Principles of Instrumental Analysis
Principles of Instrumental Analysis
7th Edition
ISBN: 9781305577213
Author: Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher: Cengage Learning
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Chapter 14, Problem 14.13QAP

Copper(II) forms a 1:1 complex with the organic complexing agent R in acidic medium. The formation ofthe complex can be monitored by spectrophotometry at 480 nm. Use the following data collected under pseudo-first-order conditions to construct a calibration curve of rate versus concentration of R. Find the concentration of copper(II) in an unknown whose rate under the same conditions was 6.2 × 10- 3A s-1.
Chapter 14, Problem 14.13QAP, Copper(II) forms a 1:1 complex with the organic complexing agent R in acidic medium. The formation

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. A student collects the following data for the absorbance of a complex measured in 1.00 cmspectrophotometric cells. The molar absorptivity (ε) of the complex under investigation is 2.25×103L/mol·cm. Calculate the concentration of the complex in solution at each time of the reaction.Time (min)MeasuredAbsorbanceComplex Concentration(M)0.000 1.50010.000 1.31320.000 1.12530.000 0.93840.000 0.750
11. A researcher wants to synthesize some pentaaminefluoromanganese(l) starting with pentaaminechloromanganese(l). These are octahedral compounds. In order to identify the mechanism of reaction the researcher increased the concentration of chloride and found that no Mn(NH3)sF is formed. Do you think this is a dissociative or associative mechanism? Draw out the reaction steps. What is the coordination number for the intermediate?
Use the equation:  ln(k1/k2)=−Ea/R(1/T1−1/T2)  to calculate the activation energy k1 is 0.00316 k2 is 0.0106 R is 8.314 T2 is 298  T1 is 273
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