Organic Chemistry
Organic Chemistry
6th Edition
ISBN: 9781936221349
Author: Marc Loudon, Jim Parise
Publisher: W. H. Freeman
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Chapter 16, Problem 16.47AP
Interpretation Introduction

Interpretation:

The reason for the fact that the nitration of phenyl acetate gives para-substituted nitro compound, whereas nitration of dimethyl phenyl phosphate gives meta substituted nitro compound is to be stated.

Concept introduction:

The replacement of hydrogen atom attached to a carbon atom of electron-rich benzene ring by an electrophile is known as electrophilic aromatic substitution reaction. The rate of electrophilic aromatic substitution reaction depends on the substituted group on the aromatic ring. The ring deactivating group retards the electrophilic aromatic substitution reaction and ring activating group enhances the electrophilic aromatic substitution reaction.

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In the following acid - base reactions, a) Draw Lewis structures of the reactants and the products. b) Determine which species are acting as electrophiles (acids) and which are acting as nucleophiles (bases). c) Use the curved - arrow formalism to show the movement of electron pairs in these reactions and the imaginary movement in the resonance hybrids of the products. d) Indicate which reactions are best termed Brønsted-Lowry acid - base reactions i. CH3CHO + HCI-- > CH3CH2O + + Cl- ii. CH3CHO + OH- - - > CH3CO-(OH) H
(b) A compound with the molecular formula C4H9CI has four structural isomers. Write the structural formulas for all the four isomers. (c) Arrange the following compounds in order of increasing acidity, and explain the reasons for
a) Give the products of the following acid-base reaction. CH3CH₂OH (aq) + HCI (aq) ⇒ ? b) Will the reaction occur as written? Clearly explain your answer.

Chapter 16 Solutions

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