(a)
Interpretation:
The given integral which is exactly zero due to symmetry considerations is to be identified.
Concept introduction:
The integral is represented as shown below.
Where,
•
If the above integral has nonzero numeric value then the above integral can be written as given below.
Where,
•
If the product of irreducible representation will not be equal to
(b)
Interpretation:
The given integral which is exactly zero due to symmetry considerations is to be identified.
Concept introduction:
The integral is represented as shown below.
Where,
•
If the above integral has nonzero numeric value then the above integral can be written as given below.
Where,
•
If the product of irreducible representation will not be equal to
(c)
Interpretation:
The given integral which is exactly zero due to symmetry considerations is to be identified.
Concept introduction:
The integral is represented as shown below.
Where,
•
If the above integral has nonzero numeric value then the above integral can be written as given below.
Where,
•
If the product of irreducible representation will not be equal to
(d)
Interpretation:
The given integral which is exactly zero due to symmetry considerations is to be identified.
Concept introduction:
The integral is represented as shown below.
Where,
•
If the above integral has nonzero numeric value then the above integral can be written as given below.
Where,
•
If the product of irreducible representation will not be equal to
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Physical Chemistry
- Assume that x- polarized light can be assigned an E symmetry species in a system that has C4v symmetry. Can a transition from E state to a B2 state occur? Why or why not?arrow_forwardDetermine which single symmetry operation of the following point groups is equivalent to the given combination of multiple symmetry operations. a In C2v, C2v=? b In C2h, iC2=? c In D6h, C6h=? d In D2d, C2C2=? e In Oh, iS4=?arrow_forwardPoint groups are called such because all of the symmetry elements in the group intersect at one point in space. For point groups that have i as a symmetry operation, why must i be at that point?arrow_forward
- What is the bond order for the lowest excited state of H2+ ? From this single result, propose a general statement about unstable diatomic molecules and bond orders.arrow_forwardThe mutual exclusion rule states that for certain molecules, vibrations that are IR-active are not Raman-active, and vice versa. Molecules must have a certain symmetry element in order for the mutual exclusion rule to apply. Examine the character tables in Appendix 3 and determine what that symmetry element is.arrow_forwardConstruct the matrices for all symmetry elements in the point group C2h. Choose any pair of these symmetry elements and show that their product generates another member of the group.arrow_forward
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- Physical ChemistryChemistryISBN:9781133958437Author:Ball, David W. (david Warren), BAER, TomasPublisher:Wadsworth Cengage Learning,