To identify the appropriate base-solvent pair to accomplish a Claisen condensation with the ester Concept introduction: For a Claisen condensation reaction, unwanted transesterification and saponification reactions can be avoided if the base that is added is the same as the alkoxide leaving group on the ester, and if the alcohol solvent is the conjugate acid of that base. Here, the leaving group is CH 3 CH 2 CH 2 O -- .

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Answer 1

Question

Chapter 21, Problem 21.21P

Interpretation Introduction

Interpretation:

To identify the appropriate base-solvent pair to accomplish a Claisen condensation with the ester

Concept introduction:

For a Claisen condensation reaction, unwanted transesterification and saponification reactions can be avoided if the base that is added is the same as the alkoxide leaving group on the ester, and if the alcohol solvent is the conjugate acid of that base.

Here, the leaving group is CH₃CH₂CH₂O^--.

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Answer 2

Question

Chapter 21, Problem 21.21P

Interpretation Introduction

Interpretation:

To identify the appropriate base-solvent pair to accomplish a Claisen condensation with the ester

Concept introduction:

For a Claisen condensation reaction, unwanted transesterification and saponification reactions can be avoided if the base that is added is the same as the alkoxide leaving group on the ester, and if the alcohol solvent is the conjugate acid of that base.

Here, the leaving group is CH₃CH₂CH₂O^--.

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Answer 3

Question

Chapter 21, Problem 21.21P

Interpretation Introduction

Interpretation:

To identify the appropriate base-solvent pair to accomplish a Claisen condensation with the ester

Concept introduction:

For a Claisen condensation reaction, unwanted transesterification and saponification reactions can be avoided if the base that is added is the same as the alkoxide leaving group on the ester, and if the alcohol solvent is the conjugate acid of that base.

Here, the leaving group is CH₃CH₂CH₂O^--.

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Answer 4

Question

Chapter 21, Problem 21.21P

Interpretation Introduction

Interpretation:

To identify the appropriate base-solvent pair to accomplish a Claisen condensation with the ester

Concept introduction:

For a Claisen condensation reaction, unwanted transesterification and saponification reactions can be avoided if the base that is added is the same as the alkoxide leaving group on the ester, and if the alcohol solvent is the conjugate acid of that base.

Here, the leaving group is CH₃CH₂CH₂O^--.

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Answer 5

Chapter 21, Problem 21.21P

Interpretation Introduction

Interpretation:

To identify the appropriate base-solvent pair to accomplish a Claisen condensation with the ester

Concept introduction:

For a Claisen condensation reaction, unwanted transesterification and saponification reactions can be avoided if the base that is added is the same as the alkoxide leaving group on the ester, and if the alcohol solvent is the conjugate acid of that base.

Here, the leaving group is CH₃CH₂CH₂O^--.

Answer 6

Chapter 21, Problem 21.21P

Interpretation Introduction

Interpretation:

To identify the appropriate base-solvent pair to accomplish a Claisen condensation with the ester

Concept introduction:

For a Claisen condensation reaction, unwanted transesterification and saponification reactions can be avoided if the base that is added is the same as the alkoxide leaving group on the ester, and if the alcohol solvent is the conjugate acid of that base.

Here, the leaving group is CH₃CH₂CH₂O^--.

Answer 7

Chapter 21, Problem 21.21P

Interpretation Introduction

Interpretation:

To identify the appropriate base-solvent pair to accomplish a Claisen condensation with the ester

Concept introduction:

For a Claisen condensation reaction, unwanted transesterification and saponification reactions can be avoided if the base that is added is the same as the alkoxide leaving group on the ester, and if the alcohol solvent is the conjugate acid of that base.

Here, the leaving group is CH₃CH₂CH₂O^--.

Answer 8

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Answer 9

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Answer 10

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Answer 11

Ch. 21 - Prob. 21.1P Ch. 21 - Prob. 21.2P Ch. 21 - Prob. 21.3P Ch. 21 - Prob. 21.4P Ch. 21 - Prob. 21.5P Ch. 21 - Prob. 21.6P Ch. 21 - Prob. 21.7P Ch. 21 - Prob. 21.8P Ch. 21 - Prob. 21.9P Ch. 21 - Prob. 21.10P

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Chapter 21 Solutions