Organic Chemistry (9th Edition)
9th Edition
ISBN: 9780321971371
Author: Leroy G. Wade, Jan W. Simek
Publisher: PEARSON
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Chapter 21, Problem 21.54SP
Show how you would accomplish the following syntheses. Some of these conversions may require more than one step.
- a. isopentylalcohol → isopentyl acetate (banana oil)
- b. 3 – ethylpentanoicacid → 3 – ethylpentanenitrile
- c. isobutylamine → N - isobutylformamide
- d. ethyl acetate → 3 - methylpentan - 3 - ol
- e. cyclohexylamine → N – cyclohexylacetamide
- f. bromocyclohexane → dicyclohexylmethanol
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Show how to convert cyclohexanol to these compounds.
a. Cyclohexene
b. Cyclohexane
c. Cyclohexanone
d. Bromocyclohexane
which has the greatest acidity?
a. 2-hexanol
b. valeric acid
c. naphtol
d. ethyl propionate
which produces effervescence when
dissolved in 10% sodium bicarbonate?
a. 2-hexanol
b. valeric acid
c. napththol
d. ethyl propionate
1. An alkene reacts with water with an acid catalyst results into a formation of:
A. Aldehyde
B. Ketone
C. Alcohol
D. Ester
2. 3-Methylhexanal with K2Cr2O7 will yield:
A. 3-Methyl-1-hexanol
B. 3-Methylhexanoic acid
C. 3-Methyl-1-hexanone
D. 3-Methyl-1-hexanethiol
3. This is a reverse process of Hydration reaction:
A. Oxidation reaction
B. Reduction reaction
C. Dehydration reaction
D. Hydration reaction
4. Acetic acid reacts with a strong base forms:
A. Salt
B. Water
C. Salt and Water
D. No reaction
5. Ketones can be further oxidized with benedict's solution into:
A. Alcohol
B. Aldehyde
C. Catalysts
D. No reaction
Chapter 21 Solutions
Organic Chemistry (9th Edition)
Ch. 21.2F - Name the following carboxylic acid derivatives,...Ch. 21.4A - Prob. 21.2PCh. 21.4A - Prob. 21.3PCh. 21.4A - Prob. 21.4PCh. 21.5C - Prob. 21.7PCh. 21.6 - When ethyl 4-hydroxybutyrate is heated in the...Ch. 21.6 - Propose a mechanism for the following ring-opening...Ch. 21.6 - Prob. 21.15PCh. 21.7B - Prob. 21.16PCh. 21.7C - Prob. 21.19P
Ch. 21.7C - Prob. 21.20PCh. 21.7C - Prob. 21.21PCh. 21.7D - Prob. 21.22PCh. 21.7D - The mechanism for acidic hydrolysis of a nitrile...Ch. 21.8A - Prob. 21.24PCh. 21.8C - Prob. 21.25PCh. 21.9 - Prob. 21.26PCh. 21.9 - Prob. 21.27PCh. 21.9 - Prob. 21.28PCh. 21.10 - Draw a mechanism for the acylation of anisole by...Ch. 21.10 - Prob. 21.30PCh. 21.11 - Prob. 21.31PCh. 21.11 - Prob. 21.32PCh. 21.12 - Problem 21-33 Propose a mechanism for the...Ch. 21.12 - Suggest the most appropriate reagent for each...Ch. 21.12 - Show how you would synthesize each compound,...Ch. 21.13 - Prob. 21.36PCh. 21.13 - Prob. 21.37PCh. 21.14 - Prob. 21.38PCh. 21.14 - Prob. 21.39PCh. 21.16 - Prob. 21.40PCh. 21.16 - Prob. 21.41PCh. 21 - Prob. 21.42SPCh. 21 - Give appropriate names for the following...Ch. 21 - Predict the major products formed when benzoyl...Ch. 21 - Predict the products of the following reactions....Ch. 21 - Prob. 21.46SPCh. 21 - Prob. 21.47SPCh. 21 - Prob. 21.48SPCh. 21 - Propose mechanisms for the following reactions.Ch. 21 - Prob. 21.51SPCh. 21 - An ether extraction of nutmeg gives large...Ch. 21 - Prob. 21.53SPCh. 21 - Show how you would accomplish the following...Ch. 21 - Prob. 21.55SPCh. 21 - Prob. 21.56SPCh. 21 - Prob. 21.57SPCh. 21 - Prob. 21.58SPCh. 21 - Prob. 21.59SPCh. 21 - Explain this curious result. What does this...Ch. 21 - Prob. 21.61SPCh. 21 - Prob. 21.62SPCh. 21 - Prob. 21.63SPCh. 21 - A chemist was called to an abandoned aspirin...Ch. 21 - Prob. 21.67SPCh. 21 - The IR spectrum, 13ONTVTR spectrum, and 1HNMR...Ch. 21 - Prob. 21.69SPCh. 21 - Prob. 21.70SPCh. 21 - Prob. 21.71SP
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