Chemistry: Atoms First
Chemistry: Atoms First
2nd Edition
ISBN: 9780073511184
Author: Julia Burdge, Jason Overby Professor
Publisher: McGraw-Hill Education
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Chapter 23, Problem 23.53QP

(a) Define carbocation.

(b) Which of the following are carbocations?

Chapter 23, Problem 23.53QP, (a) Define carbocation. (b) Which of the following are carbocations?

(i)

Expert Solution
Check Mark
Interpretation Introduction

Interpretation:

Explanation of carbocation, Carbocation should be identified for the given molecule.

Concept introduction:

Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it plays vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation.

Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.

Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation.

Answer to Problem 23.53QP

Answer

Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it plays vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation. (a).

Explanation of Solution

To explain:carbocation

Structure of the carbocation is given below,

Chemistry: Atoms First, Chapter 23, Problem 23.53QP , additional homework tip  1

Carbon atom bears positive charged species with three bonds is called Carbocation and it plays vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation.

(ii)

Expert Solution
Check Mark
Interpretation Introduction

Interpretation:

Explanation of carbocation, Carbocation should be identified for the given molecule.

Concept introduction:

Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it plays vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation.

Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.

Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation.

Answer to Problem 23.53QP

Answer

The given molecule is not a carbocation, the structure of the molecule is shown below

Chemistry: Atoms First, Chapter 23, Problem 23.53QP , additional homework tip  2

Explanation of Solution

To find: The carbocation.

The given molecule is not a carbocation, the structure of the molecule is shown below

Chemistry: Atoms First, Chapter 23, Problem 23.53QP , additional homework tip  3

Oxygen is bearing positive charge, so the given molecule is not a carbocation.

(iii)

Expert Solution
Check Mark
Interpretation Introduction

Interpretation:

Explanation of carbocation, Carbocation should be identified for the given molecule.

Concept introduction:

Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it plays vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation.

Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.

Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation.

Answer to Problem 23.53QP

Answer

The given molecule is carbocation, the structure of the molecule is shown below

Chemistry: Atoms First, Chapter 23, Problem 23.53QP , additional homework tip  4

Explanation of Solution

To find: The carbocation.

The given molecule is carbocation, the structure of the molecule is shown below

Chemistry: Atoms First, Chapter 23, Problem 23.53QP , additional homework tip  5

Carbon atom bears positive charged species with three bonds so the given molecule is called Carbocation

(vi)

Expert Solution
Check Mark
Interpretation Introduction

Interpretation:

Explanation of carbocation, Carbocation should be identified for the given molecule.

Concept introduction:

Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it plays vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation.

Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.

Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation.

Answer to Problem 23.53QP

Answer

The given molecule is carbocation, the structure of the molecule is shown below (d)

Chemistry: Atoms First, Chapter 23, Problem 23.53QP , additional homework tip  6

Explanation of Solution

To find:The carbocation.

The given molecule is carbocation, the structure of the molecule is shown below

Chemistry: Atoms First, Chapter 23, Problem 23.53QP , additional homework tip  7

Carbon atom bears positive charged species with three bonds so the given molecule is called Carbocation

(v)

Expert Solution
Check Mark
Interpretation Introduction

Interpretation:

Explanation of carbocation, Carbocation should be identified for the given molecule.

Concept introduction:

Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it plays vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation.

Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.

Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation.

Answer to Problem 23.53QP

Answer

The given molecule is carbocation, the structure of the molecule is shown below (e)

Chemistry: Atoms First, Chapter 23, Problem 23.53QP , additional homework tip  8

Explanation of Solution

To find:The carbocation.

The given molecule is carbocation, the structure of the molecule is shown below

Chemistry: Atoms First, Chapter 23, Problem 23.53QP , additional homework tip  9

Carbon atom bears positive charged species with three bonds so the given molecule is called Carbocation.

 (vi)

Expert Solution
Check Mark
Interpretation Introduction

Interpretation:

Explanation of carbocation, Carbocation should be identified for the given molecule.

Concept introduction:

Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it plays vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation.

Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.

Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation.

Answer to Problem 23.53QP

Answer

The given molecule is not a carbocation, the structure of the molecule is shown below (f)

Chemistry: Atoms First, Chapter 23, Problem 23.53QP , additional homework tip  10

Explanation of Solution

To find: The carbocation.

The given molecule is not a carbocation, the structure of the molecule is shown below (f)

Chemistry: Atoms First, Chapter 23, Problem 23.53QP , additional homework tip  11

Nitrogen is bearing positive charge with four bonds, so the given molecule is not a carbocation.

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Chapter 23 Solutions

Chemistry: Atoms First

Ch. 23.2 - Prob. 23.2.3SRCh. 23.2 - Prob. 23.2.4SRCh. 23.2 - Prob. 23.2.5SRCh. 23.2 - Prob. 23.2.6SRCh. 23.3 - Prob. 23.3WECh. 23.3 - Prob. 3PPACh. 23.3 - Prob. 3PPBCh. 23.3 - Prob. 3PPCCh. 23.3 - Prob. 23.4WECh. 23.3 - Prob. 4PPACh. 23.3 - Prob. 4PPBCh. 23.3 - Prob. 4PPCCh. 23.3 - Prob. 23.3.1SRCh. 23.3 - Prob. 23.3.2SRCh. 23.3 - Which of the following pairs of species are...Ch. 23.3 - Prob. 23.3.4SRCh. 23.5 - Prob. 23.5WECh. 23.5 - Prob. 5PPACh. 23.5 - Prob. 5PPBCh. 23.5 - Prob. 23.5.1SRCh. 23.5 - Prob. 23.5.2SRCh. 23 - Prob. 23.1QPCh. 23 - Prob. 23.2QPCh. 23 - Prob. 23.3QPCh. 23 - Prob. 23.4QPCh. 23 - Prob. 23.5QPCh. 23 - Prob. 23.6QPCh. 23 - Prob. 23.7QPCh. 23 - Prob. 23.8QPCh. 23 - Prob. 23.9QPCh. 23 - Name each of the following compounds.Ch. 23 - Prob. 23.11QPCh. 23 - Prob. 23.12QPCh. 23 - Prob. 23.13QPCh. 23 - Prob. 23.14QPCh. 23 - Prob. 23.15QPCh. 23 - Prob. 23.16QPCh. 23 - Prob. 23.17QPCh. 23 - Prob. 23.18QPCh. 23 - Prob. 23.19QPCh. 23 - Prob. 23.20QPCh. 23 - Prob. 23.21QPCh. 23 - Prob. 23.22QPCh. 23 - Prob. 23.23QPCh. 23 - Prob. 23.24QPCh. 23 - Prob. 23.25QPCh. 23 - Prob. 23.26QPCh. 23 - Prob. 23.27QPCh. 23 - Prob. 23.28QPCh. 23 - Prob. 23.29QPCh. 23 - Prob. 23.30QPCh. 23 - Prob. 23.31QPCh. 23 - Prob. 23.32QPCh. 23 - Prob. 23.33QPCh. 23 - Prob. 23.34QPCh. 23 - Fill in the blanks in the given paragraph with the...Ch. 23 - Prob. 23.36QPCh. 23 - Draw all possible structural isomers for the...Ch. 23 - Prob. 23.38QPCh. 23 - Prob. 23.39QPCh. 23 - Prob. 23.40QPCh. 23 - Prob. 23.41QPCh. 23 - Prob. 23.42QPCh. 23 - Prob. 23.43QPCh. 23 - Prob. 23.44QPCh. 23 - Prob. 23.45QPCh. 23 - Prob. 23.46QPCh. 23 - Prob. 23.47QPCh. 23 - Prob. 23.48QPCh. 23 - Prob. 23.49QPCh. 23 - Prob. 23.50QPCh. 23 - Prob. 23.51QPCh. 23 - Prob. 23.52QPCh. 23 - (a) Define carbocation. (b) Which of the following...Ch. 23 - Prob. 23.54QPCh. 23 - Prob. 23.55QPCh. 23 - Prob. 23.56QPCh. 23 - Prob. 23.57QPCh. 23 - Prob. 23.58QPCh. 23 - Prob. 23.59QPCh. 23 - Consider the following reactions of butanal. In...Ch. 23 - Prob. 23.61QPCh. 23 - Prob. 23.62QPCh. 23 - Prob. 23.63QPCh. 23 - Prob. 23.64QPCh. 23 - Prob. 23.65QPCh. 23 - Prob. 23.66QPCh. 23 - Prob. 23.67QPCh. 23 - Prob. 23.68QPCh. 23 - Prob. 23.69QPCh. 23 - Prob. 23.70QPCh. 23 - Prob. 23.71QPCh. 23 - Prob. 23.72QPCh. 23 - Prob. 23.73QPCh. 23 - Prob. 23.74QPCh. 23 - Prob. 23.75QPCh. 23 - Prob. 23.76QPCh. 23 - Prob. 23.77QPCh. 23 - Prob. 23.78QPCh. 23 - Prob. 23.79QPCh. 23 - Prob. 23.80QPCh. 23 - Prob. 23.81QPCh. 23 - Prob. 23.82QPCh. 23 - Prob. 23.83QPCh. 23 - Prob. 23.84QPCh. 23 - Prob. 23.85QPCh. 23 - Prob. 23.86QPCh. 23 - Prob. 23.87QPCh. 23 - Prob. 23.88QPCh. 23 - Prob. 23.89QPCh. 23 - Prob. 23.90QPCh. 23 - Prob. 23.91QPCh. 23 - Prob. 23.92QPCh. 23 - Prob. 23.93QPCh. 23 - Prob. 23.94QPCh. 23 - Prob. 23.95QPCh. 23 - Prob. 23.96QPCh. 23 - Prob. 23.97QPCh. 23 - Prob. 23.98QPCh. 23 - Prob. 23.99QPCh. 23 - Prob. 23.100QPCh. 23 - Prob. 23.101QPCh. 23 - Prob. 23.102QPCh. 23 - Prob. 23.103QPCh. 23 - Prob. 23.104QPCh. 23 - Prob. 23.105QP
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