(a)
Interpretation:
Whether the given set of compounds is a constitutional isomer or not has to be indicated.
Concept Introduction:
Constitutional isomers:
Constitutional isomers compounds having same molecular formula but differ in structural formulas. These isomers differ in the connectivity of their atoms in the chain or in the kind of bonds they have (single bond, double bond or triple bond).
(b)
Interpretation:
Whether the given set of compounds is a constitutional isomer or not has to be indicated.
Concept Introduction:
Constitutional isomers:
Constitutional isomers compounds having same molecular formula but differ in structural formulas. These isomers differ in the connectivity of their atoms in the chain or in the kind of bonds they have (single bond, double bond or triple bond).
(c)
Interpretation:
Whether the given set of compounds is a constitutional isomer or not has to be indicated.
Concept Introduction:
Constitutional isomers:
Constitutional isomers compounds having same molecular formula but differ in structural formulas. These isomers differ in the connectivity of their atoms in the chain or in the kind of bonds they have (single bond, double bond or triple bond).
(d)
Interpretation:
Whether the given set of compounds is a constitutional isomer or not has to be indicated.
Concept Introduction:
Constitutional isomers:
Constitutional isomers compounds having same molecular formula but differ in structural formulas. These isomers differ in the connectivity of their atoms in the chain or in the kind of bonds they have (single bond, double bond or triple bond).
(e)
Interpretation:
Whether the given set of compounds is a constitutional isomer or not has to be indicated.
Concept Introduction:
Constitutional isomers:
Constitutional isomers compounds having same molecular formula but differ in structural formulas. These isomers differ in the connectivity of their atoms in the chain or in the kind of bonds they have (single bond, double bond or triple bond).
(f)
Interpretation:
Whether the given set of compounds is a constitutional isomer or not has to be indicated.
Concept Introduction:
Constitutional isomers:
Constitutional isomers compounds having same molecular formula but differ in structural formulas. These isomers differ in the connectivity of their atoms in the chain or in the kind of bonds they have (single bond, double bond or triple bond).
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Chapter 2 Solutions
Organic Chemistry
- Assign a common name to the following ether. (a) CH3 CH₂-0-CH₂CH3 (b) (c) (d) CH3-0- 0-CH₂ CH3 CH3 ___ CH3-O-C-CH3 M CH3arrow_forwardArrange these compounds in order of increasing boiling point. Use the boiling point values of 0°C, 35°C, and 97°C. (a) CH3CH2CH2OH (b) CH3CH2OCH2CH3 (c) CH3CH2CH2CH3arrow_forwardName the following using IUPAC system of nomenclature: (a) CH2 (Cl) CH (NH2) CHO (b) CH3 C (Br) CH2 CH (F) COOH Brarrow_forward
- 5) Use compounds X, Y and Z (shown below) to answer the following questions. H. H3C" "CH3 ОН CH3 compound X compound Y compound Z a) Is compound X classified as cis, trans or neither? b) Is compound Y classified as E, Z or neither? c) Is compound Z classified as R, S or neither? d) Are compounds X and Y constitutional isomers of each other? (YES or NO) e) Are compounds Y and Z constitutional isomers of each other? (YES or NO) f) Classify compound Y as a primary, secondary or tertiary alcohol. g) Which compound(s) is(are) chiral? h) Give the IUPAC name for compound Z, omitting the absolute configuration (R or S) designation. i) In the indicated spaces below, draw stereoisomers of compounds X, Y and Z. stereoisomer of compound X stereoisomer of compound Y stereoisomer of compound Zarrow_forwardDraw structures to correspond with the following common and systematic names:(a) phenyl formate (b) cyclohexyl benzoatearrow_forward6) Which one of the following compounds is an isomer of CH3CH2CH2CH2OH? A) CH3CH2CH2OH B) CH3 CHCH3 OH C) CH3CH2CH2C H D) CH3CH2CHCH3 OH E) СH3ОНarrow_forward
- In each pair of compounds, select the one with the higher boiling point. (a) Acetaldehyde or ethanol (b) Acetone or 3-pentanone (c) Butanal or butane (d) Butanone or 2-butanolarrow_forwardThe cis ketone A is isomerized to a trans ketone B with aqueous NaOH. Asimilar isomerization does not occur with ketone C. (a) Draw thestructure of B using a chair cyclohexane. (b) Label the substituents in Cas cis or trans, and explain the difference in reactivity.arrow_forwardDraw the molecule that corresponds to each IUPAC name. (a) 3,3-dipropoxypentan-1-amine; (b) 2,3,4-trichlorocyclohexanol; (c) 3-cyclopropylpentan-1-ol; (d) 3-(1-methylethyl)cycloheptanaminearrow_forward
- Propylamine (bp 48°C), ethylmethylamine (bp 37°C), and trimethylamine (bp 3°C) are constitutional isomers with the molecular formula C3H9N. Account for the fact that trimethylamine has the lowest boiling point of the three and propylamine has the highest.arrow_forwardProvide the IUPAC name for each of the following compounds. Pay attention to stereochemistry. (c) (a) (Б) О NO2 OH NH2 ОН NH2arrow_forwardThe IUPAC name of the compound is (a) 5-formylhex-2-en-3-one (b) 5-methyl-4-oxohex-2-en-5-al (c) 3-keto-2-methylhex-5-enal (d) 3-keto-2-methylhex-4-enal The correct statement regarding electrophile is (a) electrophile is a negatively charged species and can form a bond by accepting a pair of electrons from another electrophile (b) electrophiles are generally neutral species and can form a bond by accepting a pair of electrons from a nucleophile (c) electrophile can be either neutral or positively charged species and can form a bond by accepting a pair of electrons from a nucleophile (d) electrophile is a negatively charged species and can form a bond by accepting a pair of electrons from a nucleophile, Which among the given molecules can exhibit tautomerism? Ph Ph I III (a) III only (b) Both I and III (d) Both II and III (c) Both I and II 5) Which of the following biphenyls is optically active? IIarrow_forward
- Organic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage Learning