The synthesis of given tertiary amine in three different ways by using reductive amination is to be shown. Concept introduction: Reductive amination is also known as reductive alkylation. This is basically used for the conversion of a carbonyl group to an amine via an intermediate imine. The carbonyl groups generally are ketone or aldehyde .

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Answer 1

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Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 19, Problem 19.49SP

(a)

Interpretation Introduction

Interpretation:

The synthesis of given tertiary amine in three different ways by using reductive amination is to be shown.

Concept introduction:

Reductive amination is also known as reductive alkylation. This is basically used for the conversion of a carbonyl group to an amine via an intermediate imine. The carbonyl groups generally are ketone or aldehyde.

(b)

Interpretation Introduction

Interpretation:

The synthesis of given tertiary amine in three different ways by using acylation-reduction is to be shown.

Concept introduction:

Acylation-reduction is a process in which compound first undergoes acylation process. One of the best acylation processes is Friedel Craft acylation. Then the compound undergoes reduction process by suitable reducing agent or by catalytic reduction in the presence of metals like Ni/Pd/Pt.

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3. Show the mechanism for the following addition/substitution. cat. H2SO4 MeNH2 remove H₂O H H Why doesn't a primary amine need to add a second nucleophile? (i.e. why does it make an imine instead of an aminal?)

4. The following questions concern ethyl acetate, a common laboratory solvent and key ingredient in nail polish remover. a. Draw the stabilizing resonance interaction that lessens the electrophilicity of the carbonyl carbon. H- H Et b. Draw the hyperconjugation interaction that lessens the electrophilicity of the carbonyl carbon below. H- Et c. Which has the more electrophilic carbonyl carbon, ethyl acetate or phenyl acetate? Explain. io VS. ethyl acetate phenyl acetate

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Answer 2

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Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 19, Problem 19.49SP

(a)

Interpretation Introduction

Interpretation:

The synthesis of given tertiary amine in three different ways by using reductive amination is to be shown.

Concept introduction:

Reductive amination is also known as reductive alkylation. This is basically used for the conversion of a carbonyl group to an amine via an intermediate imine. The carbonyl groups generally are ketone or aldehyde.

(b)

Interpretation Introduction

Interpretation:

The synthesis of given tertiary amine in three different ways by using acylation-reduction is to be shown.

Concept introduction:

Acylation-reduction is a process in which compound first undergoes acylation process. One of the best acylation processes is Friedel Craft acylation. Then the compound undergoes reduction process by suitable reducing agent or by catalytic reduction in the presence of metals like Ni/Pd/Pt.

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Answer 3

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 19, Problem 19.49SP

(a)

Interpretation Introduction

Interpretation:

The synthesis of given tertiary amine in three different ways by using reductive amination is to be shown.

Concept introduction:

Reductive amination is also known as reductive alkylation. This is basically used for the conversion of a carbonyl group to an amine via an intermediate imine. The carbonyl groups generally are ketone or aldehyde.

(b)

Interpretation Introduction

Interpretation:

The synthesis of given tertiary amine in three different ways by using acylation-reduction is to be shown.

Concept introduction:

Acylation-reduction is a process in which compound first undergoes acylation process. One of the best acylation processes is Friedel Craft acylation. Then the compound undergoes reduction process by suitable reducing agent or by catalytic reduction in the presence of metals like Ni/Pd/Pt.

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Answer 4

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 19, Problem 19.49SP

(a)

Interpretation Introduction

Interpretation:

The synthesis of given tertiary amine in three different ways by using reductive amination is to be shown.

Concept introduction:

Reductive amination is also known as reductive alkylation. This is basically used for the conversion of a carbonyl group to an amine via an intermediate imine. The carbonyl groups generally are ketone or aldehyde.

(b)

Interpretation Introduction

Interpretation:

The synthesis of given tertiary amine in three different ways by using acylation-reduction is to be shown.

Concept introduction:

Acylation-reduction is a process in which compound first undergoes acylation process. One of the best acylation processes is Friedel Craft acylation. Then the compound undergoes reduction process by suitable reducing agent or by catalytic reduction in the presence of metals like Ni/Pd/Pt.

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Answer 5

Chapter 19, Problem 19.49SP

(a)

Interpretation Introduction

Interpretation:

The synthesis of given tertiary amine in three different ways by using reductive amination is to be shown.

Concept introduction:

Reductive amination is also known as reductive alkylation. This is basically used for the conversion of a carbonyl group to an amine via an intermediate imine. The carbonyl groups generally are ketone or aldehyde.

(b)

Interpretation Introduction

Interpretation:

The synthesis of given tertiary amine in three different ways by using acylation-reduction is to be shown.

Concept introduction:

Acylation-reduction is a process in which compound first undergoes acylation process. One of the best acylation processes is Friedel Craft acylation. Then the compound undergoes reduction process by suitable reducing agent or by catalytic reduction in the presence of metals like Ni/Pd/Pt.

Answer 6

Chapter 19, Problem 19.49SP

(a)

Interpretation Introduction

Interpretation:

The synthesis of given tertiary amine in three different ways by using reductive amination is to be shown.

Concept introduction:

Reductive amination is also known as reductive alkylation. This is basically used for the conversion of a carbonyl group to an amine via an intermediate imine. The carbonyl groups generally are ketone or aldehyde.

Answer 7

Chapter 19, Problem 19.49SP

(a)

Interpretation Introduction

Interpretation:

The synthesis of given tertiary amine in three different ways by using reductive amination is to be shown.

Concept introduction:

Reductive amination is also known as reductive alkylation. This is basically used for the conversion of a carbonyl group to an amine via an intermediate imine. The carbonyl groups generally are ketone or aldehyde.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The synthesis of given tertiary amine in three different ways by using acylation-reduction is to be shown.

Concept introduction:

Acylation-reduction is a process in which compound first undergoes acylation process. One of the best acylation processes is Friedel Craft acylation. Then the compound undergoes reduction process by suitable reducing agent or by catalytic reduction in the presence of metals like Ni/Pd/Pt.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The synthesis of given tertiary amine in three different ways by using acylation-reduction is to be shown.

Concept introduction:

Acylation-reduction is a process in which compound first undergoes acylation process. One of the best acylation processes is Friedel Craft acylation. Then the compound undergoes reduction process by suitable reducing agent or by catalytic reduction in the presence of metals like Ni/Pd/Pt.

Answer 10

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Answer 12

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Answer 13

Ch. 19.2A - Prob. 19.1P Ch. 19.2B - Prob. 19.2P Ch. 19.2B - Give correct names for the following amines:Ch. 19.3 - Prob. 19.4P Ch. 19.4 - Prob. 19.5P Ch. 19.6 - Rank each set of compounds in order of increasing...Ch. 19.8A - Prob. 19.7P Ch. 19.8C - Prob. 19.8P Ch. 19.8C - Prob. 19.9P Ch. 19.8D - a. Show how fragmentation occurs to give the base...

Solution Summary: The author explains the synthesis of tertiary amine in three different ways by using reductive amination.

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