The color of the light absorbed by the given complex ion has to be determined. Concept introduction: The transition metal atoms have tendency to form complex compounds that are linked to the certain neutral or ionic species which leads to the formation of coordination compounds. There exists a large number of coordination compounds that have a large number of applications in the chemical industry as well as in daily life. The properties of the coordination compounds depend upon the primary and secondary valancy of the metal ion in the coordination sphere. The electrical conductivity depends upon the number of ions that are produced by complex. The strong-field ligands results in pairing of electrons present in the complex and leads to diamagnetic species , while the low-field ligand do not have tendency to pair up the electrons therefore forms paramagnetic species. The strong field ligands lead to splitting to a higher extent than the weak field ligands and the wavelength of light absorbed depends on the energy gap that is produced by a particular ligand in which the energy gap in d orbital splitting lies on the wave length of visible region. Visible region: The electromagnetic radiation in range of 400 − 700 n m is regarded as visible region which is actually visible to human eyes.

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Chapter 22, Problem 52PS

Interpretation Introduction

Interpretation: The color of the light absorbed by the given complex ion has to be determined.

Concept introduction: The transition metal atoms have tendency to form complex compounds that are linked to the certain neutral or ionic species which leads to the formation of coordination compounds. There exists a large number of coordination compounds that have a large number of applications in the chemical industry as well as in daily life.

The properties of the coordination compounds depend upon the primary and secondary valancy of the metal ion in the coordination sphere. The electrical conductivity depends upon the number of ions that are produced by complex.

The strong-field ligands results in pairing of electrons present in the complex and leads to diamagnetic species , while the low-field ligand do not have tendency to pair up the electrons therefore forms paramagnetic species.

The strong field ligands lead to splitting to a higher extent than the weak field ligands and the wavelength of light absorbed depends on the energy gap that is produced by a particular ligand in which the energy gap in d orbital splitting lies on the wave length of visible region.

Visible region: The electromagnetic radiation in range of 400−700 nm is regarded as visible region which is actually visible to human eyes.

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