Organic Chemistry (6th Edition)
Organic Chemistry (6th Edition)
6th Edition
ISBN: 9781260119107
Author: Janice Gorzynski Smith
Publisher: McGraw Hill Education
Question
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Chapter 24.1, Problem 1P
Interpretation Introduction

(a)

Interpretation: Product of the given coupling reaction is to be predicted.

Concept introduction: Organocuprate reagents (R2CuLi) react with halides of organic compounds, RX to form coupling products. Only one alkyl group of the organocuprate reagent is transferred to form the product, while the other becomes part of reaction’s by-product.

Interpretation Introduction

(b)

Interpretation: Product of the coupling reaction is to be predicted.

Concept introduction: Organocuprate reagents (R2CuLi) react with halides of organic compounds RX to form coupling products.

Only one alkyl group of the organocuprate reagent is transferred to form the product, while the other becomes part of reaction’s by-product.

Interpretation Introduction

(c)

Interpretation: Product of the coupling reaction is to be predicted.

Concept introduction: Organocuprate reagents (R2CuLi) react with halides of organic compounds RX to form coupling products.

Only one alkyl group of the organocuprate reagent is transferred to form the product, while the other becomes part of reaction’s by-product.

Interpretation Introduction

(d)

Interpretation: Product of the coupling reaction is to be predicted.

Concept introduction: Organocuprate reagents (R2CuLi) react with halides of organic compounds RX to form coupling products.

Only one alkyl group of the organocuprate reagent is transferred to form the product, while the other becomes part of reaction’s by-product.

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Draw a stepwise mechanism for the sulfonation of an alkyl benzene such as A to form asubstituted benzenesulfonic acid B. Treatment of B with base forms a sodium salt C that canbe used as a synthetic detergent to clean away dirt.
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Draw a stepwise mechanism for the following reduction.

Chapter 24 Solutions

Organic Chemistry (6th Edition)

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