Chemistry by OpenStax (2015-05-04)
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ISBN: 9781938168390
Author: Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
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Chapter 12, Problem 83E
For each of the following reaction diagrams, estimate the activation energy (Ea) of the reaction:
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Chapter 12 Solutions
Chemistry by OpenStax (2015-05-04)
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- . Account for the increase in reaction rate brought about by a catalyst.arrow_forwardBy which of the following mechanisms does a catalyst operate? a. It decreases the activation energy barrier for a reaction. b. It serves as a reactant and is consumed. c. It increases the temperature of a reaction. d. It increases the concentration of reactants.arrow_forwardWhat is the role of the activated complex in a chemical reaction?arrow_forward
- Which reaction mechanism assumptions are unimportant in describing simple ionic reactions between cations and anions? Why?arrow_forwardSubstances that poison a catalyst pose a major concern for many engineering designs, including those for catalytic converters. One design option is to add materials that react with potential poisons before they reach the catalyst. Among the commonly encountered catalyst poisons are silicon and phosphorus, which typically form phosphate or silicate ions in the oxidizing environment of an engine. Group 2 elements are added to the catalyst to react with these contaminants before they reach the working portion of the catalytic converter. If estimates show that a catalytic converter will be exposed to 625 g of silicon during its lifetime, what mass of beryllium would need to be included in the design?arrow_forwardHow do chemists envision reactions taking place in terms of the collision model for reactions? Give an example of a simple reaction and how you might envision the reaction’s taking place by means of a collision between the molecules.arrow_forward
- Consider the following activation energy diagram. Which of the following statements about the diagram are true? (a) E a(forward)E a(reverse)(b) B represents the activation energy of the forward reaction. (c) Energy (H)for the reaction is AC. (d) E a(forward)=BA(e) E a(forward)=E a(reverse)Carrow_forwardFor the following reaction profile, indicate a. the positions of reactants and products. b. the activation energy. c. E for the reaction.arrow_forwardHow is it possible for a catalyst to give products from a reaction mixture that are different from those obtained when no catalyst or a different catalyst is used? Give an example.arrow_forward
- Account for the relationship between the rate of a reaction and its activation energy.arrow_forwardOne of the concerns about the use of Freons is that they will migrate to the upper atmosphere, where chlorine atoms can be generated by the following reaction: CCl2F2(g)Freon-12hvCF2Cl(g)+Cl(g) Chlorine atoms can act as a catalyst for the destruction of ozone. The activation energy for the reaction Cl(g) + O3(g) ClO(g) + O2(g) Is 2.1 kJ/mol. Which is the more effective catalyst for the destruction of ozone, Cl or NO? (See Exercise 75.)arrow_forwardConsider a reaction in which E a=129 kJ and H=29 kJ. In the presence of a catalyst, the activation energy is 48% of the uncatalyzed reaction. Follow the directions in Question 71 in drawing an energy diagram.arrow_forward
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