Organic Chemistry: A Guided Inquiry
Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN: 9780618974122
Author: Andrei Straumanis
Publisher: Cengage Learning
Question
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Chapter 2, Problem 3E

(a)

Interpretation Introduction

Interpretation:

The COH bond angle based on the given Lewis structure should be predicted.

  Organic Chemistry: A Guided Inquiry, Chapter 2, Problem 3E , additional homework tip  1

Concept Introduction :

There are three steps to determine the bond angles in a molecule.

  1. Lewis structure should be drawn
  2. The electron domain geometry should be determine using the steric number and VSEPR theory.
  3. Then the shape of the molecule is used to determine the angles between electron domains.

(b)

Interpretation Introduction

Interpretation:

The COH bond angle based on the given Lewis structure should be predicted.

  Organic Chemistry: A Guided Inquiry, Chapter 2, Problem 3E , additional homework tip  2

Concept Introduction :

There are three steps to determine the bond angles in a molecule.

  1. Lewis structure should be drawn
  2. The electron domain geometry should be determine using the steric number and VSEPR theory.
  3. Then the shape of the molecule is used to determine the angles between electron domains.

(c)

Interpretation Introduction

Interpretation:

The prediction expected to be more accurate should be explained.

Concept Introduction :

There are three steps to determine the bond angles in a molecule.

  1. Lewis structure should be drawn
  2. The electron domain geometry should be determine using the steric number and VSEPR theory.
  3. Then the shape of the molecule is used to determine the angles between electron domains.

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The formula for nitryl chloride is CINO2 (in which N is the central atom). a.Draw the Lewis structure for the molecule, including all resonance structures. b.What is the N-O bond order? c.Describe the electron-pair and molecular geometries and give values for all bond angles. d.What is the most polar bond in the molecule? Is the molecule polar? e.The computer program used to calculate electrostatic potential surfaces gave the following charges on atoms in the molecule: A =-0.03, B = -0.26, and C = +0.56. Identify the atoms A, B, and C. Are these calculated charges in accord with your predictions?
Sodium Azide is an ionic compound that is used in automotive air bags. It has the chemical formula NaN3 (The Azide ion is N , and should not be confused with the Nitride ion, N°). a. Give the LEWIS diagram of the Azide ion. b. What is the geometry of the Azide ion? What is the bond angle of the Azide ion?
How does adding an atom affect the position and angles of existing atoms or lone pairs? How does adding a lone pair affect the position and angles of existing atoms and lone pairs? Is the effect of adding bonded atoms and lone pairs to the central similar? Explain your answer. Describe what is meant by the "Steric #". Explain the difference between the terms "Electron Geometry" and "Molecule Geometry". How does changing a bond to a double or triple bond affect the shape of the molecules? List the molecules in Part III where the real bond angles differ from the theoretical model values. Why do you think the values differ?
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