Organic Chemistry
Organic Chemistry
9th Edition
ISBN: 9781305080485
Author: John E. McMurry
Publisher: Cengage Learning
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Chapter 23.SE, Problem 48AP
Interpretation Introduction

a)

Organic Chemistry, Chapter 23.SE, Problem 48AP , additional homework tip  1

Interpretation:

Whether trimethylacetaldehyde undergoes aldol self-condensation reaction or not is to be stated. The product formed, if the reaction is successful, is also to be shown.

Concept introduction:

Aldehydes and ketones with α-hydrogen undergo a base catalyzed carbonyl condensation reaction in aldol condensation. In this reaction two molecules of the reactant combine by forming a bond between α-carbon of one molecule and the carbonyl carbon within the same molecule or of the second molecule.

To state:

Whether trimethylacetaldehyde undergoes aldol self-condensation reaction or not.

To show:

The product formed, if the reaction is successful.

Expert Solution
Check Mark

Answer to Problem 48AP

Trimethylacetaldehyde does not undergo aldol self-condensation reaction. The reaction is not successful.

Explanation of Solution

The requirement of aldol reaction is the aldehyde or ketone should have α-hydrogen atom. Trimethylacetaldehyde does not possess α-hydrogen atom. Hence the reaction is not successful.

Conclusion

Trimethylacetaldehyde does not undergo aldol self-condensation reaction. The reaction is not successful.

Interpretation Introduction

b)

Organic Chemistry, Chapter 23.SE, Problem 48AP , additional homework tip  2

Interpretation:

Whether cyclobutanone undergoes aldol self-condensation reaction or not is to be stated. The product formed, if the reaction is successful, is also to be shown.

Concept introduction:

Aldehydes and ketones with α-hydrogen undergo a base catalyzed carbonyl condensation reaction in aldol condensation. In this reaction two molecules of the reactant combine by forming a bond between α-carbon of one molecule and the carbonyl carbon within the same molecule or of the second molecule.

To state:

Whether cyclobutanone undergoes aldol self-condensation reaction or not.

To show:

The product formed, if the reaction is successful.

Expert Solution
Check Mark

Answer to Problem 48AP

Cyclobutanone undergoes aldol self-condensation reaction. The product formed is

Organic Chemistry, Chapter 23.SE, Problem 48AP , additional homework tip  3

Explanation of Solution

The requirement of aldol reaction is the aldehyde or ketone should have α-hydrogen atom. Cyclobutanone has α-hydrogen atoms. Hence the reaction is successful. Two molecules of cyclobutanone condense in the presence of a base to yield an aldol which dehydrates to give α, β-unsaturated ketone.

Organic Chemistry, Chapter 23.SE, Problem 48AP , additional homework tip  4

Conclusion

Cyclobutanone undergoes aldol self-condensation reaction. The product formed is

Organic Chemistry, Chapter 23.SE, Problem 48AP , additional homework tip  5

Interpretation Introduction

c)

Organic Chemistry, Chapter 23.SE, Problem 48AP , additional homework tip  6

Interpretation:

Whether benzophenone undergoes aldol self-condensation reaction or not is to be stated. The product formed, if the reaction is successful, is also to be shown.

Concept introduction:

Aldehydes and ketones with α-hydrogen undergo a base catalyzed carbonyl condensation reaction in aldol condensation. In this reaction two molecules of the reactant combine by forming a bond between α-carbon of one molecule and the carbonyl carbon within the same molecule or of the second molecule.

To state:

Whether benzophenone undergoes aldol self-condensation reaction or not.

To show:

The product formed, if the reaction is successful.

Expert Solution
Check Mark

Answer to Problem 48AP

Benzophenone does not undergo self aldol condensation reaction. The reaction is not successful.

Explanation of Solution

The requirement of aldol reaction is the aldehyde or ketone should have α-hydrogen atom. Benzophenone does not possess α-hydrogen atom. Hence the reaction is not successful.

Conclusion

Benzophenone does not undergo self aldol condensation reaction. Theb reaction is not successful.

Interpretation Introduction

d)

Organic Chemistry, Chapter 23.SE, Problem 48AP , additional homework tip  7

Interpretation:

Whether 3-pentanone undergoes aldol self-condensation reaction or not is to be stated. The product formed, if the reaction is successful, is also to be shown.

Concept introduction:

Aldehydes and ketones with α-hydrogen undergo a base catalyzed carbonyl condensation reaction in aldol condensation. In this reaction two molecules of the reactant combine by forming a bond between α-carbon of one molecule and the carbonyl carbon within the same molecule or of the second molecule.

To state:

Whether 3-pentanone undergoes aldol self-condensation reaction or not.

To show:

The product formed, if the reaction is successful.

Expert Solution
Check Mark

Answer to Problem 48AP

3-pentanone undergoes aldol self-condensation reaction. The product formed is

Organic Chemistry, Chapter 23.SE, Problem 48AP , additional homework tip  8

Explanation of Solution

The requirement of aldol reaction is the aldehyde or ketone should have α-hydrogen atom. 3-Pentanone has α-hydrogen atom. Hence the reaction is successful. Two molecules of 3-pentanone condense in the presence of a base to yield an aldol which dehydrates to give the α, β-unsaturated ketone.

Organic Chemistry, Chapter 23.SE, Problem 48AP , additional homework tip  9

Conclusion

3-pentanone undergoes aldol self-condensation reaction. The product formed is

Organic Chemistry, Chapter 23.SE, Problem 48AP , additional homework tip  10

Interpretation Introduction

e)

Organic Chemistry, Chapter 23.SE, Problem 48AP , additional homework tip  11

Interpretation:

Whether decanal undergoes aldol self-condensation reaction or not is to be stated. The product formed, if the reaction is successful, is also to be shown.

Concept introduction:

Aldehydes and ketones with α-hydrogen undergo a base catalyzed carbonyl condensation reaction in aldol condensation. In this reaction two molecules of the reactant combine by forming a bond between α-carbon of one molecule and the carbonyl carbon within the same molecule or of the second molecule.

To state:

Whether decanal undergoes aldol self-condensation reaction or not.

To show:

The product formed, if the reaction is successful.

Expert Solution
Check Mark

Answer to Problem 48AP

Decanal undergoes aldol self-condensation reaction. The product formed is

Organic Chemistry, Chapter 23.SE, Problem 48AP , additional homework tip  12

Explanation of Solution

The requirement of aldol reaction is the aldehyde or ketone should have α-hydrogen atom. Decanal has α-hydrogen atom. Hence the reaction is successful. Two molecules of decanal condense in the presence of a base to yield an aldol which dehydrates to give an α, β-unsaturated aldehyde.

Organic Chemistry, Chapter 23.SE, Problem 48AP , additional homework tip  13

Conclusion

Decanal undergoes aldol self-condensation reaction. The product formed is

Organic Chemistry, Chapter 23.SE, Problem 48AP , additional homework tip  14

Interpretation Introduction

f)

Organic Chemistry, Chapter 23.SE, Problem 48AP , additional homework tip  15

Interpretation:

Whether 3-phenyl-2-propenal undergoes aldol self-condensation reaction or not is to be stated. The product formed, if the reaction is successful, is also to be shown.

Concept introduction:

Aldehydes and ketones with α-hydrogen undergo a base catalyzed carbonyl condensation reaction in aldol condensation. In this reaction two molecules of the reactant combine by forming a bond between α-carbon of one molecule and the carbonyl carbon within the same molecule or of the second molecule.

To state:

Whether 3-phenyl-2-propenal undergoes aldol self-condensation reaction or not.

To show:

The product formed, if the reaction is successful.

Expert Solution
Check Mark

Answer to Problem 48AP

3-Phenyl-2-propenal does not undergo aldol self-condensation reaction. The reaction is not successful.

Explanation of Solution

The requirement of aldol reaction is the aldehyde or ketone should have α-hydrogen atom. 3-Phenyl-2-propenal does not possess α-hydrogen atom. Hence the reaction is not successful.

Conclusion

3-Phenyl-2-propenal does not undergo aldol self-condensation reaction. The reaction is not successful.

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Chapter 23 Solutions

Organic Chemistry

Ch. 23.7 - Show the products you would expect to obtain by...Ch. 23.7 - Prob. 12PCh. 23.8 - What product would you expect from the following...Ch. 23.9 - What product would you expect From the following...Ch. 23.9 - Prob. 15PCh. 23.10 - Prob. 16PCh. 23.10 - Prob. 17PCh. 23.10 - Prob. 18PCh. 23.11 - Prob. 19PCh. 23.11 - Show how you might use an enamine reaction to...Ch. 23.12 - Prob. 21PCh. 23.12 - How would you prepare the following compound using...Ch. 23.SE - Prob. 23VCCh. 23.SE - Prob. 24VCCh. 23.SE - Prob. 25VCCh. 23.SE - The following molecule was formed by a Robinson...Ch. 23.SE - Prob. 27MPCh. 23.SE - Prob. 28MPCh. 23.SE - Predict the product(s) and provide the mechanism...Ch. 23.SE - Predict the product(s) and provide the mechanism...Ch. 23.SE - Predict the product(s) and provide the mechanism...Ch. 23.SE - Knoevenagel condensation is a reaction involving...Ch. 23.SE - Azlactones are important starting materials used...Ch. 23.SE - Prob. 34MPCh. 23.SE - Isoleucine, another of the twenty amino acids...Ch. 23.SE - The first step in the citric acid cycle of food...Ch. 23.SE - Prob. 37MPCh. 23.SE - The Knoevenagel reaction is a carbonyl...Ch. 23.SE - The Darzens reaction invoIves a two-step,...Ch. 23.SE - The following reaction involves a hydrolysis...Ch. 23.SE - Prob. 41MPCh. 23.SE - Prob. 42MPCh. 23.SE - Prob. 43MPCh. 23.SE - Propose a mechanism for the following...Ch. 23.SE - Prob. 45MPCh. 23.SE - Prob. 46MPCh. 23.SE - Prob. 47MPCh. 23.SE - Prob. 48APCh. 23.SE - Prob. 49APCh. 23.SE - Prob. 50APCh. 23.SE - Prob. 51APCh. 23.SE - Prob. 52APCh. 23.SE - Prob. 53APCh. 23.SE - Prob. 54APCh. 23.SE - Prob. 55APCh. 23.SE - Prob. 56APCh. 23.SE - Prob. 57APCh. 23.SE - Prob. 58APCh. 23.SE - In the mixed Claisen reaction of cyclopentanone...Ch. 23.SE - Ethyl dimethylacetoacetate reacts instantly at...Ch. 23.SE - Prob. 61APCh. 23.SE - Prob. 62APCh. 23.SE - The so-called Wieland-Miescher ketone is a...Ch. 23.SE - Prob. 64APCh. 23.SE - Prob. 65APCh. 23.SE - Prob. 66APCh. 23.SE - What condensation products would you expect to...Ch. 23.SE - The following reactions are unlikely to provide...Ch. 23.SE - Fill in the missing reagents a-h in the following...Ch. 23.SE - Prob. 70APCh. 23.SE - Prob. 71APCh. 23.SE - Prob. 72APCh. 23.SE - Prob. 73AP
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