(a) Interpretation: The structure of coordinate complex [ FeBr ( ox ) 2 ] 2 − needs to be determined. Concept introduction: The coordinate complex is formed by the reaction of metal ions which are electron deficient with ligands which are electron rich. The structure of the coordinate complex is drawn in such a way that metal ion is always placed at the center. The metal ion is than surrounded by ligands which can be negatively charged or neutral. The shape or geometry of the complex can be determined by number of ligands surrounded by a metal ion.

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Answer 1

Question

Chapter 24, Problem 7E

Interpretation Introduction

(a)

Interpretation:

The structure of coordinate complex [FeBr( ox)2]2− needs to be determined.

Concept introduction:

The coordinate complex is formed by the reaction of metal ions which are electron deficient with ligands which are electron rich. The structure of the coordinate complex is drawn in such a way that metal ion is always placed at the center. The metal ion is than surrounded by ligands which can be negatively charged or neutral. The shape or geometry of the complex can be determined by number of ligands surrounded by a metal ion.

Interpretation Introduction

(b)

Interpretation:

The structure of coordinate complex [CoBr4( NH 3 )2]− needs to be determined.

Concept introduction:

The coordinate complex is formed by the reaction of metal ions which are electron deficient with ligands which are electron rich. The structure of the coordinate complex is drawn in such a way that metal ion is always placed at the center. The metal ion is than surrounded by ligands which can be negatively charged or neutral. The shape or geometry of the complex can be determined by number of ligands surrounded by a metal ion.

Interpretation Introduction

(c)

Interpretation:

The structure of coordinate complex [Cu(EDTA)]2− needs to be determined.

Concept introduction:

The coordinate complex is formed by the reaction of metal ions which are electron deficient with ligands which are electron rich. The structure of the coordinate complex is drawn in such a way that metal ion is always placed at the center. The metal ion is than surrounded by ligands which can be negatively charged or neutral. The shape or geometry of the complex can be determined by number of ligands surrounded by a metal ion.

Interpretation Introduction

(d)

Interpretation:

The structure of coordinate complex [CrBr2( H 2 O)4]+ needs to be determined.

Concept introduction:

The coordinate complex is formed by the reaction of metal ions which are electron deficient with ligands which are electron rich. The structure of the coordinate complex is drawn in such a way that metal ion is always placed at the center. The metal ion is than surrounded by ligands which can be negatively charged or neutral. The shape or geometry of the complex can be determined by number of ligands surrounded by a metal ion.

Interpretation Introduction

(e)

Interpretation:

The structure of coordinate complex [PtBr6]2− needs to be determined.

Concept introduction:

The coordinate complex is formed by the reaction of metal ions which are electron deficient with ligands which are electron rich. The structure of the coordinate complex is drawn in such a way that metal ion is always placed at the center. The metal ion is than surrounded by ligands which can be negatively charged or neutral. The shape or geometry of the complex can be determined by number of ligands surrounded by a metal ion.

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Hi, what is the product of this reaction, and how to balance it? Thank you [Co(OH2)6](NO3)2+NaHCO3+H2O2--> ??

Consider the reactions 1. [Cr(H2O)6]** + [C©CI(NH3)s]* → [Co(NH3)s(H2O)]²* + [CrCl(H2O)s]** 2. [Fe(CN)6]* + [Mo(CN)s]-→ [Fe(CN)6]³¯ + [Mo(CN)8]* Which one of the following is the correct statement? (i) Both involve an inner sphere mechanism (ii) Both involve an outer sphere mechanism (iii) Reaction 1 follows inner sphere and reaction 2 follows outer sphere mechanism (iv) Reaction 1 follows outer sphere and reaction 2 follows inner sphere mechanism (A) i (B) ii (C) iv (D) ii

Why is [Fe(OH2)6]3+ prepared in an acidic solution? A. It is a Bronsted acid in aqueous solution B. It is stabilized against reduction in acid C. It is not soluble in water at pH = 7.0 D. All of the choices

Answer 2

Question

Chapter 24, Problem 7E

Interpretation Introduction

(a)

Interpretation:

The structure of coordinate complex [FeBr( ox)2]2− needs to be determined.

Concept introduction:

The coordinate complex is formed by the reaction of metal ions which are electron deficient with ligands which are electron rich. The structure of the coordinate complex is drawn in such a way that metal ion is always placed at the center. The metal ion is than surrounded by ligands which can be negatively charged or neutral. The shape or geometry of the complex can be determined by number of ligands surrounded by a metal ion.

Interpretation Introduction

(b)

Interpretation:

The structure of coordinate complex [CoBr4( NH 3 )2]− needs to be determined.

Concept introduction:

The coordinate complex is formed by the reaction of metal ions which are electron deficient with ligands which are electron rich. The structure of the coordinate complex is drawn in such a way that metal ion is always placed at the center. The metal ion is than surrounded by ligands which can be negatively charged or neutral. The shape or geometry of the complex can be determined by number of ligands surrounded by a metal ion.

Interpretation Introduction

(c)

Interpretation:

The structure of coordinate complex [Cu(EDTA)]2− needs to be determined.

Concept introduction:

The coordinate complex is formed by the reaction of metal ions which are electron deficient with ligands which are electron rich. The structure of the coordinate complex is drawn in such a way that metal ion is always placed at the center. The metal ion is than surrounded by ligands which can be negatively charged or neutral. The shape or geometry of the complex can be determined by number of ligands surrounded by a metal ion.

Interpretation Introduction

(d)

Interpretation:

The structure of coordinate complex [CrBr2( H 2 O)4]+ needs to be determined.

Concept introduction:

The coordinate complex is formed by the reaction of metal ions which are electron deficient with ligands which are electron rich. The structure of the coordinate complex is drawn in such a way that metal ion is always placed at the center. The metal ion is than surrounded by ligands which can be negatively charged or neutral. The shape or geometry of the complex can be determined by number of ligands surrounded by a metal ion.

Interpretation Introduction

(e)

Interpretation:

The structure of coordinate complex [PtBr6]2− needs to be determined.

Concept introduction:

The coordinate complex is formed by the reaction of metal ions which are electron deficient with ligands which are electron rich. The structure of the coordinate complex is drawn in such a way that metal ion is always placed at the center. The metal ion is than surrounded by ligands which can be negatively charged or neutral. The shape or geometry of the complex can be determined by number of ligands surrounded by a metal ion.

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Answer 3

Question

Chapter 24, Problem 7E

Interpretation Introduction

(a)

Interpretation:

The structure of coordinate complex [FeBr( ox)2]2− needs to be determined.

Concept introduction:

The coordinate complex is formed by the reaction of metal ions which are electron deficient with ligands which are electron rich. The structure of the coordinate complex is drawn in such a way that metal ion is always placed at the center. The metal ion is than surrounded by ligands which can be negatively charged or neutral. The shape or geometry of the complex can be determined by number of ligands surrounded by a metal ion.

Interpretation Introduction

(b)

Interpretation:

The structure of coordinate complex [CoBr4( NH 3 )2]− needs to be determined.

Concept introduction:

The coordinate complex is formed by the reaction of metal ions which are electron deficient with ligands which are electron rich. The structure of the coordinate complex is drawn in such a way that metal ion is always placed at the center. The metal ion is than surrounded by ligands which can be negatively charged or neutral. The shape or geometry of the complex can be determined by number of ligands surrounded by a metal ion.

Interpretation Introduction

(c)

Interpretation:

The structure of coordinate complex [Cu(EDTA)]2− needs to be determined.

Concept introduction:

The coordinate complex is formed by the reaction of metal ions which are electron deficient with ligands which are electron rich. The structure of the coordinate complex is drawn in such a way that metal ion is always placed at the center. The metal ion is than surrounded by ligands which can be negatively charged or neutral. The shape or geometry of the complex can be determined by number of ligands surrounded by a metal ion.

Interpretation Introduction

(d)

Interpretation:

The structure of coordinate complex [CrBr2( H 2 O)4]+ needs to be determined.

Concept introduction:

The coordinate complex is formed by the reaction of metal ions which are electron deficient with ligands which are electron rich. The structure of the coordinate complex is drawn in such a way that metal ion is always placed at the center. The metal ion is than surrounded by ligands which can be negatively charged or neutral. The shape or geometry of the complex can be determined by number of ligands surrounded by a metal ion.

Interpretation Introduction

(e)

Interpretation:

The structure of coordinate complex [PtBr6]2− needs to be determined.

Concept introduction:

The coordinate complex is formed by the reaction of metal ions which are electron deficient with ligands which are electron rich. The structure of the coordinate complex is drawn in such a way that metal ion is always placed at the center. The metal ion is than surrounded by ligands which can be negatively charged or neutral. The shape or geometry of the complex can be determined by number of ligands surrounded by a metal ion.

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Answer 4

Question

Chapter 24, Problem 7E

Interpretation Introduction

(a)

Interpretation:

The structure of coordinate complex [FeBr( ox)2]2− needs to be determined.

Concept introduction:

The coordinate complex is formed by the reaction of metal ions which are electron deficient with ligands which are electron rich. The structure of the coordinate complex is drawn in such a way that metal ion is always placed at the center. The metal ion is than surrounded by ligands which can be negatively charged or neutral. The shape or geometry of the complex can be determined by number of ligands surrounded by a metal ion.

Interpretation Introduction

(b)

Interpretation:

The structure of coordinate complex [CoBr4( NH 3 )2]− needs to be determined.

Concept introduction:

The coordinate complex is formed by the reaction of metal ions which are electron deficient with ligands which are electron rich. The structure of the coordinate complex is drawn in such a way that metal ion is always placed at the center. The metal ion is than surrounded by ligands which can be negatively charged or neutral. The shape or geometry of the complex can be determined by number of ligands surrounded by a metal ion.

Interpretation Introduction

(c)

Interpretation:

The structure of coordinate complex [Cu(EDTA)]2− needs to be determined.

Concept introduction:

The coordinate complex is formed by the reaction of metal ions which are electron deficient with ligands which are electron rich. The structure of the coordinate complex is drawn in such a way that metal ion is always placed at the center. The metal ion is than surrounded by ligands which can be negatively charged or neutral. The shape or geometry of the complex can be determined by number of ligands surrounded by a metal ion.

Interpretation Introduction

(d)

Interpretation:

The structure of coordinate complex [CrBr2( H 2 O)4]+ needs to be determined.

Concept introduction:

The coordinate complex is formed by the reaction of metal ions which are electron deficient with ligands which are electron rich. The structure of the coordinate complex is drawn in such a way that metal ion is always placed at the center. The metal ion is than surrounded by ligands which can be negatively charged or neutral. The shape or geometry of the complex can be determined by number of ligands surrounded by a metal ion.

Interpretation Introduction

(e)

Interpretation:

The structure of coordinate complex [PtBr6]2− needs to be determined.

Concept introduction:

The coordinate complex is formed by the reaction of metal ions which are electron deficient with ligands which are electron rich. The structure of the coordinate complex is drawn in such a way that metal ion is always placed at the center. The metal ion is than surrounded by ligands which can be negatively charged or neutral. The shape or geometry of the complex can be determined by number of ligands surrounded by a metal ion.

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Answer 5

Chapter 24, Problem 7E

Interpretation Introduction

(a)

Interpretation:

The structure of coordinate complex [FeBr( ox)2]2− needs to be determined.

Concept introduction:

The coordinate complex is formed by the reaction of metal ions which are electron deficient with ligands which are electron rich. The structure of the coordinate complex is drawn in such a way that metal ion is always placed at the center. The metal ion is than surrounded by ligands which can be negatively charged or neutral. The shape or geometry of the complex can be determined by number of ligands surrounded by a metal ion.

Interpretation Introduction

(b)

Interpretation:

The structure of coordinate complex [CoBr4( NH 3 )2]− needs to be determined.

Concept introduction:

The coordinate complex is formed by the reaction of metal ions which are electron deficient with ligands which are electron rich. The structure of the coordinate complex is drawn in such a way that metal ion is always placed at the center. The metal ion is than surrounded by ligands which can be negatively charged or neutral. The shape or geometry of the complex can be determined by number of ligands surrounded by a metal ion.

Interpretation Introduction

(c)

Interpretation:

The structure of coordinate complex [Cu(EDTA)]2− needs to be determined.

Concept introduction:

The coordinate complex is formed by the reaction of metal ions which are electron deficient with ligands which are electron rich. The structure of the coordinate complex is drawn in such a way that metal ion is always placed at the center. The metal ion is than surrounded by ligands which can be negatively charged or neutral. The shape or geometry of the complex can be determined by number of ligands surrounded by a metal ion.

Interpretation Introduction

(d)

Interpretation:

The structure of coordinate complex [CrBr2( H 2 O)4]+ needs to be determined.

Concept introduction:

The coordinate complex is formed by the reaction of metal ions which are electron deficient with ligands which are electron rich. The structure of the coordinate complex is drawn in such a way that metal ion is always placed at the center. The metal ion is than surrounded by ligands which can be negatively charged or neutral. The shape or geometry of the complex can be determined by number of ligands surrounded by a metal ion.

Interpretation Introduction

(e)

Interpretation:

The structure of coordinate complex [PtBr6]2− needs to be determined.

Concept introduction:

The coordinate complex is formed by the reaction of metal ions which are electron deficient with ligands which are electron rich. The structure of the coordinate complex is drawn in such a way that metal ion is always placed at the center. The metal ion is than surrounded by ligands which can be negatively charged or neutral. The shape or geometry of the complex can be determined by number of ligands surrounded by a metal ion.

Answer 6

Chapter 24, Problem 7E

Interpretation Introduction

(a)

Interpretation:

The structure of coordinate complex [FeBr( ox)2]2− needs to be determined.

Concept introduction:

The coordinate complex is formed by the reaction of metal ions which are electron deficient with ligands which are electron rich. The structure of the coordinate complex is drawn in such a way that metal ion is always placed at the center. The metal ion is than surrounded by ligands which can be negatively charged or neutral. The shape or geometry of the complex can be determined by number of ligands surrounded by a metal ion.

Answer 7

Chapter 24, Problem 7E

Interpretation Introduction

(a)

Interpretation:

The structure of coordinate complex [FeBr( ox)2]2− needs to be determined.

Concept introduction:

The coordinate complex is formed by the reaction of metal ions which are electron deficient with ligands which are electron rich. The structure of the coordinate complex is drawn in such a way that metal ion is always placed at the center. The metal ion is than surrounded by ligands which can be negatively charged or neutral. The shape or geometry of the complex can be determined by number of ligands surrounded by a metal ion.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The structure of coordinate complex [CoBr4( NH 3 )2]− needs to be determined.

Concept introduction:

The coordinate complex is formed by the reaction of metal ions which are electron deficient with ligands which are electron rich. The structure of the coordinate complex is drawn in such a way that metal ion is always placed at the center. The metal ion is than surrounded by ligands which can be negatively charged or neutral. The shape or geometry of the complex can be determined by number of ligands surrounded by a metal ion.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The structure of coordinate complex [CoBr4( NH 3 )2]− needs to be determined.

Concept introduction:

The coordinate complex is formed by the reaction of metal ions which are electron deficient with ligands which are electron rich. The structure of the coordinate complex is drawn in such a way that metal ion is always placed at the center. The metal ion is than surrounded by ligands which can be negatively charged or neutral. The shape or geometry of the complex can be determined by number of ligands surrounded by a metal ion.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The structure of coordinate complex [Cu(EDTA)]2− needs to be determined.

Concept introduction:

The coordinate complex is formed by the reaction of metal ions which are electron deficient with ligands which are electron rich. The structure of the coordinate complex is drawn in such a way that metal ion is always placed at the center. The metal ion is than surrounded by ligands which can be negatively charged or neutral. The shape or geometry of the complex can be determined by number of ligands surrounded by a metal ion.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The structure of coordinate complex [Cu(EDTA)]2− needs to be determined.

Concept introduction:

The coordinate complex is formed by the reaction of metal ions which are electron deficient with ligands which are electron rich. The structure of the coordinate complex is drawn in such a way that metal ion is always placed at the center. The metal ion is than surrounded by ligands which can be negatively charged or neutral. The shape or geometry of the complex can be determined by number of ligands surrounded by a metal ion.

Answer 12

Interpretation Introduction

(d)

Interpretation:

The structure of coordinate complex [CrBr2( H 2 O)4]+ needs to be determined.

Concept introduction:

The coordinate complex is formed by the reaction of metal ions which are electron deficient with ligands which are electron rich. The structure of the coordinate complex is drawn in such a way that metal ion is always placed at the center. The metal ion is than surrounded by ligands which can be negatively charged or neutral. The shape or geometry of the complex can be determined by number of ligands surrounded by a metal ion.

Answer 13

Interpretation Introduction

(d)

Interpretation:

The structure of coordinate complex [CrBr2( H 2 O)4]+ needs to be determined.

Concept introduction:

The coordinate complex is formed by the reaction of metal ions which are electron deficient with ligands which are electron rich. The structure of the coordinate complex is drawn in such a way that metal ion is always placed at the center. The metal ion is than surrounded by ligands which can be negatively charged or neutral. The shape or geometry of the complex can be determined by number of ligands surrounded by a metal ion.

Answer 14

Interpretation Introduction

(e)

Interpretation:

The structure of coordinate complex [PtBr6]2− needs to be determined.

Concept introduction:

The coordinate complex is formed by the reaction of metal ions which are electron deficient with ligands which are electron rich. The structure of the coordinate complex is drawn in such a way that metal ion is always placed at the center. The metal ion is than surrounded by ligands which can be negatively charged or neutral. The shape or geometry of the complex can be determined by number of ligands surrounded by a metal ion.

Answer 15

Interpretation Introduction

(e)

Interpretation:

The structure of coordinate complex [PtBr6]2− needs to be determined.

Concept introduction:

The coordinate complex is formed by the reaction of metal ions which are electron deficient with ligands which are electron rich. The structure of the coordinate complex is drawn in such a way that metal ion is always placed at the center. The metal ion is than surrounded by ligands which can be negatively charged or neutral. The shape or geometry of the complex can be determined by number of ligands surrounded by a metal ion.

Answer 16

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Answer 17

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Answer 18

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Answer 19

Ch. 24 - Prob. 1E Ch. 24 - Prob. 2E Ch. 24 - Prob. 3E Ch. 24 - Write appropriate formulas for the following. a....Ch. 24 - Prob. 5E Ch. 24 - Prob. 6E Ch. 24 - Prob. 7E Ch. 24 - Prob. 8E Ch. 24 - Prob. 9E Ch. 24 - Prob. 10E

Solution Summary: The author explains that the coordinate complex is formed by the reaction of metal ions which are electron deficient with ligands.

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Chapter 24 Solutions