Concept explainers
(a)
Interpretation:
The percent transmittance of the solution for the absorbance half of
Concept introduction:
The percent transmittance of a solution is the ability of the solution to allow the monochromatic light to pass through it. The percent transmittance of a solution is the ratio of the intensity of monochromatic light incident on the solution to the intensity transmitted through the solution.
The relation between the absorbance and transmittance is established by the Beer’s law.
(b)
Interpretation:
The percent transmittance of the solution for the absorbance half of
Concept introduction:
The percent transmittance of a solution is the ability of the solution to allow the monochromatic light to pass through it. The percent transmittance of a solution is the ratio of the intensity of monochromatic light incident on the solution to the intensity transmitted through the solution.
The relation between the absorbance and transmittance is established by the Beer’s law.
(c)
Interpretation:
The percent transmittance of the solution for the absorbance half of
Concept introduction:
The percent transmittance of a solution is the ability of the solution to allow the monochromatic light to pass through it. The percent transmittance of a solution is the ratio of the intensity of monochromatic light incident on the solution to the intensity transmitted through the solution.
The relation between the absorbance and transmittance is established by the Beer’s law.
(d)
Interpretation:
The percent transmittance of the solution for the absorbance half of
Concept introduction:
The percent transmittance of a solution is the ability of the solution to allow the monochromatic light to pass through it. The percent transmittance of a solution is the ratio of the intensity of monochromatic light incident on the solution to the intensity transmitted through the solution.
The relation between the absorbance and transmittance is established by the Beer’s law.
(e)
Interpretation:
The percent transmittance of the solution for the absorbance half of
Concept introduction:
The percent transmittance of a solution is the ability of the solution to allow the monochromatic light to pass through it. The percent transmittance of a solution is the ratio of the intensity of monochromatic light incident on the solution to the intensity transmitted through the solution.
The relation between the absorbance and transmittance is established by the Beer’s law.
(f)
Interpretation:
The percent transmittance of the solution for the absorbance half of
Concept introduction:
The percent transmittance of a solution is the ability of the solution to allow the monochromatic light to pass through it. The percent transmittance of a solution is the ratio of the intensity of monochromatic light incident on the solution to the intensity transmitted through the solution.
The relation between the absorbance and transmittance is established by the Beer’s law.
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Chapter 13 Solutions
Principles of Instrumental Analysis
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- (d) The Beer-Lambert law states that the absorbance (A) of light by a solution in a cuvette is given by: 10 A = In == ECL where lo is the incident light intensity, is the transmitted light intensity, e is the molar absorptivity, c is the concentration of the solution, and L is the path length of the cuvette. (1) Light with a wavelength of 800 nm is passed through a cuvette containing a solution of Coumarin dye. After passing through the cuvette, the light intensity was reduced to 10% of its initial value. What is the absorbance of the solution of Coumarin dye? (ii) The concentration of the Coumarin dye is 0.004 mol dm3, and the cuvette has a path length of 1 cm. What is the molar absorptivity of Coumarin dye at 800 nm, in units of m² mot¹? (IT) The molar absorptivity of Coumarin dye at 400 nm is three times larger than at 800 nm. How would the absorbance of the solution change, when measured with 400 nm light rather than 800 nm light?arrow_forwardWhat is the absorbance of a solution if it had 79.5% transmittance?arrow_forwardA student mixed 5.00mL of 0.0020M Fe(NO3)3, 3.00mL of 0.0020M KSCN, and 3.00mL of distilled water. The mixture reacted to form a reddish solution indicating that FeSCN2+ was formed, according to the equation below. An absorbance of 0.21 was measured for this solution in a Spectrophotometer set at a wavelength of 447nm. Fe³+ (aq) + SCN (aq) FeSCN2+ (aq) A calibration curve was used to find the equilibrium concentration of the product of this reaction: y = 1895x + 0.027 Calculate the equilibrium concentration of the Fe³+ Report your answer to 4 sig figsarrow_forward
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