The given cycloalkane undergoes reaction with the given Simmons-Smith reagent which is stereospecific and gives only the isomer shown. The reason has to be suggested. Concept Introduction: Simmons-Smith reaction: This is ultrasonication improve the rate of formation of these organic zinc compounds, as with many organometallic reactions occurring at a surface condition. Example: The substance of a carbenoid a carbine like substance that converters alkene into cyclopropanes stereospcically. Addition Reaction: It is a type of reaction in which two reactants adding together to form a single product. It can be said as a reverse reaction of elimination reaction. It is a characteristic reaction of alkane . Hydrogenation reaction is an addition reaction in which addition of hydrogen to an unsaturated molecule occurs Stereoisomers a re isomeric molecules that have the same molecular formula and sequence of bonded atoms but differ in the three-dimensional orientations of their atoms in space. Stereospecific reaction: reaction undergoes from a stereoisomer to a unique stereo isomeric product.

Question

Because bromocyclohexane is a secondary alkyl halide, both cyclohexanol and cyclohexene are formed when the alkyl halide reacts with hydroxide ion. Suggest a method to synthesize cyclohexanol from bromocyclohexane that forms little or no cyclohexene.

Answer 1

Question

Chapter 15, Problem 15.13P

Interpretation Introduction

Interpretation:

The given cycloalkane undergoes reaction with the given Simmons-Smith reagent which is stereospecific and gives only the isomer shown. The reason has to be suggested.

Concept Introduction:

Simmons-Smith reaction: This is ultrasonication improve the rate of formation of these organic zinc compounds, as with many organometallic reactions occurring at a surface condition.

Example: The substance of a carbenoid a carbine like substance that converters alkene into cyclopropanes stereospcically.

Addition Reaction:

It is a type of reaction in which two reactants adding together to form a single product.

It can be said as a reverse reaction of elimination reaction.

It is a characteristic reaction of alkane.

Hydrogenation reaction is an addition reaction in which addition of hydrogen to an unsaturated molecule occurs

Stereoisomers are isomeric molecules that have the same molecular formula and sequence of bonded atoms but differ in the three-dimensional orientations of their atoms in space.

Stereospecific reaction: reaction undergoes from a stereoisomer to a unique stereo isomeric product.

Expert Solution & Answer

Trending nowThis is a popular solution!

See solution

Check out sample textbook solution

Students have asked these similar questions

Because bromocyclohexane is a secondary alkyl halide, both cyclohexanol and cyclohexene are formed when the alkyl halide reacts with hydroxide ion. Suggest a method to synthesize cyclohexanol from bromocyclohexane that forms little or no cyclohexene.

Elimination of HBr from 2-bromobutane affords a mixture of but-1-ene and but-2-ene. With sodium ethoxide as base, but2-ene constitutes 81% of the alkene products, but with potassium tert-butoxide, but-2-ene constitutes only 67% of the alkene products. Offer an explanation for this difference.

Compounds X and Y are both C7H15Cl products formed in the radical chlorination of 2,4-dimethylpentane. Base-promoted E2 elimination of X and Y gives, in each case, a single C7H₁4 alkene. Both X and Y undergo an SN2 reaction with sodium iodide in acetone solution to give C7H15l products; in this reaction Y reacts faster than X. What is the structure of X? • Do not use stereobonds in your answer. • In cases where there is more than one possible structure for each molecule, just give one for each. . Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. Separate structures with + signs from the drop-down menu. на