A mechanism corresponding to the acid-catalyzed reaction of salicylic acid with acetic anhydride is to be proposed. Concept introduction: Acid-catalyzed reactions are the chemical reactions that are catalyzed by an acid. An acid is a proton donor and is known as Bronsted-Lowry acid. The reactions that are typically catalyzed by proton transfer are esterification and aldol reactions.

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Answer 1

Question

Chapter 21.6, Problem 21.15P

(a)

Interpretation Introduction

Interpretation:

A mechanism corresponding to the acid-catalyzed reaction of salicylic acid with acetic anhydride is to be proposed.

Concept introduction:

Acid-catalyzed reactions are the chemical reactions that are catalyzed by an acid. An acid is a proton donor and is known as Bronsted-Lowry acid. The reactions that are typically catalyzed by proton transfer are esterification and aldol reactions.

(b)

Interpretation Introduction

Interpretation:

An explanation corresponding to the statement that a single drop of sulfuric acid dramatically increases the reaction rate is to be stated.

Concept introduction:

Catalysts are basically the substances that increase the rate of reaction and they are not consumed in the reaction. In the presence of catalysts, more collisions occurs in a reaction that increases the rate of a reaction.

Acid-catalyzed reactions are the chemical reactions that are catalyzed by an acid. An acid is a proton donor and is known as Bronsted-Lowry acid. The reactions that are typically catalyzed by proton transfer are esterification and aldol reactions.

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Part 1. Aqueous 0.010M AgNO 3 is slowly added to a 50-ml solution containing both carbonate [co32-] = 0.105 M and sulfate [soy] = 0.164 M anions. Given the ksp of Ag2CO3 and Ag₂ soy below. Answer the ff: Ag₂ CO3 = 2 Ag+ caq) + co} (aq) ksp = 8.10 × 10-12 Ag₂SO4 = 2Ag+(aq) + soy² (aq) ksp = 1.20 × 10-5 a) which salt will precipitate first? (b) What % of the first anion precipitated will remain in the solution. by the time the second anion starts to precipitate? (c) What is the effect of low pH (more acidic) condition on the separate of the carbonate and sulfate anions via silver precipitation? What is the effect of high pH (more basic)? Provide appropriate explanation per answer

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Answer 2

Question

Chapter 21.6, Problem 21.15P

(a)

Interpretation Introduction

Interpretation:

A mechanism corresponding to the acid-catalyzed reaction of salicylic acid with acetic anhydride is to be proposed.

Concept introduction:

Acid-catalyzed reactions are the chemical reactions that are catalyzed by an acid. An acid is a proton donor and is known as Bronsted-Lowry acid. The reactions that are typically catalyzed by proton transfer are esterification and aldol reactions.

(b)

Interpretation Introduction

Interpretation:

An explanation corresponding to the statement that a single drop of sulfuric acid dramatically increases the reaction rate is to be stated.

Concept introduction:

Catalysts are basically the substances that increase the rate of reaction and they are not consumed in the reaction. In the presence of catalysts, more collisions occurs in a reaction that increases the rate of a reaction.

Acid-catalyzed reactions are the chemical reactions that are catalyzed by an acid. An acid is a proton donor and is known as Bronsted-Lowry acid. The reactions that are typically catalyzed by proton transfer are esterification and aldol reactions.

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Answer 3

Question

Chapter 21.6, Problem 21.15P

(a)

Interpretation Introduction

Interpretation:

A mechanism corresponding to the acid-catalyzed reaction of salicylic acid with acetic anhydride is to be proposed.

Concept introduction:

Acid-catalyzed reactions are the chemical reactions that are catalyzed by an acid. An acid is a proton donor and is known as Bronsted-Lowry acid. The reactions that are typically catalyzed by proton transfer are esterification and aldol reactions.

(b)

Interpretation Introduction

Interpretation:

An explanation corresponding to the statement that a single drop of sulfuric acid dramatically increases the reaction rate is to be stated.

Concept introduction:

Catalysts are basically the substances that increase the rate of reaction and they are not consumed in the reaction. In the presence of catalysts, more collisions occurs in a reaction that increases the rate of a reaction.

Acid-catalyzed reactions are the chemical reactions that are catalyzed by an acid. An acid is a proton donor and is known as Bronsted-Lowry acid. The reactions that are typically catalyzed by proton transfer are esterification and aldol reactions.

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Answer 4

Question

Chapter 21.6, Problem 21.15P

(a)

Interpretation Introduction

Interpretation:

A mechanism corresponding to the acid-catalyzed reaction of salicylic acid with acetic anhydride is to be proposed.

Concept introduction:

Acid-catalyzed reactions are the chemical reactions that are catalyzed by an acid. An acid is a proton donor and is known as Bronsted-Lowry acid. The reactions that are typically catalyzed by proton transfer are esterification and aldol reactions.

(b)

Interpretation Introduction

Interpretation:

An explanation corresponding to the statement that a single drop of sulfuric acid dramatically increases the reaction rate is to be stated.

Concept introduction:

Catalysts are basically the substances that increase the rate of reaction and they are not consumed in the reaction. In the presence of catalysts, more collisions occurs in a reaction that increases the rate of a reaction.

Acid-catalyzed reactions are the chemical reactions that are catalyzed by an acid. An acid is a proton donor and is known as Bronsted-Lowry acid. The reactions that are typically catalyzed by proton transfer are esterification and aldol reactions.

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Answer 5

Chapter 21.6, Problem 21.15P

(a)

Interpretation Introduction

Interpretation:

A mechanism corresponding to the acid-catalyzed reaction of salicylic acid with acetic anhydride is to be proposed.

Concept introduction:

Acid-catalyzed reactions are the chemical reactions that are catalyzed by an acid. An acid is a proton donor and is known as Bronsted-Lowry acid. The reactions that are typically catalyzed by proton transfer are esterification and aldol reactions.

(b)

Interpretation Introduction

Interpretation:

An explanation corresponding to the statement that a single drop of sulfuric acid dramatically increases the reaction rate is to be stated.

Concept introduction:

Catalysts are basically the substances that increase the rate of reaction and they are not consumed in the reaction. In the presence of catalysts, more collisions occurs in a reaction that increases the rate of a reaction.

Acid-catalyzed reactions are the chemical reactions that are catalyzed by an acid. An acid is a proton donor and is known as Bronsted-Lowry acid. The reactions that are typically catalyzed by proton transfer are esterification and aldol reactions.

Answer 6

Chapter 21.6, Problem 21.15P

(a)

Interpretation Introduction

Interpretation:

A mechanism corresponding to the acid-catalyzed reaction of salicylic acid with acetic anhydride is to be proposed.

Concept introduction:

Acid-catalyzed reactions are the chemical reactions that are catalyzed by an acid. An acid is a proton donor and is known as Bronsted-Lowry acid. The reactions that are typically catalyzed by proton transfer are esterification and aldol reactions.

Answer 7

Chapter 21.6, Problem 21.15P

(a)

Interpretation Introduction

Interpretation:

A mechanism corresponding to the acid-catalyzed reaction of salicylic acid with acetic anhydride is to be proposed.

Concept introduction:

Acid-catalyzed reactions are the chemical reactions that are catalyzed by an acid. An acid is a proton donor and is known as Bronsted-Lowry acid. The reactions that are typically catalyzed by proton transfer are esterification and aldol reactions.

Answer 8

(b)

Interpretation Introduction

Interpretation:

An explanation corresponding to the statement that a single drop of sulfuric acid dramatically increases the reaction rate is to be stated.

Concept introduction:

Catalysts are basically the substances that increase the rate of reaction and they are not consumed in the reaction. In the presence of catalysts, more collisions occurs in a reaction that increases the rate of a reaction.

Acid-catalyzed reactions are the chemical reactions that are catalyzed by an acid. An acid is a proton donor and is known as Bronsted-Lowry acid. The reactions that are typically catalyzed by proton transfer are esterification and aldol reactions.

Answer 9

(b)

Interpretation Introduction

Interpretation:

An explanation corresponding to the statement that a single drop of sulfuric acid dramatically increases the reaction rate is to be stated.

Concept introduction:

Catalysts are basically the substances that increase the rate of reaction and they are not consumed in the reaction. In the presence of catalysts, more collisions occurs in a reaction that increases the rate of a reaction.

Acid-catalyzed reactions are the chemical reactions that are catalyzed by an acid. An acid is a proton donor and is known as Bronsted-Lowry acid. The reactions that are typically catalyzed by proton transfer are esterification and aldol reactions.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 21.2F - Name the following carboxylic acid derivatives,...Ch. 21.4A - Prob. 21.2P Ch. 21.4A - Prob. 21.3P Ch. 21.4A - Prob. 21.4P Ch. 21.5C - Prob. 21.7P Ch. 21.6 - When ethyl 4-hydroxybutyrate is heated in the...Ch. 21.6 - Propose a mechanism for the following ring-opening...Ch. 21.6 - Prob. 21.15P Ch. 21.7B - Prob. 21.16P Ch. 21.7C - Prob. 21.19P

Solution Summary: The author proposes a mechanism corresponding to the acid-catalyzed reaction of salicylic acid with acetic anhydride.

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Chapter 21 Solutions