Introductory Chemistry: An Active Learning Approach
6th Edition
ISBN: 9781305079250
Author: Mark S. Cracolice, Ed Peters
Publisher: Cengage Learning
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Chapter 21, Problem 104E
Interpretation Introduction
Interpretation:
The position of
Concept introduction:
Here, R and
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In an esterification reaction, a carboxylic acid reacts with an excess of alcohol in acidic conditions to form an ester. Draw the structure of the ester product in the reaction between pentanoic acid and 1‑propanol.
What chemical test will you use to differentiate methyl salicylate from methanol?
What kind of reactions are common to carboxylic acids and esters? Provide an example of each.
Chapter 21 Solutions
Introductory Chemistry: An Active Learning Approach
Ch. 21 - Prob. 1ECh. 21 - Prob. 2ECh. 21 - Prob. 3ECh. 21 - Prob. 4ECh. 21 - Prob. 5ECh. 21 - Prob. 6ECh. 21 - Prob. 7ECh. 21 - Prob. 8ECh. 21 - Prob. 9ECh. 21 - Prob. 10E
Ch. 21 - Prob. 11ECh. 21 - Prob. 12ECh. 21 - Prob. 13ECh. 21 - Prob. 14ECh. 21 - Prob. 15ECh. 21 - Prob. 16ECh. 21 - Prob. 17ECh. 21 - Prob. 18ECh. 21 - Prob. 19ECh. 21 - Prob. 20ECh. 21 - Prob. 21ECh. 21 - Prob. 22ECh. 21 - Is the general formula of a cycloalkanes the same...Ch. 21 - Prob. 24ECh. 21 - Draw the skeleton diagram of cyclopentane.Ch. 21 - Prob. 26ECh. 21 - Prob. 27ECh. 21 - Prob. 28ECh. 21 - Prob. 29ECh. 21 - Prob. 30ECh. 21 - Prob. 31ECh. 21 - Prob. 32ECh. 21 - Prob. 33ECh. 21 - Prob. 34ECh. 21 - Prob. 35ECh. 21 - Prob. 36ECh. 21 - What is the difference in bonding and in the...Ch. 21 - Prob. 38ECh. 21 - Draw the structural formula of trichloroethene, a...Ch. 21 - Prob. 40ECh. 21 - Prob. 41ECh. 21 - Prob. 42ECh. 21 - Prob. 43ECh. 21 - Prob. 44ECh. 21 - Give the IUPAC name of the following molecule:Ch. 21 - Give the IUPAC name of the following molecule:Ch. 21 - Prob. 47ECh. 21 - Prob. 48ECh. 21 - Prob. 49ECh. 21 - Prob. 50ECh. 21 - Prob. 51ECh. 21 - Prob. 52ECh. 21 - Prob. 53ECh. 21 - Prob. 54ECh. 21 - Write an equation for the hydrogenation of...Ch. 21 - Prob. 56ECh. 21 - Prob. 57ECh. 21 - Prob. 58ECh. 21 - Prob. 59ECh. 21 - Explain why the ether with formula C2H6O is very...Ch. 21 - Prob. 61ECh. 21 - Prob. 62ECh. 21 - Prob. 63ECh. 21 - Prob. 64ECh. 21 - Prob. 65ECh. 21 - Prob. 66ECh. 21 - Prob. 67ECh. 21 - Prob. 68ECh. 21 - Prob. 69ECh. 21 - Prob. 70ECh. 21 - Prob. 71ECh. 21 - Prob. 72ECh. 21 - Prob. 73ECh. 21 - Prob. 74ECh. 21 - Prob. 75ECh. 21 - Prob. 76ECh. 21 - Prob. 77ECh. 21 - Prob. 78ECh. 21 - Prob. 79ECh. 21 - Prob. 80ECh. 21 - Prob. 81ECh. 21 - Prob. 82ECh. 21 - Prob. 83ECh. 21 - Prob. 84ECh. 21 - Prob. 85ECh. 21 - Prob. 86ECh. 21 - Prob. 87ECh. 21 - Prob. 88ECh. 21 - Prob. 89ECh. 21 - Prob. 90ECh. 21 - Prob. 91ECh. 21 - Prob. 92ECh. 21 - Prob. 93ECh. 21 - Prob. 94ECh. 21 - Distinguish precisely, and in scientific terms,...Ch. 21 - Prob. 96ECh. 21 - What is the difference in bonding and in general...Ch. 21 - Draw all isomers of C4H8.Ch. 21 - Prob. 99ECh. 21 - Prob. 100ECh. 21 - Prob. 101ECh. 21 - Prob. 102ECh. 21 - Prob. 103ECh. 21 - Prob. 104ECh. 21 - Prob. 105ECh. 21 - Prob. 106ECh. 21 - Prob. 107ECh. 21 - Prob. 21.1TCCh. 21 - Prob. 21.2TCCh. 21 - Prob. 21.3TCCh. 21 - Prob. 21.4TCCh. 21 - Prob. 21.5TCCh. 21 - Prob. 21.6TCCh. 21 - Prob. 21.7TCCh. 21 - Prob. 21.8TCCh. 21 - Prob. 21.9TCCh. 21 - Prob. 21.10TCCh. 21 - Prob. 21.11TCCh. 21 - Prob. 21.12TCCh. 21 - Prob. 1CLECh. 21 - Prob. 2CLECh. 21 - Prob. 3CLECh. 21 - Prob. 4CLECh. 21 - Prob. 5CLECh. 21 - Prob. 6CLECh. 21 - Prob. 7CLECh. 21 - Prob. 8CLECh. 21 - Prob. 9CLECh. 21 - Prob. 10CLE
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- How do carboxylic acids and esters differ in their characteristic? Why are there differences in the solubility of the two acids tested? Write the complete (including states) balanced chemical reaction that occurs when acetic acid reacts with sodium bicarbonate.arrow_forwardWrite the chemical equation for the decarboxylation of 2-methyl-propanoic acid. Which is formula of this rule of reaction?arrow_forwardWrite an equation for the reaction of chloroacetic acid (Ka=1.5103) with trimethylamine (Kb=5.9105) . Calculate the equilibrium constant for the reaction. If 0.10 M solutions of these two species are mixed, what will be their concentrations at equilibrium?arrow_forward
- Briefly explain why alcoholic solutions (alcoholic NH2OHꞏHCl, alcoholic KOH, alcoholic HCl) are used in the hydroxamic acid test for esters, what happens if we use other solutions?arrow_forwardExplain the reaction between Methyl Salicylate with acetyl chloride (CH3COCl). Gives your answer in detail from the name of the reaction until the formation of the product. You are advised to give an illustration of the reaction.arrow_forwardGiven the reaction: benzoic anhydride + methanol Draw the structure of the tetrahedral intermediate that is formed and indicate how it dissociates to give the reaction product (use arrows).arrow_forward
- Many substitution reactions are initiated by electrostatic attraction between reactants. Show where this attraction arises in the formation of an amide from an amine and an ester.arrow_forwardDraw Lewis structure for an isomer of C3H6O2 that is a carboxylic acid, and draw another Lewis structure for an isomer of C3H6O2 that is an ester.arrow_forwardWrite the chemical equation for the reaction of ethanoic acid with N-methylethanamine. Which is formula of this rule of reaction?arrow_forward
- Modified true or false. If statement is true, write TRUE, otherwise change the italicized words/phrases in the statement. Cations in hard water like Ca2+ and Mg2+ can form precipitates with carboxylates in soaps, reducing their efficiency as cleansing agents. If an ester is to be prepared with ethanol, using at least 70% ethanol could maximize the yield.arrow_forwardEster formation and ester hydrolysis are exactly the same reaction only written in reverse. General reaction of ester formation: H*, heat R—с—он + Н—о—R' R—с—о-R' + H,O carboxylic acid alcohol carboxylic or phenol ester General reaction of ester hydrolysis: || R—с—OR' + H—оН R—с—оН +R—ОH ester carboxylic acid alcohol or phenol What determines which direction the reaction proceeds and what actually forms? o the boiling point of the carboxylic acid o the presence (or absence) of heat as well as the concentration of reactants and products o the molecular weight of reactants and products o the presence (or absence) of heat as well as the catalystarrow_forwardWhich statement is true? Statement 1: In the synthesis of aspirin, sulfuric acid serves as the catalyst to speed up the reaction and is consumed in the course of the reaction. Statement 2: In the synthesis of aspirin, salicylic acid and acetic anhydride are the starting materials, acetylsalicylic acid is the final product and acetic acid is the by-product.arrow_forward
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