General Chemistry
General Chemistry
4th Edition
ISBN: 9781891389603
Author: Donald A. McQuarrie, Peter A. Rock, Ethan B. Gallogly
Publisher: University Science Books
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Chapter 17, Problem 17.44P
Interpretation Introduction

Interpretation:

A graph of time versus 1/[HBr] has to be drawn to prove the second order reaction.  Also, the value of rate constant of the reaction has to be determined.

Concept Introduction:

For the second-order decomposition of a single reactant A, the rate expression is

    rateofreaction=-Δ[A]Δt=k[A]2By using elementary calculus, the concentrationof A at any time. The result is1[A]=1[A]o+kt

By comparing the above equation to the equation y=mx+b, it is clear that a plot of

1/[A] versus time, t, is a straight line whose slope is the rate constant, k.

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Chapter 17 Solutions

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