Chemistry: The Molecular Nature of Matter and Change
Chemistry: The Molecular Nature of Matter and Change
9th Edition
ISBN: 9781260477467
Author: Martin Silberberg
Publisher: Mcgraw-hill Higher Education (us)
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Chapter 21, Problem 21.98P

(a)

Interpretation Introduction

Interpretation:

For aqueous electrolysis of ZnBr2 the balanced half reaction for products forms at each electrode has to be identified.

Concept Introduction:

An electrochemical cell is a device in which a redox reaction is used to convert chemical energy into electrical energy. Such device is also known as the galvanic or voltaic cell.

Anode: The electrode where the oxidation occurs is called as an anode. It is a negatively charged electrode.

Cathode: The electrode where reduction occurs is called as a cathode. It is a positively charged electrode.

Redox reaction: Redox reaction is a type of chemical reaction, where both the oxidation and reduction occur at the same time. In a redox reaction, one of the reactant is oxidized and the other is reduced simultaneously.

Generally, the anode compartment with oxidation components are written on the left side of the salt bridge and the cathode compartment with reduction components are notified on the right of the salt bridge. The cathode and anode are separated by using the double vertical line which actually represents the salt bridge. The species of different phases are notified by using a single vertical line in the cell notation.

(b)

Interpretation Introduction

Interpretation:

For aqueous electrolysis of Cu(HCO3)2 the balanced half reaction for products forms at each electrode has to be identified.

Concept Introduction:

An electrochemical cell is a device in which a redox reaction is used to convert chemical energy into electrical energy. Such device is also known as the galvanic or voltaic cell.

Anode: The electrode where the oxidation occurs is called as an anode. It is a negatively charged electrode.

Cathode: The electrode where reduction occurs is called as a cathode. It is a positively charged electrode.

Redox reaction: Redox reaction is a type of chemical reaction, where both the oxidation and reduction occur at the same time. In a redox reaction, one of the reactant is oxidized and the other is reduced simultaneously.

Generally, the anode compartment with oxidation components are written on the left side of the salt bridge and the cathode compartment with reduction components are notified on the right of the salt bridge. The cathode and anode are separated by using the double vertical line which actually represents the salt bridge. The species of different phases are notified by using a single vertical line in the cell notation.

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Chapter 21 Solutions

Chemistry: The Molecular Nature of Matter and Change

Ch. 21.4 - Prob. 21.6AFPCh. 21.4 - Prob. 21.6BFPCh. 21.4 - Prob. 21.7AFPCh. 21.4 - Prob. 21.7BFPCh. 21.4 - Prob. 21.8AFPCh. 21.4 - Prob. 21.8BFPCh. 21.7 - The most ionic and least ionic of the common...Ch. 21.7 - Prob. 21.9BFPCh. 21.7 - Prob. 21.10AFPCh. 21.7 - Prob. 21.10BFPCh. 21.7 - Prob. 21.11AFPCh. 21.7 - Prob. 21.11BFPCh. 21 - Prob. 21.1PCh. 21 - Prob. 21.2PCh. 21 - Prob. 21.3PCh. 21 - Water is used to balance O atoms in the...Ch. 21 - Prob. 21.5PCh. 21 - Prob. 21.6PCh. 21 - Prob. 21.7PCh. 21 - Prob. 21.8PCh. 21 - Prob. 21.9PCh. 21 - Prob. 21.10PCh. 21 - Prob. 21.11PCh. 21 - Prob. 21.12PCh. 21 - Prob. 21.13PCh. 21 - Prob. 21.14PCh. 21 - Prob. 21.15PCh. 21 - Prob. 21.16PCh. 21 - Prob. 21.17PCh. 21 - Prob. 21.18PCh. 21 - Prob. 21.19PCh. 21 - Prob. 21.20PCh. 21 - Aqua regia, a mixture of concentrated HNO3 and...Ch. 21 - Consider the following general voltaic...Ch. 21 - Why does a voltaic cell not operate unless the two...Ch. 21 - Prob. 21.24PCh. 21 - Prob. 21.25PCh. 21 - Prob. 21.26PCh. 21 - Consider the following voltaic cell: In which...Ch. 21 - Consider the following voltaic cell: In which...Ch. 21 - Prob. 21.29PCh. 21 - Prob. 21.30PCh. 21 - A voltaic cell is constructed with an Fe/Fe2+...Ch. 21 - Prob. 21.32PCh. 21 - Prob. 21.33PCh. 21 - Prob. 21.34PCh. 21 - Prob. 21.35PCh. 21 - What does a negative indicate about a redox...Ch. 21 - Prob. 21.37PCh. 21 - In basic solution, Se2− and ions react...Ch. 21 - Prob. 21.39PCh. 21 - Prob. 21.40PCh. 21 - Use the emf series (Appendix D) to arrange each...Ch. 21 - Prob. 21.42PCh. 21 - Prob. 21.43PCh. 21 - Prob. 21.44PCh. 21 - Prob. 21.45PCh. 21 - Prob. 21.46PCh. 21 - Prob. 21.47PCh. 21 - Prob. 21.48PCh. 21 - Prob. 21.49PCh. 21 - Prob. 21.50PCh. 21 - Prob. 21.51PCh. 21 - Prob. 21.52PCh. 21 - Prob. 21.53PCh. 21 - Prob. 21.54PCh. 21 - Prob. 21.55PCh. 21 - Prob. 21.56PCh. 21 - Prob. 21.57PCh. 21 - Prob. 21.58PCh. 21 - Prob. 21.59PCh. 21 - Prob. 21.60PCh. 21 - Prob. 21.61PCh. 21 - Prob. 21.62PCh. 21 - Prob. 21.63PCh. 21 - Prob. 21.64PCh. 21 - Prob. 21.65PCh. 21 - Prob. 21.66PCh. 21 - Prob. 21.67PCh. 21 - Prob. 21.68PCh. 21 - Prob. 21.69PCh. 21 - Prob. 21.70PCh. 21 - Prob. 21.71PCh. 21 - Prob. 21.72PCh. 21 - Prob. 21.73PCh. 21 - Prob. 21.74PCh. 21 - Prob. 21.75PCh. 21 - Prob. 21.76PCh. 21 - Prob. 21.77PCh. 21 - Prob. 21.78PCh. 21 - Prob. 21.79PCh. 21 - Prob. 21.80PCh. 21 - Prob. 21.81PCh. 21 - Consider the following general electrolytic...Ch. 21 - Prob. 21.83PCh. 21 - Prob. 21.84PCh. 21 - Prob. 21.85PCh. 21 - Prob. 21.86PCh. 21 - In the electrolysis of molten NaBr: What product...Ch. 21 - Prob. 21.88PCh. 21 - Prob. 21.89PCh. 21 - Prob. 21.90PCh. 21 - Prob. 21.91PCh. 21 - Prob. 21.92PCh. 21 - Prob. 21.93PCh. 21 - Prob. 21.94PCh. 21 - Prob. 21.95PCh. 21 - Prob. 21.96PCh. 21 - Prob. 21.97PCh. 21 - Write a balanced half-reaction for the product...Ch. 21 - Prob. 21.99PCh. 21 - Prob. 21.100PCh. 21 - Prob. 21.101PCh. 21 - Prob. 21.102PCh. 21 - Prob. 21.103PCh. 21 - Prob. 21.104PCh. 21 - Prob. 21.105PCh. 21 - Prob. 21.106PCh. 21 - Prob. 21.107PCh. 21 - Prob. 21.108PCh. 21 - Prob. 21.109PCh. 21 - Prob. 21.110PCh. 21 - Prob. 21.111PCh. 21 - Prob. 21.112PCh. 21 - Prob. 21.113PCh. 21 - Prob. 21.114PCh. 21 - Prob. 21.115PCh. 21 - Prob. 21.116PCh. 21 - Prob. 21.117PCh. 21 - Prob. 21.118PCh. 21 - Prob. 21.119PCh. 21 - Prob. 21.120PCh. 21 - To examine the effect of ion removal on cell...Ch. 21 - Prob. 21.122PCh. 21 - Prob. 21.123PCh. 21 - Prob. 21.124PCh. 21 - Prob. 21.125PCh. 21 - Prob. 21.126PCh. 21 - Commercial electrolytic cells for producing...Ch. 21 - Prob. 21.128PCh. 21 - Prob. 21.129PCh. 21 - Prob. 21.130PCh. 21 - The following reactions are used in...Ch. 21 - Prob. 21.132PCh. 21 - Prob. 21.133PCh. 21 - Prob. 21.134PCh. 21 - Prob. 21.135PCh. 21 - If the Ecell of the following cell is 0.915 V,...Ch. 21 - Prob. 21.137PCh. 21 - Prob. 21.138PCh. 21 - Prob. 21.139PCh. 21 - Prob. 21.140PCh. 21 - Prob. 21.141PCh. 21 - Prob. 21.142PCh. 21 - Prob. 21.143PCh. 21 - Prob. 21.144PCh. 21 - Prob. 21.145PCh. 21 - Prob. 21.146PCh. 21 - Prob. 21.147PCh. 21 - Both Ti and V are reactive enough to displace H2...Ch. 21 - For the reaction ∆G° = 87.8 kJ/mol Identity the...Ch. 21 - Prob. 21.150PCh. 21 - Two voltaic cells are to be joined so that one...Ch. 21 - Prob. 21.152PCh. 21 - Prob. 21.153P
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