General, Organic, and Biological Chemistry - 4th edition
4th Edition
ISBN: 9781259883989
Author: by Janice Smith
Publisher: McGraw-Hill Education
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Question
Chapter 15, Problem 43P
Interpretation Introduction
Interpretation:
Fischer projection for the given ball and stick model needs to be determined.
Concept Introduction:
Fischer Projection is a method of drawing 3-D structures of organic molecules in 2D nature. In this method, all non-terminal bonds are depicted as horizontal or vertical lines.
For a simple molecule consists of one chiral center with four different groups attached (e.g. CHClBrI), the Fischer projection method uses a cross formula to draw the two bonds in the plane. In the Fischer projection, both horizontal bonds come forward (drawn on wedges) and both vertical bonds go behind (on dashed lines).
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Convert each three-dimensional representation into a Fischer projection.
Convert each ball-and-stick model to a Fischer projection,
a.
b.
Convert each Fischer projection into a three-dimensional representation with wedges and dashed bonds.
Chapter 15 Solutions
General, Organic, and Biological Chemistry - 4th edition
Ch. 15.1 - Prob. 15.1PCh. 15.1 - Prob. 15.1PPCh. 15.1 - For trans-2-hexene: (a) draw a stereoisomer; (b)...Ch. 15.2 - Prob. 15.3PCh. 15.2 - Prob. 15.4PCh. 15.3 - Prob. 15.2PPCh. 15.3 - Prob. 15.5PCh. 15.3 - Prob. 15.6PCh. 15.3 - Prob. 15.3PPCh. 15.3 - Prob. 15.7P
Ch. 15.3 - Prob. 15.8PCh. 15.3 - Prob. 15.9PCh. 15.4 - Prob. 15.4PPCh. 15.4 - Prob. 15.10PCh. 15.4 - Prob. 15.11PCh. 15.4 - Prob. 15.12PCh. 15.5 - Prob. 15.13PCh. 15.6 - Prob. 15.5PPCh. 15.6 - Prob. 15.14PCh. 15.6 - Prob. 15.15PCh. 15.7 - Prob. 15.16PCh. 15.7 - Prob. 15.17PCh. 15.7 - Prob. 15.6PPCh. 15.7 - Prob. 15.18PCh. 15.8 - Prob. 15.7PPCh. 15.8 - Prob. 15.19PCh. 15.9 - Prob. 15.20PCh. 15 - Prob. 21PCh. 15 - Prob. 22PCh. 15 - Prob. 23PCh. 15 - Prob. 24PCh. 15 - Prob. 25PCh. 15 - Prob. 26PCh. 15 - Prob. 27PCh. 15 - Prob. 28PCh. 15 - Prob. 29PCh. 15 - Prob. 30PCh. 15 - Prob. 31PCh. 15 - Prob. 32PCh. 15 - Prob. 33PCh. 15 - Prob. 34PCh. 15 - Prob. 35PCh. 15 - Prob. 36PCh. 15 - How are the compounds in each pair related? Are...Ch. 15 - Prob. 38PCh. 15 - Prob. 39PCh. 15 - Prob. 40PCh. 15 - Prob. 41PCh. 15 - Prob. 42PCh. 15 - Prob. 43PCh. 15 - Prob. 44PCh. 15 - Prob. 45PCh. 15 - Prob. 46PCh. 15 - Prob. 47PCh. 15 - Prob. 48PCh. 15 - Prob. 49PCh. 15 - Prob. 50PCh. 15 - (a) Define the terms “optically active” and...Ch. 15 - Prob. 52PCh. 15 - Prob. 53PCh. 15 - Prob. 54PCh. 15 - Prob. 55PCh. 15 - Prob. 56PCh. 15 - Prob. 57PCh. 15 - Prob. 58PCh. 15 - Prob. 59PCh. 15 - Prob. 60PCh. 15 - Prob. 61PCh. 15 - Prob. 62PCh. 15 - Prob. 63PCh. 15 - Prob. 64PCh. 15 - Prob. 65PCh. 15 - Prob. 66PCh. 15 - Prob. 67CPCh. 15 - Prob. 68CP
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- Convert each compound to a Fischer projection, and label each stereogenic center as R or S.arrow_forwardConvert each compound to a Fischer projection formula.arrow_forwardDraw a Fischer projection for each compound. Remember that the cross represents an asymmetric carbon atom, and the carbon chain should be along the vertical, with the IUPAC numbering from top to bottom.(R)-butan-2-olarrow_forward
- Re-draw each Fischer projection formula using wedges and dashed wedgesfor the stereogenic center, and label the center as R or S.arrow_forwardLocating Stereogenic Centers Locate the stereogenic centers in each drug. Albuterol is a bronchodilator— that is, it widens airways—so it is used to treat asthma. Chloramphenicol is an antibiotic used extensively in developing countries because of its low cost.arrow_forwardDraw the Fischer projection for structure I. Circle each chiral group in structure II.arrow_forward
- Draw a Fischer projection for each compound. Remember that the cross represents an asymmetric carbon atom, and the carbon chain should be along the vertical, with the IUPAC numbering from top to bottom.(R)-glyceraldehyde,arrow_forwardThis is one enantiomer of the molecule. OH H CCH2-CH2-CH3 CH3 Draw the structure of the other enantiomer using wedges and dashes. Click and drag to start drawing a structure.arrow_forwardConvert each compound to a Fischer projection, and label eachstereogenic center as R or S.arrow_forward
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