Inorganic Chemistry
5th Edition
ISBN: 9780321811059
Author: Gary L. Miessler, Paul J. Fischer, Donald A. Tarr
Publisher: Prentice Hall
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Textbook Question
Chapter 2.3, Problem 2.8E
Explain why all three graphs in Figure 2.14 have maxima at 4 electrons and minima at 5 electrons.
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1. Sodium has a bigger first ionization energy than potassium
2. sodium has a bigger atomic size than clorine
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Chapter 2 Solutions
Inorganic Chemistry
Ch. 2.1 - Determine the energy of the transition from nh=3...Ch. 2.2 - Describe the angular nodal surfaces for a dz2...Ch. 2.2 - Prob. 2.3ECh. 2.2 - A third possible state for the p4 configuration...Ch. 2.2 - A nitrogen atom, with three 2p electrons, could...Ch. 2.2 - Calculate the effective nuclear charge on a 5s,...Ch. 2.2 - Calculate the effective nuclear charge on a 7s,...Ch. 2.3 - Explain why all three graphs in Figure 2.14 have...Ch. 2 - Determine the de Brogue wavelength of a. an...Ch. 2 - Using the equation E=RH(1221nh2) determine the...
Ch. 2 - The transition from the n=7 to the n=2 level of...Ch. 2 - Emissions are observed at wavelengths of 383.65...Ch. 2 - What is the least amount of energy that can be...Ch. 2 - Hydrogen atom emission spectra measured from the...Ch. 2 - The Rydberg constant equation has two terms that...Ch. 2 - For the 3pz and 4dxz hydrogen-like atomic...Ch. 2 - Repeat the exercise in Problem 2.7 for the 4s and...Ch. 2 - Repeat the exercise in Problem 2.7 for the 5s and...Ch. 2 - The 4fz(x2y2) orbital has the angular function...Ch. 2 - Prob. 2.13PCh. 2 - The label for an fz2 orbital, like that for a dz2...Ch. 2 - a. Determine the possible values for the l and ml...Ch. 2 - a. What are the values of quantum numbers I and n...Ch. 2 - a. At most, how many electrons in an atom can have...Ch. 2 - Determine the Coulombic and exchange energies for...Ch. 2 - Prob. 2.19PCh. 2 - Prob. 2.20PCh. 2 - What states are possible for a d3 configuration?...Ch. 2 - Provide explanations of the following phenomena:...Ch. 2 - Give electron configurations for the following:...Ch. 2 - Predict the electron configurations of the...Ch. 2 - Radial probability plots shed insight on issues of...Ch. 2 - Briefly explain the following on the basis of...Ch. 2 - Briefly explain the following on the basis of...Ch. 2 - a. Which 2+ ion has two 3d electrons? Which has...Ch. 2 - A sample calculation in this chapter showed that,...Ch. 2 - Ionization energies should depend on the effective...Ch. 2 - Prepare a diagram such as the one in Figure (a)...Ch. 2 - Why are the ionization energies of the alkali...Ch. 2 - The second ionization of carbon (C+C2++e) and the...Ch. 2 - Prob. 2.35PCh. 2 - Prob. 2.36PCh. 2 - The second ionization energy involves removing an...Ch. 2 - Prob. 2.38PCh. 2 - On the basis of electron configurations, explain...Ch. 2 - a. The graph of ionization energy versus atomic...Ch. 2 - The second ionization energy of He ¡s almost...Ch. 2 - The size of the transition-metal atoms decreases...Ch. 2 - Predict the largest and smallest radius in each...Ch. 2 - Select the best choice, and briefly indicate the...Ch. 2 - Select the best choice, and briefly indicate the...Ch. 2 - There are a number of Web sites that display...Ch. 2 - Prob. 2.47P
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- Place the following elements in order of increasing covalent radius (i.e., from smallest to largest): Aluminum (Al) Boron (B) Fluorine (F) Helium (He) Potassium (K)arrow_forwardReorder the list in the table, if necessary, so that the atoms and ions in it are list in order of decreasing size.arrow_forwardWhich 2+ ion has two 3d electrons? Which has eight 3d electrons?arrow_forward
- Please help me with these three :)arrow_forwardThe maximum number of valence electrons that any element in the periodic table may have is eight. True or False?arrow_forwardMatch a row to a column * transition alkaline earth halogen alkali metal inert gas metal metal 1s*2 2s^2 2p^6 3s^2 1s^2 2s^2 2p^6 3s^2 3p^6 3d^5 1s^2 2s^2 2p^6 3s^2 3p^6 3d^10 4s^2 4p^5arrow_forward
- Re-order each list in the table below, if necessary, so that the atoms or ions in it are listed in order of decreasing size. atoms or ions in order of decreasing size atoms or ions F, I, Cl 0.0.0 B, Li, O 0.0.0 Li, Be', Be 0.0.0arrow_forwardsulfur dichloride. Show outer shell electrons only. URarrow_forwardAluminum (Al) and silicon (Si) are in the same row (period) on the periodic table. The atomic radius of aluminum is 125 pm, while the atomic radius of silicon is 110 pm. Why is the aluminum atom larger than the silicon atom? Choose the best explanation. O Aluminum contains more electrons than silicon, so the electron cloud is larger. O The valence electrons in aluminum experience a lower effective nuclear charge than those in silicon, so they aren't pulled as strongly toward the nucleus. Valence electrons in aluminum are attracted to only 13 protons, while those in silicon are attracted to 14 protons, so the valence electrons aren't pulled as strongly toward the nucleus in aluminum. O Atomic radius decreases left-to-right on the periodic table and aluminum is farther to the left.arrow_forward
- 1) In the past you have learned that bismuth (Bi) is a metal that can lose 3 electrons and become Bi* . Actually, Bismuth is able to form 3 ions! The charges for each of the ions are 3-, 3+ and 5+. Propose electron configurations (long form only) for each ion. Explain the reasoning behind your configurations. Be sure to include the electron configuration of the neutral atom. Atom/ Electron Configuration (shorthand only) Reasoning for electron configuration of each ion Ion Bi (neutral) Bi3- Bi3+ Bi5+arrow_forwardPlease see imagearrow_forward1-An atomic cation with a charge of +2 has the following electron configuration: [He] 2s22p4 What is the chemical symbol for the ion? How many electrons does the ion have? How many 2s electrons are in the ion? 2- Ammonium perchlorate (NH4ClO4) is powerful solid rocket fuel, used in the Space Shuttle boosters. It decomposes into nitrogen (N2) gas, chlorine (Cl2) gas, oxygen (O2) gas, and water vapor, releasing a great deal of energy. Calculate the moles of chlorine produced by the reaction of 0.90mol of ammonium perchlorate. Be sure your answer has a unit symbol, if necessary, and round it to the correct number of significant digits. _____________ 3-How many protons and neutrons are in an atom of Th-229 ? Number of protons= ________ Number of neutrons= _______ 4- The chemical formula for beryllium sulfide is BeS. A chemist determined by measurements that 0.055 moles of beryllium sulfide…arrow_forward
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