Physical Chemistry
2nd Edition
ISBN: 9781133958437
Author: Ball, David W. (david Warren), BAER, Tomas
Publisher: Wadsworth Cengage Learning,
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Chapter 19, Problem 19.30E
Interpretation Introduction
Interpretation:
The relative values of
Concept introduction:
A gas is made up of many atoms or molecules that move with very high speeds. The kinetic energy of gases is very high. Every molecule or atom present in a gas can have a different velocity. Therefore, root mean square speed, most probable velocity, and mean velocity are calculated for a gas.
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The average kinetic energy of the molecules in a gas sample depends only on the temperature, ?.
However, given the same kinetic energies, a lighter molecule will move faster than a heavier molecule, as shown in the equation for rms speed
rms speed=3??ℳ‾‾‾‾‾√
where ?=8.314 J/(mol⋅K)
and ℳ
is molar mass in kilograms per mole. Note that a joule is the same as a kilogram‑meter squared per second squared (kg·m2/s2).
What is the rms speed of N2
molecules at 345 K?
The average kinetic energy of the molecules in a gas sample depends only on the temperature, ?.
However, given the same kinetic energies, a lighter molecule will move faster than a heavier molecule, as shown in the equation for rms speed
rms speed=3??ℳ‾‾‾‾‾√
where ?=8.314 J/(mol⋅K)
and ℳ
is molar mass in kilograms per mole. Note that a joule is the same as a kilogram‑meter squared per second squared (kg·m2/s2).
What is the rms speed of N2
molecules at 345 K?
50
Assume that a room at sea level is filled with a gas of nitrogen molecules N2
in thermal equilibrium at -10.0 °C (negative ten degrees Celsius). There are 7 protons and 7
neutrons in the nucleus of a nitrogen atom N. You may take the masses of the proton and the
neutron to be the same, and ignore the mass of the electrons. 1 atm=1.01x10 N/m?,
h=1.05x10 34 J-s, m,-1.67x1027 kg, ks = 1.38x1023 J/K.
%3!
a) What is the (particle) number density n according to the ideal gas law?
b) Compare the number density n with the quantum concentration na at the same
temperature.
c) Is the gas in the classical or quantum regime?
The average kinetic energy of the molecules in a gas sample depends only on the temperature, ?.
However, given the same kinetic energies, a lighter molecule will move faster than a heavier molecule, as shown in the equation for rms speed
rms speed=3??ℳ‾‾‾‾‾√
where ?=8.314 J/(mol⋅K)
and ℳ
is molar mass in kilograms per mole. Note that a joule is the same as a kilogram‑meter squared per second squared (kg·m2/s2).
What is the rms speed of F2
molecules at 375 K?
What is the rms speed?
What is the rms speed of He atoms at 375 k?
Chapter 19 Solutions
Physical Chemistry
Ch. 19 - Prob. 19.1ECh. 19 - What is the kinetic energy of a single atom of...Ch. 19 - Prob. 19.3ECh. 19 - One mole of Ne atoms confined to a volume of 10.0L...Ch. 19 - Prob. 19.5ECh. 19 - Prob. 19.6ECh. 19 - Prob. 19.7ECh. 19 - Prob. 19.8ECh. 19 - Prob. 19.9ECh. 19 - Prob. 19.10E
Ch. 19 - Prob. 19.11ECh. 19 - Interstellar space can be considered as having...Ch. 19 - Prob. 19.13ECh. 19 - SF6 is a gas at room temperature, 295K. What is...Ch. 19 - Prob. 19.15ECh. 19 - Prob. 19.16ECh. 19 - If relativistic effects were ignored, what...Ch. 19 - Prob. 19.18ECh. 19 - Prob. 19.19ECh. 19 - Prob. 19.20ECh. 19 - Prob. 19.21ECh. 19 - Prob. 19.22ECh. 19 - Prob. 19.23ECh. 19 - Prob. 19.24ECh. 19 - What is the ratio of vrms/vmostprob for any gas at...Ch. 19 - Prob. 19.26ECh. 19 - Prob. 19.27ECh. 19 - Prob. 19.28ECh. 19 - Prob. 19.29ECh. 19 - Prob. 19.30ECh. 19 - Prob. 19.31ECh. 19 - The previous exercise gives an expression for...Ch. 19 - Prob. 19.33ECh. 19 - Prob. 19.34ECh. 19 - Prob. 19.35ECh. 19 - What must the pressure be if the mean free path of...Ch. 19 - Prob. 19.37ECh. 19 - Prob. 19.38ECh. 19 - Prob. 19.39ECh. 19 - Explain why the molecular diameter for argon, at...Ch. 19 - Prob. 19.41ECh. 19 - Prob. 19.42ECh. 19 - Prob. 19.43ECh. 19 - A 1.00-mol sample of Xe gas is kept at a...Ch. 19 - Prob. 19.45ECh. 19 - Prob. 19.46ECh. 19 - Prob. 19.47ECh. 19 - Prob. 19.48ECh. 19 - Prob. 19.49ECh. 19 - Consider a gas mixture containing equal...Ch. 19 - The inverse of the collision rate, 1/z, is the...Ch. 19 - Prob. 19.52ECh. 19 - Prob. 19.53ECh. 19 - Prob. 19.54ECh. 19 - Prob. 19.55ECh. 19 - Estimate the rate at which Hg effuses out a hole...Ch. 19 - Prob. 19.57ECh. 19 - Knudsen effusion cells are used to determine vapor...Ch. 19 - Prob. 19.59ECh. 19 - Prob. 19.60ECh. 19 - Prob. 19.61ECh. 19 - Prob. 19.62ECh. 19 - Prob. 19.63ECh. 19 - Prob. 19.64ECh. 19 - Prob. 19.65ECh. 19 - Prob. 19.66ECh. 19 - Prob. 19.67ECh. 19 - Prob. 19.68ECh. 19 - Prob. 19.69ECh. 19 - Prob. 19.70ECh. 19 - Prob. 19.71ECh. 19 - Prob. 19.72ECh. 19 - Prob. 19.73E
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