(a) Interpretation: Whether 1-methoxynapthalene nitrates more rapidly or more slowly than naphthalene at carbon -4 is to be stated. The reason for this is to be explained. Concept introduction: Nitration is a process in which an aromatic compound is nitrated by electrophilic substitution mechanism in presence of concentrated sulfuric acid and concentrated nitric acid. Electron donating groups substituted on the aromatic ring are those which donates electron to the aromatic ring. Electron donating groups are ortho and para-directing.

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Answer 1

Question

Chapter 16, Problem 16.62AP

Interpretation Introduction

(a)

Interpretation:

Whether 1-methoxynapthalene nitrates more rapidly or more slowly than naphthalene at carbon -4 is to be stated. The reason for this is to be explained.

Concept introduction:

Nitration is a process in which an aromatic compound is nitrated by electrophilic substitution mechanism in presence of concentrated sulfuric acid and concentrated nitric acid. Electron donating groups substituted on the aromatic ring are those which donates electron to the aromatic ring. Electron donating groups are ortho and para-directing.

Interpretation Introduction

(b)

Interpretation:

Whether 1-methoxynapthalene nitrates more rapidly or more slowly than naphthalene at carbon -5 is to be stated. The reason for this is to be explained.

Concept introduction:

Nitration is a process in which an aromatic compound is nitrated by electrophilic substitution mechanism in presence of concentrated sulfuric acid and concentrated nitric acid. Electron donating groups substituted on the aromatic ring are those which donates electron to the aromatic ring. Electron donating groups are ortho and para-directing.

Interpretation Introduction

(c)

Interpretation:

Whether 1-methoxynapthalene nitrates more rapidly or more slowly than naphthalene at carbon -6 is to be stated. The reason for this is to be explained.

Concept introduction:

Nitration is a process in which an aromatic compound is nitrated by electrophilic substitution mechanism in presence of concentrated sulfuric acid and concentrated nitric acid. Electron donating groups substituted on the aromatic ring are those which donates electron to the aromatic ring. Electron donating groups are ortho and para-directing.

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Answer 2

Question

Chapter 16, Problem 16.62AP

Interpretation Introduction

(a)

Interpretation:

Whether 1-methoxynapthalene nitrates more rapidly or more slowly than naphthalene at carbon -4 is to be stated. The reason for this is to be explained.

Concept introduction:

Nitration is a process in which an aromatic compound is nitrated by electrophilic substitution mechanism in presence of concentrated sulfuric acid and concentrated nitric acid. Electron donating groups substituted on the aromatic ring are those which donates electron to the aromatic ring. Electron donating groups are ortho and para-directing.

Interpretation Introduction

(b)

Interpretation:

Whether 1-methoxynapthalene nitrates more rapidly or more slowly than naphthalene at carbon -5 is to be stated. The reason for this is to be explained.

Concept introduction:

Nitration is a process in which an aromatic compound is nitrated by electrophilic substitution mechanism in presence of concentrated sulfuric acid and concentrated nitric acid. Electron donating groups substituted on the aromatic ring are those which donates electron to the aromatic ring. Electron donating groups are ortho and para-directing.

Interpretation Introduction

(c)

Interpretation:

Whether 1-methoxynapthalene nitrates more rapidly or more slowly than naphthalene at carbon -6 is to be stated. The reason for this is to be explained.

Concept introduction:

Nitration is a process in which an aromatic compound is nitrated by electrophilic substitution mechanism in presence of concentrated sulfuric acid and concentrated nitric acid. Electron donating groups substituted on the aromatic ring are those which donates electron to the aromatic ring. Electron donating groups are ortho and para-directing.

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Answer 3

Question

Chapter 16, Problem 16.62AP

Interpretation Introduction

(a)

Interpretation:

Whether 1-methoxynapthalene nitrates more rapidly or more slowly than naphthalene at carbon -4 is to be stated. The reason for this is to be explained.

Concept introduction:

Nitration is a process in which an aromatic compound is nitrated by electrophilic substitution mechanism in presence of concentrated sulfuric acid and concentrated nitric acid. Electron donating groups substituted on the aromatic ring are those which donates electron to the aromatic ring. Electron donating groups are ortho and para-directing.

Interpretation Introduction

(b)

Interpretation:

Whether 1-methoxynapthalene nitrates more rapidly or more slowly than naphthalene at carbon -5 is to be stated. The reason for this is to be explained.

Concept introduction:

Nitration is a process in which an aromatic compound is nitrated by electrophilic substitution mechanism in presence of concentrated sulfuric acid and concentrated nitric acid. Electron donating groups substituted on the aromatic ring are those which donates electron to the aromatic ring. Electron donating groups are ortho and para-directing.

Interpretation Introduction

(c)

Interpretation:

Whether 1-methoxynapthalene nitrates more rapidly or more slowly than naphthalene at carbon -6 is to be stated. The reason for this is to be explained.

Concept introduction:

Nitration is a process in which an aromatic compound is nitrated by electrophilic substitution mechanism in presence of concentrated sulfuric acid and concentrated nitric acid. Electron donating groups substituted on the aromatic ring are those which donates electron to the aromatic ring. Electron donating groups are ortho and para-directing.

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Answer 4

Question

Chapter 16, Problem 16.62AP

Interpretation Introduction

(a)

Interpretation:

Whether 1-methoxynapthalene nitrates more rapidly or more slowly than naphthalene at carbon -4 is to be stated. The reason for this is to be explained.

Concept introduction:

Nitration is a process in which an aromatic compound is nitrated by electrophilic substitution mechanism in presence of concentrated sulfuric acid and concentrated nitric acid. Electron donating groups substituted on the aromatic ring are those which donates electron to the aromatic ring. Electron donating groups are ortho and para-directing.

Interpretation Introduction

(b)

Interpretation:

Whether 1-methoxynapthalene nitrates more rapidly or more slowly than naphthalene at carbon -5 is to be stated. The reason for this is to be explained.

Concept introduction:

Nitration is a process in which an aromatic compound is nitrated by electrophilic substitution mechanism in presence of concentrated sulfuric acid and concentrated nitric acid. Electron donating groups substituted on the aromatic ring are those which donates electron to the aromatic ring. Electron donating groups are ortho and para-directing.

Interpretation Introduction

(c)

Interpretation:

Whether 1-methoxynapthalene nitrates more rapidly or more slowly than naphthalene at carbon -6 is to be stated. The reason for this is to be explained.

Concept introduction:

Nitration is a process in which an aromatic compound is nitrated by electrophilic substitution mechanism in presence of concentrated sulfuric acid and concentrated nitric acid. Electron donating groups substituted on the aromatic ring are those which donates electron to the aromatic ring. Electron donating groups are ortho and para-directing.

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Answer 5

Chapter 16, Problem 16.62AP

Interpretation Introduction

(a)

Interpretation:

Whether 1-methoxynapthalene nitrates more rapidly or more slowly than naphthalene at carbon -4 is to be stated. The reason for this is to be explained.

Concept introduction:

Nitration is a process in which an aromatic compound is nitrated by electrophilic substitution mechanism in presence of concentrated sulfuric acid and concentrated nitric acid. Electron donating groups substituted on the aromatic ring are those which donates electron to the aromatic ring. Electron donating groups are ortho and para-directing.

Interpretation Introduction

(b)

Interpretation:

Whether 1-methoxynapthalene nitrates more rapidly or more slowly than naphthalene at carbon -5 is to be stated. The reason for this is to be explained.

Concept introduction:

Nitration is a process in which an aromatic compound is nitrated by electrophilic substitution mechanism in presence of concentrated sulfuric acid and concentrated nitric acid. Electron donating groups substituted on the aromatic ring are those which donates electron to the aromatic ring. Electron donating groups are ortho and para-directing.

Interpretation Introduction

(c)

Interpretation:

Whether 1-methoxynapthalene nitrates more rapidly or more slowly than naphthalene at carbon -6 is to be stated. The reason for this is to be explained.

Concept introduction:

Nitration is a process in which an aromatic compound is nitrated by electrophilic substitution mechanism in presence of concentrated sulfuric acid and concentrated nitric acid. Electron donating groups substituted on the aromatic ring are those which donates electron to the aromatic ring. Electron donating groups are ortho and para-directing.

Answer 6

Chapter 16, Problem 16.62AP

Interpretation Introduction

(a)

Interpretation:

Whether 1-methoxynapthalene nitrates more rapidly or more slowly than naphthalene at carbon -4 is to be stated. The reason for this is to be explained.

Concept introduction:

Nitration is a process in which an aromatic compound is nitrated by electrophilic substitution mechanism in presence of concentrated sulfuric acid and concentrated nitric acid. Electron donating groups substituted on the aromatic ring are those which donates electron to the aromatic ring. Electron donating groups are ortho and para-directing.

Answer 7

Chapter 16, Problem 16.62AP

Interpretation Introduction

(a)

Interpretation:

Whether 1-methoxynapthalene nitrates more rapidly or more slowly than naphthalene at carbon -4 is to be stated. The reason for this is to be explained.

Concept introduction:

Nitration is a process in which an aromatic compound is nitrated by electrophilic substitution mechanism in presence of concentrated sulfuric acid and concentrated nitric acid. Electron donating groups substituted on the aromatic ring are those which donates electron to the aromatic ring. Electron donating groups are ortho and para-directing.

Answer 8

Interpretation Introduction

(b)

Interpretation:

Whether 1-methoxynapthalene nitrates more rapidly or more slowly than naphthalene at carbon -5 is to be stated. The reason for this is to be explained.

Concept introduction:

Nitration is a process in which an aromatic compound is nitrated by electrophilic substitution mechanism in presence of concentrated sulfuric acid and concentrated nitric acid. Electron donating groups substituted on the aromatic ring are those which donates electron to the aromatic ring. Electron donating groups are ortho and para-directing.

Answer 9

Interpretation Introduction

(b)

Interpretation:

Whether 1-methoxynapthalene nitrates more rapidly or more slowly than naphthalene at carbon -5 is to be stated. The reason for this is to be explained.

Concept introduction:

Nitration is a process in which an aromatic compound is nitrated by electrophilic substitution mechanism in presence of concentrated sulfuric acid and concentrated nitric acid. Electron donating groups substituted on the aromatic ring are those which donates electron to the aromatic ring. Electron donating groups are ortho and para-directing.

Answer 10

Interpretation Introduction

(c)

Interpretation:

Whether 1-methoxynapthalene nitrates more rapidly or more slowly than naphthalene at carbon -6 is to be stated. The reason for this is to be explained.

Concept introduction:

Nitration is a process in which an aromatic compound is nitrated by electrophilic substitution mechanism in presence of concentrated sulfuric acid and concentrated nitric acid. Electron donating groups substituted on the aromatic ring are those which donates electron to the aromatic ring. Electron donating groups are ortho and para-directing.

Answer 11

Interpretation Introduction

(c)

Interpretation:

Whether 1-methoxynapthalene nitrates more rapidly or more slowly than naphthalene at carbon -6 is to be stated. The reason for this is to be explained.

Concept introduction:

Nitration is a process in which an aromatic compound is nitrated by electrophilic substitution mechanism in presence of concentrated sulfuric acid and concentrated nitric acid. Electron donating groups substituted on the aromatic ring are those which donates electron to the aromatic ring. Electron donating groups are ortho and para-directing.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 16 - Prob. 16.1P Ch. 16 - Prob. 16.2P Ch. 16 - Prob. 16.3P Ch. 16 - Prob. 16.4P Ch. 16 - Prob. 16.5P Ch. 16 - Prob. 16.6P Ch. 16 - Prob. 16.7P Ch. 16 - Prob. 16.8P Ch. 16 - Prob. 16.9P Ch. 16 - Prob. 16.10P

Solution Summary: The author explains that 1-methoxynapthalene nitrates more rapidly or more slowly than the aromatic compound.

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