Organic Chemistry (6th Edition)
6th Edition
ISBN: 9781260119107
Author: Janice Gorzynski Smith
Publisher: McGraw Hill Education
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Chapter 21.7, Problem 13P
Draw the products of each reaction. Assume excess halogen is present.
a. 
b. 
c. 
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What are the composition of the following reagents?
a. Tollen's reagent
b. Fehling's A
c. Fehling's B
d. Schiff's reagent
e. KMnO4
What is the mojor product of this reaction?
OTs
NaOEt
OEt
A.
OEt
B.
C.
D.
For alkylhalides, elimination reaction is much
favored than substitution reaction when
A. Temperature is relatively high.
B. Temperature is relatively low.
C. Base is relatively weak
D. Pressure is relatively high.
Chapter 21 Solutions
Organic Chemistry (6th Edition)
Ch. 21.2 - Problem 23.1 Draw the enol or keto tautomer(s) of...Ch. 21.2 - Problem 23.3 When phenylacetaldehyde is dissolved...Ch. 21.3 - Prob. 5PCh. 21.3 - Problem 23.5 Which bonds in the following...Ch. 21.3 - Prob. 7PCh. 21.3 - Prob. 8PCh. 21.3 - Prob. 9PCh. 21.4 - Prob. 10PCh. 21.5 - Prob. 11PCh. 21.7 - Problem 23.11 Draw the products of each...
Ch. 21.7 - Problem 23.12 Draw the products of each reaction....Ch. 21.7 - Prob. 14PCh. 21.7 - Prob. 15PCh. 21.8 - Prob. 16PCh. 21.8 - Prob. 17PCh. 21.8 - Prob. 18PCh. 21.8 - Problem 23.18 How can pentan-2-one be converted...Ch. 21.8 - Problem 23.19 Identify A, B, and C, intermediates...Ch. 21.9 - Problem 23.20 Which of the following compounds...Ch. 21.9 - Problem 23.21 Draw the products of each...Ch. 21.9 - Prob. 23PCh. 21.9 - Prob. 24PCh. 21.9 - Prob. 25PCh. 21.10 - Prob. 26PCh. 21.10 - Prob. 27PCh. 21.10 - Prob. 28PCh. 21.10 - Prob. 29PCh. 21 - 23.29 Draw enol tautomer(s) for each compound....Ch. 21 - 22.30 The cis ketone A is isomerized to a trans...Ch. 21 - 23.31 Draw enol tautomer(s) for each compound.
...Ch. 21 - Prob. 33PCh. 21 - Prob. 34PCh. 21 - 23.35 Rank the labeled protons in each compound in...Ch. 21 - Prob. 36PCh. 21 - Prob. 37PCh. 21 - 23.38 Acyclovir is an effective antiviral agent...Ch. 21 - 23.39 Explain why forms two different alkylation...Ch. 21 - Prob. 40PCh. 21 - 23.42 Draw a stepwise mechanism for the following...Ch. 21 - Prob. 42PCh. 21 - Prob. 43PCh. 21 - 23.45 Devise a synthesis of valproic acid , a...Ch. 21 - Prob. 57PCh. 21 - 23.57 Draw a stepwise mechanism showing how two...Ch. 21 - 23.58 Draw a stepwise mechanism for the following...Ch. 21 - Prob. 65PCh. 21 - 23.66 Synthesize (Z)-hept-5-en-2-one from ethyl...
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- compound a HC=CH a. b. compound f Reagents HCI HBr H₂O, H₂SO4 C. d. Br₂ e. Cl₂ r compound d compound j compound i n compound h compound c compound b n HC=CH m. n. O. compound g compound e HC=CH 2 equivalents of NaNH₂ H₂, Lindlar's catalyst Na/NH3 p. H₂SO4, HgSO4 q. (sia)₂BH then H₂O₂, NaOH Prarrow_forward1. Draw the products of each nucleophilic substitution reaction a. b. D b OH C. d. e. f. Br 1 NaCN + NaOCH3 H₂Oarrow_forwardWhat is the major organic product obtained from the following reaction? A. B. HN 1. H₂NCH3, H* cat. 2. NaBH3CN C. D. HNarrow_forward
- a. 2. Draw the product(s) for each reaction d. b. OH a. NaH, DCM b. CH,CH₂Br OH a. PBr3, THF b. MeOH Br a. H₂O b. NaH, THF OH H₂SO4 Δarrow_forward2. What is the product(s) of the following reaction? A HN B. N A NH2 [H+] -H₂O C. D. HN 3. What is/are the product(s) of the following reaction? A. B. D [H+] -H₂O C.arrow_forward17. What is the missing reagent in the reaction below? aq. HCI A. CH2(COOE1)2, NaOEt C. CH2(COOE1)2, HOAC B. CH3CO2Et, NaOEt D. CH3CO,Et, HOAC 18. In several reactions of carhonyl compounds that we have studied, the reaction proceeds by carrow_forward
- 1. For each reaction, write the letter corresponding to the type of reaction in column I and predict the MAJOR product. Draw the structure of the product in column III. A. Addition Reaction B. Electrophilic Aromatic Substitution Column I A. B. B. A. A. B. B. A. A. A. B. A. B. A. B. H₂C H3C H3C. H3C H3C H3C H3C H₂C CH3 CH3 H3C CH3 Reaction CH3 CH3 CH3 CH₂ ECH CH3 CH CH3 l CH3 CH₂ oso NH OEt CH3 CH3 orada CH3 CH3 -CH3 HNO3 H₂SO4 CH3 Br₂ DCM Br₂ hv H₂SO₂, H₂O HgSO4 Br₂ AlBr CH3 NBS hv HCI AICI Na₂Cr₂O7 H₂SO4, H₂O Br₂ FeBr H₂O* H₂ Lindlar's Catalyst 1) NaNH, 2) CH₂CH₂CH₂Br 3) H₂, Lindlar's catalyst CH3 NBS hv HNO, H₂SO4 C. Free Radical Substitution D. Redox Reaction Product (Column III)arrow_forward19. What is the product? a. b. Li/NH3 ? ethanol d. e. not a.-d.arrow_forwardReagents available f. PBr3 g. Mg, ether a. CH3CH,COCH b. C6H5 COCI c. AlCl3 d. NaBH₁, ethanol e. H₂SO4, dil am h. H₂SO4, conc i. SOCI₂ j. C6H5 CNarrow_forward
- 3. Draw arrows to show movement of electrons in the following reaction. H H. H.arrow_forward41. Draw the structure of a hydrocarbon that has six carbon atoms and a. three vinylic hydrogens and two allylic hydrogens. b. three vinylic hydrogens and one allylic hydrogen. c. three vinylic hydrogens and no allylic hydrogens.arrow_forward4. Phenol can be prepared on industrial scale from which of the given starting material. A. Toluene B. Styrene C. Cumene D. Caprolactamarrow_forward
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