General Chemistry
General Chemistry
4th Edition
ISBN: 9781891389603
Author: Donald A. McQuarrie, Peter A. Rock, Ethan B. Gallogly
Publisher: University Science Books
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Chapter 17, Problem 17.25P
Interpretation Introduction

Interpretation:

A graph of time versus ln([C2H4O]/M) has to be drawn to prove the first order reaction.  Also, the value of rate constant of the reaction has to be determined.

Concept Introduction:

For the first-order decomposition of a single reactant A, the rate expression is

    rateofreaction=-Δ[A]Δt=k[A]By using elementary calculus, the concentrationof A at any time. The result isln[A][A°]=-kt

By comparing the above equation to the equation y=mx+b, it is clear that a plot of

ln[A] versus time, t, is a straight line whose slope is the rate constant, -k.

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Chapter 17 Solutions

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