(a) Interpretation: The curved arrow mechanism for the reaction (2) and the analogous reaction to this reaction is to be stated. Concept introduction: The enzyme dehydroquinate synthase is used to catalyze the reaction of 3 − deoxy − D − arabinoheptulosonate − 7 − phosphate to 3 − dehydroquinate and phosphate. Along with it it also uses NAD + as a coenzyme. This enzyme also involved in the synthesis of aromatic amino acids.

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Answer 1

Question

Chapter 22, Problem 22.97AP

Interpretation Introduction

(a)

Interpretation:

The curved arrow mechanism for the reaction (2) and the analogous reaction to this reaction is to be stated.

Concept introduction:

The enzyme dehydroquinate synthase is used to catalyze the reaction of 3− deoxy −D− arabinoheptulosonate −7− phosphate to 3− dehydroquinate and phosphate. Along with it it also uses NAD+ as a coenzyme. This enzyme also involved in the synthesis of aromatic amino acids.

Interpretation Introduction

(b)

Interpretation:

The chemical rationale involved in the reaction (1) and reaction (3) is to be stated.

Concept introduction:

The enzyme dehydroquinate synthase is used to catalyze the reaction of 3− deoxy −D− arabinoheptulosonate −7− phosphate to 3− dehydroquinate and phosphate. Along with it it also uses NAD+ as a coenzyme. This enzyme also involved in the synthesis of aromatic amino acids.

Interpretation Introduction

(c)

Interpretation:

The curved arrow mechanism for the reaction (4) and (5) and the analogous reaction to these reactions are to be stated.

Concept introduction:

The enzyme dehydroquinate synthase is used to catalyze the reaction of 3− deoxy −D− arabinoheptulosonate −7− phosphate to 3− dehydroquinate and phosphate. Along with it it also uses NAD+ as a coenzyme. This enzyme also involved in the synthesis of aromatic amino acids.

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14.

Outline syntheses of each of the following from aniline and any necessary organic or inorganic reagents. (a) p-Nitroaniline (b) 2,4-Dinitroaniline (c) p-Aminoacetanilide

Answer 2

Question

Chapter 22, Problem 22.97AP

Interpretation Introduction

(a)

Interpretation:

The curved arrow mechanism for the reaction (2) and the analogous reaction to this reaction is to be stated.

Concept introduction:

The enzyme dehydroquinate synthase is used to catalyze the reaction of 3− deoxy −D− arabinoheptulosonate −7− phosphate to 3− dehydroquinate and phosphate. Along with it it also uses NAD+ as a coenzyme. This enzyme also involved in the synthesis of aromatic amino acids.

Interpretation Introduction

(b)

Interpretation:

The chemical rationale involved in the reaction (1) and reaction (3) is to be stated.

Concept introduction:

The enzyme dehydroquinate synthase is used to catalyze the reaction of 3− deoxy −D− arabinoheptulosonate −7− phosphate to 3− dehydroquinate and phosphate. Along with it it also uses NAD+ as a coenzyme. This enzyme also involved in the synthesis of aromatic amino acids.

Interpretation Introduction

(c)

Interpretation:

The curved arrow mechanism for the reaction (4) and (5) and the analogous reaction to these reactions are to be stated.

Concept introduction:

The enzyme dehydroquinate synthase is used to catalyze the reaction of 3− deoxy −D− arabinoheptulosonate −7− phosphate to 3− dehydroquinate and phosphate. Along with it it also uses NAD+ as a coenzyme. This enzyme also involved in the synthesis of aromatic amino acids.

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Answer 3

Question

Chapter 22, Problem 22.97AP

Interpretation Introduction

(a)

Interpretation:

The curved arrow mechanism for the reaction (2) and the analogous reaction to this reaction is to be stated.

Concept introduction:

The enzyme dehydroquinate synthase is used to catalyze the reaction of 3− deoxy −D− arabinoheptulosonate −7− phosphate to 3− dehydroquinate and phosphate. Along with it it also uses NAD+ as a coenzyme. This enzyme also involved in the synthesis of aromatic amino acids.

Interpretation Introduction

(b)

Interpretation:

The chemical rationale involved in the reaction (1) and reaction (3) is to be stated.

Concept introduction:

The enzyme dehydroquinate synthase is used to catalyze the reaction of 3− deoxy −D− arabinoheptulosonate −7− phosphate to 3− dehydroquinate and phosphate. Along with it it also uses NAD+ as a coenzyme. This enzyme also involved in the synthesis of aromatic amino acids.

Interpretation Introduction

(c)

Interpretation:

The curved arrow mechanism for the reaction (4) and (5) and the analogous reaction to these reactions are to be stated.

Concept introduction:

The enzyme dehydroquinate synthase is used to catalyze the reaction of 3− deoxy −D− arabinoheptulosonate −7− phosphate to 3− dehydroquinate and phosphate. Along with it it also uses NAD+ as a coenzyme. This enzyme also involved in the synthesis of aromatic amino acids.

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Answer 4

Question

Chapter 22, Problem 22.97AP

Interpretation Introduction

(a)

Interpretation:

The curved arrow mechanism for the reaction (2) and the analogous reaction to this reaction is to be stated.

Concept introduction:

The enzyme dehydroquinate synthase is used to catalyze the reaction of 3− deoxy −D− arabinoheptulosonate −7− phosphate to 3− dehydroquinate and phosphate. Along with it it also uses NAD+ as a coenzyme. This enzyme also involved in the synthesis of aromatic amino acids.

Interpretation Introduction

(b)

Interpretation:

The chemical rationale involved in the reaction (1) and reaction (3) is to be stated.

Concept introduction:

The enzyme dehydroquinate synthase is used to catalyze the reaction of 3− deoxy −D− arabinoheptulosonate −7− phosphate to 3− dehydroquinate and phosphate. Along with it it also uses NAD+ as a coenzyme. This enzyme also involved in the synthesis of aromatic amino acids.

Interpretation Introduction

(c)

Interpretation:

The curved arrow mechanism for the reaction (4) and (5) and the analogous reaction to these reactions are to be stated.

Concept introduction:

The enzyme dehydroquinate synthase is used to catalyze the reaction of 3− deoxy −D− arabinoheptulosonate −7− phosphate to 3− dehydroquinate and phosphate. Along with it it also uses NAD+ as a coenzyme. This enzyme also involved in the synthesis of aromatic amino acids.

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Answer 5

Chapter 22, Problem 22.97AP

Interpretation Introduction

(a)

Interpretation:

The curved arrow mechanism for the reaction (2) and the analogous reaction to this reaction is to be stated.

Concept introduction:

The enzyme dehydroquinate synthase is used to catalyze the reaction of 3− deoxy −D− arabinoheptulosonate −7− phosphate to 3− dehydroquinate and phosphate. Along with it it also uses NAD+ as a coenzyme. This enzyme also involved in the synthesis of aromatic amino acids.

Interpretation Introduction

(b)

Interpretation:

The chemical rationale involved in the reaction (1) and reaction (3) is to be stated.

Concept introduction:

The enzyme dehydroquinate synthase is used to catalyze the reaction of 3− deoxy −D− arabinoheptulosonate −7− phosphate to 3− dehydroquinate and phosphate. Along with it it also uses NAD+ as a coenzyme. This enzyme also involved in the synthesis of aromatic amino acids.

Interpretation Introduction

(c)

Interpretation:

The curved arrow mechanism for the reaction (4) and (5) and the analogous reaction to these reactions are to be stated.

Concept introduction:

The enzyme dehydroquinate synthase is used to catalyze the reaction of 3− deoxy −D− arabinoheptulosonate −7− phosphate to 3− dehydroquinate and phosphate. Along with it it also uses NAD+ as a coenzyme. This enzyme also involved in the synthesis of aromatic amino acids.

Answer 6

Chapter 22, Problem 22.97AP

Interpretation Introduction

(a)

Interpretation:

The curved arrow mechanism for the reaction (2) and the analogous reaction to this reaction is to be stated.

Concept introduction:

The enzyme dehydroquinate synthase is used to catalyze the reaction of 3− deoxy −D− arabinoheptulosonate −7− phosphate to 3− dehydroquinate and phosphate. Along with it it also uses NAD+ as a coenzyme. This enzyme also involved in the synthesis of aromatic amino acids.

Answer 7

Chapter 22, Problem 22.97AP

Interpretation Introduction

(a)

Interpretation:

The curved arrow mechanism for the reaction (2) and the analogous reaction to this reaction is to be stated.

Concept introduction:

The enzyme dehydroquinate synthase is used to catalyze the reaction of 3− deoxy −D− arabinoheptulosonate −7− phosphate to 3− dehydroquinate and phosphate. Along with it it also uses NAD+ as a coenzyme. This enzyme also involved in the synthesis of aromatic amino acids.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The chemical rationale involved in the reaction (1) and reaction (3) is to be stated.

Concept introduction:

The enzyme dehydroquinate synthase is used to catalyze the reaction of 3− deoxy −D− arabinoheptulosonate −7− phosphate to 3− dehydroquinate and phosphate. Along with it it also uses NAD+ as a coenzyme. This enzyme also involved in the synthesis of aromatic amino acids.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The chemical rationale involved in the reaction (1) and reaction (3) is to be stated.

Concept introduction:

The enzyme dehydroquinate synthase is used to catalyze the reaction of 3− deoxy −D− arabinoheptulosonate −7− phosphate to 3− dehydroquinate and phosphate. Along with it it also uses NAD+ as a coenzyme. This enzyme also involved in the synthesis of aromatic amino acids.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The curved arrow mechanism for the reaction (4) and (5) and the analogous reaction to these reactions are to be stated.

Concept introduction:

The enzyme dehydroquinate synthase is used to catalyze the reaction of 3− deoxy −D− arabinoheptulosonate −7− phosphate to 3− dehydroquinate and phosphate. Along with it it also uses NAD+ as a coenzyme. This enzyme also involved in the synthesis of aromatic amino acids.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The curved arrow mechanism for the reaction (4) and (5) and the analogous reaction to these reactions are to be stated.

Concept introduction:

The enzyme dehydroquinate synthase is used to catalyze the reaction of 3− deoxy −D− arabinoheptulosonate −7− phosphate to 3− dehydroquinate and phosphate. Along with it it also uses NAD+ as a coenzyme. This enzyme also involved in the synthesis of aromatic amino acids.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 22 - Prob. 22.1P Ch. 22 - Prob. 22.2P Ch. 22 - Prob. 22.3P Ch. 22 - Prob. 22.4P Ch. 22 - Prob. 22.5P Ch. 22 - Prob. 22.6P Ch. 22 - Prob. 22.7P Ch. 22 - Prob. 22.8P Ch. 22 - Prob. 22.9P Ch. 22 - Prob. 22.10P

Solution Summary: The author explains that the reaction (2) is analogous to reduction reaction since the mechanism proceeds with the elimination of a hydrogen atom.

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Chapter 22 Solutions