 24.3 - Prob. 24.4PCh. 24.3 - Prob. 24.5PCh. 24.3 - Prob. 24.6PCh. 24.3 - Prob. 24.7PCh. 24.3 - Prob. 24.8PCh. 24.4 - Prob. 24.9PCh. 24.4 - Prob. 24.10P
Ch. 24.4 - Prob. 24.11PCh. 24.5 - Prob. 24.12PCh. 24.5 - Prob. 24.13PCh. 24.5 - Prob. 24.14PCh. 24.6 - Prob. 24.15PCh. 24.7 - Prob. 24.16PCh. 24.7 - Prob. 24.17PCh. 24.7 - Prob. 24.18PCh. 24.7 - Prob. 24.19PCh. 24.7 - Use the number of molecules of ATP formed from the...Ch. 24.7 - Prob. 24.21PCh. 24.8 - Prob. 24.22PCh. 24.8 - Prob. 24.23PCh. 24.8 - Prob. 24.24PCh. 24.8 - Prob. 24.25PCh. 24.9 - Prob. 24.26PCh. 24.9 - Prob. 24.27PCh. 24.9 - Prob. 24.28PCh. 24 - Analyze each reaction by considering the...Ch. 24 - Analyze each reaction by considering the...Ch. 24 - Prob. 24.31PCh. 24 - Prob. 24.32PCh. 24 - Prob. 24.33PCh. 24 - Prob. 24.34PCh. 24 - Prob. 24.35PCh. 24 - Prob. 24.36PCh. 24 - Prob. 24.37PCh. 24 - Prob. 24.38PCh. 24 - Glucose is completely metabolized to six molecules...Ch. 24 - Why is glycolysis described as an anaerobic...Ch. 24 - Write the overall equation with key coenzymes for...Ch. 24 - Prob. 24.42PCh. 24 - Prob. 24.43PCh. 24 - Prob. 24.44PCh. 24 - Consider the aerobic and anaerobic avenues of...Ch. 24 - Prob. 24.46PCh. 24 - Prob. 24.47PCh. 24 - Prob. 24.48PCh. 24 - Prob. 24.49PCh. 24 - Prob. 24.50PCh. 24 - Prob. 24.51PCh. 24 - Prob. 24.52PCh. 24 - Prob. 24.53PCh. 24 - Prob. 24.54PCh. 24 - Prob. 24.55PCh. 24 - Prob. 24.56PCh. 24 - Prob. 24.57PCh. 24 - Prob. 24.58PCh. 24 - Prob. 24.59PCh. 24 - Prob. 24.60PCh. 24 - Prob. 24.61PCh. 24 - Prob. 24.62PCh. 24 - Prob. 24.63PCh. 24 - Prob. 24.64PCh. 24 - Prob. 24.65PCh. 24 - Prob. 24.66PCh. 24 - Prob. 24.67PCh. 24 - Fill in the boxes with the number of moles of each...Ch. 24 - Prob. 24.69PCh. 24 - Prob. 24.70PCh. 24 - Prob. 24.71PCh. 24 - Prob. 24.72PCh. 24 - Prob. 24.73PCh. 24 - Prob. 24.74PCh. 24 - Prob. 24.75PCh. 24 - Prob. 24.76PCh. 24 - What is the difference between ketogenic and...Ch. 24 - Prob. 24.78PCh. 24 - Prob. 24.79PCh. 24 - Draw the structure of the keto acid formed by the...Ch. 24 - Draw the products formed in each transamination...Ch. 24 - Prob. 24.82PCh. 24 - Prob. 24.83PCh. 24 - Prob. 24.84PCh. 24 - What metabolic intermediate is formed from the...Ch. 24 - What metabolic intermediate is formed from the...Ch. 24 - Prob. 24.87PCh. 24 - Prob. 24.88PCh. 24 - Prob. 24.89PCh. 24 - What is the cause of the pain and cramping in a...Ch. 24 - Prob. 24.91PCh. 24 - Prob. 24.92PCh. 24 - Prob. 24.93PCh. 24 - Prob. 24.94PCh. 24 - Prob. 24.95PCh. 24 - Prob. 24.96PCh. 24 - What type of enzyme would catalyze the conversion...Ch. 24 - Prob. 24.98PCh. 24 - Prob. 24.99CPCh. 24 - Prob. 24.100CPCh. 24 - Prob. 24.101CPCh. 24 - Prob. 24.102CP
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