Chemistry
9th Edition
ISBN: 9781133611097
Author: Steven S. Zumdahl
Publisher: Cengage Learning
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Chapter 21, Problem 17Q
Interpretation Introduction
Interpretation: The explanations of the fact that compounds of
Concept introduction: The metal that has partially filled
To explain: The facts that, compounds of
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Give the electron configuration and the number of unpaired electrons for: (a) Cr3+; (b) Ti4+; (c) Co3+; (d) Ta2+.
Why are K3[Cr(C2O4)3]*3H2O and K3[Fe(C2O4)3]*3H2O colored, whereas K3[Al(C2O4)3]*3H2O is colorless?
Provide explanations of the following phenomena:
The electron configuration of Ti is [Ar] 4s2 3d2, but that of Cr2+ is [Ar] 3d4.
Chapter 21 Solutions
Chemistry
Ch. 21 - What two first-row transition metals have...Ch. 21 - Prob. 2RQCh. 21 - Prob. 3RQCh. 21 - Prob. 4RQCh. 21 - Prob. 5RQCh. 21 - Prob. 6RQCh. 21 - Prob. 7RQCh. 21 - Prob. 8RQCh. 21 - Prob. 9RQCh. 21 - Prob. 10RQ
Ch. 21 - Prob. 1ALQCh. 21 - Prob. 2ALQCh. 21 - Prob. 3ALQCh. 21 - Prob. 4ALQCh. 21 - Prob. 5QCh. 21 - Four different octahedral chromium coordination...Ch. 21 - Prob. 7QCh. 21 - Prob. 8QCh. 21 - Prob. 9QCh. 21 - Prob. 10QCh. 21 - Prob. 11QCh. 21 - Prob. 12QCh. 21 - Prob. 13QCh. 21 - Prob. 14QCh. 21 - Which of the following ligands are capable of...Ch. 21 - Prob. 16QCh. 21 - Prob. 17QCh. 21 - Prob. 18QCh. 21 - Prob. 19QCh. 21 - Prob. 20QCh. 21 - Prob. 21ECh. 21 - Prob. 22ECh. 21 - Prob. 23ECh. 21 - Prob. 24ECh. 21 - Prob. 25ECh. 21 - Prob. 26ECh. 21 - Prob. 27ECh. 21 - Prob. 28ECh. 21 - Prob. 29ECh. 21 - When an aqueous solution of KCN is added to a...Ch. 21 - Prob. 31ECh. 21 - A coordination compound of cobalt(III) contains...Ch. 21 - Prob. 33ECh. 21 - Prob. 34ECh. 21 - Prob. 35ECh. 21 - Prob. 36ECh. 21 - Prob. 37ECh. 21 - Give formulas for the following complex ions. a....Ch. 21 - Prob. 39ECh. 21 - Prob. 40ECh. 21 - Prob. 41ECh. 21 - Amino acids can act as ligands toward transition...Ch. 21 - Prob. 43ECh. 21 - Prob. 44ECh. 21 - Prob. 45ECh. 21 - Prob. 46ECh. 21 - Prob. 47ECh. 21 - Prob. 48ECh. 21 - Prob. 49ECh. 21 - Prob. 50ECh. 21 - Prob. 51ECh. 21 - Prob. 52ECh. 21 - The CrF64 ion is known to have four unpaired...Ch. 21 - Prob. 54ECh. 21 - Prob. 55ECh. 21 - The complex ion Fe(CN)63 is paramagnetic with one...Ch. 21 - Prob. 57ECh. 21 - Prob. 58ECh. 21 - Prob. 59ECh. 21 - Prob. 60ECh. 21 - The wavelength of absorbed electromagnetic...Ch. 21 - The complex ion NiCL42 has two unpaired electrons,...Ch. 21 - How many unpaired electrons are present in the...Ch. 21 - The complex ion PdCl42is diamagnetic. Propose a...Ch. 21 - Prob. 65ECh. 21 - Prob. 66ECh. 21 - Prob. 67ECh. 21 - Prob. 68ECh. 21 - Silver is sometimes found in nature as large...Ch. 21 - Prob. 70ECh. 21 - Prob. 71AECh. 21 - The compound cisplatin, Pt(NH3)2Cl2, has been...Ch. 21 - Prob. 73AECh. 21 - Prob. 74AECh. 21 - Prob. 75AECh. 21 - Prob. 76AECh. 21 - Prob. 77AECh. 21 - Name the following coordination compounds. a....Ch. 21 - Prob. 79AECh. 21 - Prob. 80AECh. 21 - Prob. 81AECh. 21 - Prob. 82AECh. 21 - Prob. 83CWPCh. 21 - Which of the following molecules exhibit(s)...Ch. 21 - Prob. 85CWPCh. 21 - The following table indicates the number of...Ch. 21 - Prob. 87CWPCh. 21 - Which of the following statement(s) is( are) true?...Ch. 21 - Consider the following complex ion, where A and B...Ch. 21 - Consider the pseudo-octahedral complex ion of...Ch. 21 - Prob. 91CPCh. 21 - Prob. 92CPCh. 21 - Chelating ligands often form more stable complex...Ch. 21 - Prob. 94CPCh. 21 - Prob. 95CPCh. 21 - Prob. 96CPCh. 21 - Sketch and explain the most likely crystal field...Ch. 21 - The ferrate ion, FeO42, is such a powerful...Ch. 21 - Ammonia and potassium iodide solutions are added...Ch. 21 - a. In the absorption spectrum of the complex ion...Ch. 21 - There are three salts that contain complex ions of...
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- Identify, based on the position in the periodic table, the actinide elements among those in the following list: Co, Cm, Cd, Ce, Cf.arrow_forwardGive the number of unpaired electrons in octahedral complexes with strong-field ligands for (a) Rh3+ (b) Mn3+ (c) Ag+ (d) Pt4+ (e) Au3+arrow_forwardSpecify whether the following complexes have isomers.. (a) tetrahedral [Ni(CO)2(Cl)2]. (b) trigonal bipyramidal [Mn(CO)4NO]. (c) [Pt(en)2Cl2]Cl2arrow_forward
- Platinum(II) forms many complexes, among them those with the following ligands. Give the formula and charge of each complex. (a) two ammonia molecules and one oxalate ion (C2O42-) (b) two ammonia molecules, one thiocyanate ion (SCN-), and one bromide ion (c) one ethylenediamine molecule and two nitrite ionsarrow_forwardConsider the reactions 1. [Cr(H2O)6]** + [C©CI(NH3)s]* → [Co(NH3)s(H2O)]²* + [CrCl(H2O)s]** 2. [Fe(CN)6]* + [Mo(CN)s]-→ [Fe(CN)6]³¯ + [Mo(CN)8]* Which one of the following is the correct statement? (i) Both involve an inner sphere mechanism (ii) Both involve an outer sphere mechanism (iii) Reaction 1 follows inner sphere and reaction 2 follows outer sphere mechanism (iv) Reaction 1 follows outer sphere and reaction 2 follows inner sphere mechanism (A) i (B) ii (C) iv (D) iiarrow_forwardHow many sigma bonds are present in [Ti(H2O)6]³+?arrow_forward
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- 5. Explain why [Fe(OH2)6]2+ is stable in aqueous solution but [Ti(OH2)6]4+ has never been isolated. 6. [Fe(OH₂)6]²+ is more readily oxidised in aqueous solution than [Fe(CN)6]. Briefly explain this observation.arrow_forwardWill Fe, Fe 2+, or Fe 3+ react more favorably with CO? Explain your reasoning.arrow_forwardQuestion 3a and 3barrow_forward
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