Interpretation:
Limit when the volume of a gas is large relative to the number of gaseous particles that leads to van der Waals equation almost identical to the corresponding ideal-gas equation has to be shown.
Concept Introduction:
For most of the gaseous molecules, the size is not almost negligibly small and this is accounted for finite-size factor denoted by constant
Here the reduced volume is accounted for by the term
The attractive forces that result in less actual pressure than the pressure in an ideal gas, a constant
Here, the terms
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