University Physics with Modern Physics (14th Edition)
University Physics with Modern Physics (14th Edition)
14th Edition
ISBN: 9780321973610
Author: Hugh D. Young, Roger A. Freedman
Publisher: PEARSON
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Chapter 18, Problem 18.69P

(a)

To determine

Plot the graph of U(r) and F(r) Vs r .

(b)

To determine

Show the locations of points on graph of U(r) and F(r) Vs r at which U(r)=0 and F(r)=0 .

(c)

To determine

The values of r1 and r2 in terms of Ro and also the ratio r1r2 .

(d)

To determine

The work that has to be done to pull the molecules at r apart.

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One description of the potential energy of a diatomic molecule is given by the Lennard–Jones potential,                          U = (A)/(r12) - (B)/(r6)where A and B are constants and r is the separation distance between the atoms. For the H2 molecule, take A = 0.124 x 10-120 eV ⋅ m12 and B = 1.488 x 10-60 eV ⋅ m6. Find (a) the separation distance r0 at which the energy of the molecule is a minimum and (b) the energy E required to break up theH2 molecule.
The potential energy of two atoms in a diatomic molecule is approximated by U(r) = a/r12-b/r6, where r is the spacing between atoms and a and b are positive constants. Suppose the distance between the two atoms is equal to the equilibrium distance found in part A. What minimum energy must be added to the molecule to dissociate it - that is, to separate the two atoms to an infinite distance apart? This is called the dissociation energy of the molecule. Express your answer in terms of the variables a and b. For the molecule CO, the equilibrium distance between the carbon and oxygen atoms is 1.13\times 10-10m and the dissociation energy is 1.54\times 10-18J per molecule. Find the value of the constant a. Express your answer in joules times meter in the twelth power. Find the value of the constant b. Express your answer in joules times meter in the sixth power.
One description of the potential energy of a diatomic molecule is given by the Lennard–Jones potential,                                            U = (A)/(r12) - (B)/(r6)where A and B are constants and r is the separation distance between the atoms. Find, in terms of A and B, (a) the value r0 at which the energy is a minimum and (b) the energy E required to break up a diatomic molecule.

Chapter 18 Solutions

University Physics with Modern Physics (14th Edition)

Ch. 18 - Unwrapped food placed in a freezer experiences...Ch. 18 - A group of students drove from their university...Ch. 18 - The derivation of the ideal-gas equation included...Ch. 18 - A rigid, perfectly insulated container has a...Ch. 18 - (a) Which has more atoms: a kilogram of hydrogen...Ch. 18 - Use the concepts of the kinetic-molecular model to...Ch. 18 - The proportions of various gases in the earths...Ch. 18 - Comment on the following statement: When two gases...Ch. 18 - Prob. 18.13DQCh. 18 - The temperature of an ideal gas is directly...Ch. 18 - If the pressure of an ideal monatomic gas is...Ch. 18 - In deriving the ideal-gas equation from the...Ch. 18 - Imagine a special air filter placed in a window of...Ch. 18 - Prob. 18.18DQCh. 18 - Consider two specimens of ideal gas at the same...Ch. 18 - The temperature of an ideal monatomic gas is...Ch. 18 - Prob. 18.21DQCh. 18 - (a) If you apply the same amount of heat to 1.00...Ch. 18 - Prob. 18.23DQCh. 18 - In a gas that contains N molecules, is it accurate...Ch. 18 - The atmosphere of the planet Mars is 95.3% carbon...Ch. 18 - Prob. 18.26DQCh. 18 - Ice is slippery to walk on, and especially...Ch. 18 - Hydrothermal vents are openings in the ocean floor...Ch. 18 - The dark areas on the moons surface are called...Ch. 18 - In addition to the normal cooking directions...Ch. 18 - A 20.0-L tank contains 4.86 104 kg of helium at...Ch. 18 - Helium gas with a volume of 3.20 L, under a...Ch. 18 - A cylindrical tank has a tight-fitting piston that...Ch. 18 - A 3.00-L lank contains air at 3.00 atm and 20.0C....Ch. 18 - Planetary Atmospheres. (a) Calculate the density...Ch. 18 - You have several identical balloons. You...Ch. 18 - A Jaguar XK8 convertible has an eight-cylinder...Ch. 18 - A welder using a tank of volume 0.0750 m3 fills it...Ch. 18 - A large cylindrical tank contains 0.750 m3 of...Ch. 18 - An empty cylindrical canister 1.50 m long and 90.0...Ch. 18 - The gas inside a balloon will always have a...Ch. 18 - An ideal gas has a density of 1.33 106 g/cm3 at...Ch. 18 - If a certain amount of ideal gas occupies a volume...Ch. 18 - A diver observes a bubble of air rising from the...Ch. 18 - A metal tank with volume 3.10 L will burst if the...Ch. 18 - Three moles of an ideal gas are in a rigid cubical...Ch. 18 - With the assumptions of Example 18.4 (Section...Ch. 18 - With the assumption that the air temperature is a...Ch. 18 - (a) Calculate the mass of nitrogen present in a...Ch. 18 - At an altitude of 11,000 m (a typical cruising...Ch. 18 - Prob. 18.21ECh. 18 - Prob. 18.22ECh. 18 - Modern vacuum pumps make it easy to attain...Ch. 18 - The Lagoon Nebula (Fig. E18.24) is a cloud of...Ch. 18 - In a gas at standard conditions, what is the...Ch. 18 - How Close Together Are Gas Molecules? Consider an...Ch. 18 - (a) What is the total translational kinetic energy...Ch. 18 - A flask contains a mixture of neon (Ne), krypton...Ch. 18 - We have two equal-size boxes, A and B. Each box...Ch. 18 - A container with volume 1.64 L is initially...Ch. 18 - Prob. 18.31ECh. 18 - Martian Climate. The atmosphere of Mars is mostly...Ch. 18 - Prob. 18.33ECh. 18 - Calculate the mean free path of air molecules at...Ch. 18 - At what temperature is the root-mean-square speed...Ch. 18 - Prob. 18.36ECh. 18 - Prob. 18.37ECh. 18 - Perfectly rigid containers each hold n moles of...Ch. 18 - (a) Compute the specific heat at constant volume...Ch. 18 - Prob. 18.40ECh. 18 - Prob. 18.41ECh. 18 - For a gas of nitrogen molecules (N2), what must...Ch. 18 - Prob. 18.43ECh. 18 - Meteorology. The vapor pressure is the pressure of...Ch. 18 - Calculate the volume of 1.00 mol of liquid water...Ch. 18 - A physics lecture room at 1.00 atm and 27.0C has a...Ch. 18 - CP BIO The Effect of Altitude on the Lungs. (a)...Ch. 18 - CP BIO The Bends. If deep-sea divers rise to the...Ch. 18 - CP A hot-air balloon stays aloft because hot air...Ch. 18 - In an evacuated enclosure, a vertical cylindrical...Ch. 18 - A cylinder 1.00 m tall with inside diameter 0.120...Ch. 18 - CP During a test dive in 1939, prior to being...Ch. 18 - Atmosphere or Titan. Titan, the largest satellite...Ch. 18 - Pressure on Venus. At the surface of Venus the...Ch. 18 - An automobile tire has a volume of 0.0150 m3 on a...Ch. 18 - A flask with a volume of 1.50 L, provided with a...Ch. 18 - CP A balloon of volume 750 m3 is to be filled with...Ch. 18 - A vertical cylindrical tank contains 1.80 mol of...Ch. 18 - CP A large tank of water has a hose connected to...Ch. 18 - CP A light, plastic sphere with mass m = 9.00 g...Ch. 18 - Prob. 18.61PCh. 18 - BIO A person at rest inhales 0.50 L of air with...Ch. 18 - You have two identical containers, one containing...Ch. 18 - The size of an oxygen molecule is about 2.0 1010...Ch. 18 - A sealed box contains a monatomic ideal gas. The...Ch. 18 - Helium gas is in a cylinder that has rigid walls....Ch. 18 - You blow up a spherical balloon to a diameter of...Ch. 18 - CP (a) Compute the increase in gravitational...Ch. 18 - Prob. 18.69PCh. 18 - Prob. 18.70PCh. 18 - It is possible to make crystalline solids that are...Ch. 18 - Hydrogen on the Sun. The surface of the sun has a...Ch. 18 - Prob. 18.73PCh. 18 - Planetary Atmospheres. (a) The temperature near...Ch. 18 - Prob. 18.75PCh. 18 - Prob. 18.76PCh. 18 - CALC (a) Explain why in a gas of N molecules, the...Ch. 18 - Prob. 18.78PCh. 18 - CP Oscillations of a Piston. A vertical cylinder...Ch. 18 - Prob. 18.80PCh. 18 - DATA The Dew Point and Clouds. The vapor pressure...Ch. 18 - DATA The statistical quantities average value and...Ch. 18 - CP Dark Nebulae and the Interstellar Medium. The...Ch. 18 - CALC Earths Atmosphere. In t he troposphere, the...Ch. 18 - Prob. 18.85PPCh. 18 - Estimate the ratio of the thermal conductivity of...Ch. 18 - The rate of effusionthat is, leakage of a gas...
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