For each reaction, predict in what direction the equilibrium will shift when the volume of the reaction vessel is decreased.
(a)
(b)
(c)
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EBK CHEMISTRY: ATOMS FIRST
- Write an equation for an equilibrium system that would lead to the following expressions (ac) for K. (a) K=(Pco)2 (PH2)5(PC2H6)(PH2O)2 (b) K=(PNH3)4 (PO2)5(PNO)4 (PH2O)6 (c) K=[ ClO3 ]2 [ Mn2+ ]2(Pcl2)[ MNO4 ]2 [ H+ ]4 ; liquid water is a productarrow_forwardShow that the complete chemical equation, the total ionic equation, and the net ionic equation for the reaction represented by the equation KI(aq)+I2(aq)KI3(aq) give the same expression for the reaction quotient. KI3 is composed of the ions K+ and I3-.arrow_forwardWrite the expression for the equilibrium constant and calculate the partial pressure of CO2(g), given that Kp is 0.25 (at 427 C) for NaHCO3(s) NaOH(s) + CO2(g)arrow_forward
- 1. Which of the following is the correct form of the equilibrium constant expression for the decomposition of SO3 to SO2 and O2? Kc = [SO2][O2]/[SO3] Kc = [SO2]2[O2]/[SO3]2 Kc = [SO3]2/[SO2]2[O2] Kc = [SO2][O2]2arrow_forwardSuppose a reaction has the equilibrium constant K = 1.3 108. What does the magnitude of this constant tell you about the relative concentrations of products and reactants that will be present once equilibrium is reached? Is this reaction likely to be a good source of the products?arrow_forwardConsider the following equilibria involving SO2(g) and their corresponding equilibrium constants. SO2(g) + 12 O2(g) SO3(g) K1 2SO3(g) 2SO2(g) + O2(g) K2 Which of the following expressions relates K1 to K2? (a) K2=K12 (b) K22=K1 (c) K2 = K1 (d) K2 = 1/K1 (e) K2=1/K12arrow_forward
- Write a chemical equation for an equilibrium system that would lead to the following expressions (ad) for K. (a) K=(PH2S)2 (PO2)3(PSO2)2 (PH2O)2 (b) K=(PF2)1/2 (PI2)1/2PIF (c) K=[ Cl ]2(Pcl2)[ Br ]2 (d) K=(PNO)2 (PH2O)4 [ Cu2+ ]3[ NO3 ]2 [ H+ ]8arrow_forwardCalculate the value of the equilibrium constant for the reaction N2(g)+2O2(g)2NO2(g) if the concentrations of the species at equilibrium are [N2] = 0.0013, [O2] = 0.0024, and [NO2] = 0.00065.arrow_forwardBecause calcium carbonate is a sink for CO32- in a lake, the student in Exercise 12.39 decides to go a step further and examine the equilibrium between carbonate ion and CaCOj. The reaction is Ca2+(aq) + COj2_(aq) ** CaCO,(s) The equilibrium constant for this reaction is 2.1 X 10*. If the initial calcium ion concentration is 0.02 AI and the carbonate concentration is 0.03 AI, what are the equilibrium concentrations of the ions? A student is simulating the carbonic acid—hydrogen carbonate equilibrium in a lake: H2COj(aq) H+(aq) + HCO}‘(aq) K = 4.4 X 10"7 She starts with 0.1000 AI carbonic acid. What are the concentrations of all species at equilibrium?arrow_forward
- At a certain temperature, K=0.29 for the decomposition of two moles of iodine trichloride, ICl3(s), to chlorine and iodine gases. The partial pressure of chlorine gas at equilibrium is three times that of iodine gas. What are the partial pressures of iodine and chlorine at equilibrium?arrow_forwardWrite equilibrium constant expressions for the following reactions. For gases, use either pressures or concentrations. (a) 2 H2O2(g) 2 H2O(g) + O2(g) (b) CO(g) + O2g CO2(g) (c) C(s) + CO2(g) 2 CO(g) (d) NiO(s) + CO(g) Ni(s) + CO2(g)arrow_forwardFor the reaction N2(g)+3H2(g)2NH3(g) show that Kc = Kp(RT)2 Do not use the formula Kp = Kc(RT)5n given in the text. Start from the fact that Pi = [i]RT, where Pi is the partial pressure of substance i and [i] is its molar concentration. Substitute into Kc.arrow_forward
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